Skip to main content
SpringerLink
Log in

Diffusion and growth mechanism of phases in the Pd-Sn system

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Growth mechanism of phases and atomic mechanism of diffusion are discussed in the Pd-Sn system. The Kirkendall marker plane location indicates that the PdSn4 phase grows because of diffusion of Sn. Atomic arrangement in the crystal indicates that Sn can diffuse through its own sublattice but Pd cannot diffuse unless antisites are present. The negligible diffusion of Pd indicates the absence of Pd antisites. The activation energy value indicates that the contribution from grain boundary diffusion cannot be neglected although experiments were conducted in the homologous temperature range of 0.7–0.79.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. J.K. Kivilahti, JOM 54(12), 52–57 (2002)

    Article  CAS  Google Scholar 

  2. G. Ghosh, J. Electron. Mater. 27, 1154–1160 (1998)

    Article  CAS  Google Scholar 

  3. G. Ghosh, J. Electron. Mater. 28, 1238–1250 (1999)

    Article  CAS  Google Scholar 

  4. G. Ghosh, Acta Mater. 48, 3719–3738 (2000)

    Article  CAS  Google Scholar 

  5. G. Ghosh, J. Electron. Mater. 33, 1080–1091 (2004)

    Article  CAS  Google Scholar 

  6. P.T. Vianco, J.A. Rejent, G.L. Zender, P.F. Hlava, Metall. Mater. Trans. A 41A, 3042–3052 (2010)

    Article  Google Scholar 

  7. P.T. Vianco, J.A. Rejent, G.L. Zender, P.F. Hlava, Metall. Mater. Trans. A 41A, 3053–3064 (2010)

    Article  Google Scholar 

  8. B. Kobe, N.S. McIntyre, Acta Mater. 50, 4667–4676 (2002)

    Article  CAS  Google Scholar 

  9. Y. Wang, K.N. Tu, Appl. Phys. Lett. 67, 1069–1072 (1995)

    Article  CAS  Google Scholar 

  10. T. Takenaka, M. Kajihara, N. Kurokawa, K. Sakamoto, Mat. Sci. Engg. A 406A, 134–141 (2005)

    Article  Google Scholar 

  11. R.R. Chromik, E.J. Cotts, MRS Proc. 398, 307–312 (1995)

    Article  Google Scholar 

  12. T. Sakama, M. Kajihara, Mater. Trans. 50, 266–274 (2009)

    Article  CAS  Google Scholar 

  13. T. Sakama, M. Kajihara, J. Alloy. Compd. 475, 608–613 (2009)

    Article  CAS  Google Scholar 

  14. H. Baker (ed.), ASM Handbook, Volume 3: Alloy Phase Diagrams (ASM International, Materials Park, OH, 1992)

  15. C. Wagner, Acta Metall. 17, 99–107 (1969)

    Article  CAS  Google Scholar 

  16. S. Prasad, A. Paul, J. Phase Equil. Diffus. 32, 212–218 (2011)

    Article  CAS  Google Scholar 

  17. J. Nylén, F.J. Garcìa Garcìa, B.D. Mosel, R. Pöttgen, U. Häussermann, Solid State Sci. 6, 147–155 (2004)

    Article  Google Scholar 

  18. A. Paul, M.J.H. Van Dal, A.A. Kodentsov, F.J.J. van Loo, Acta Mater. 52, 623–630 (2004)

    Article  CAS  Google Scholar 

  19. A. Paul, A.A. Kodentsov, F.J.J. van Loo, Intermetallics 14, 1428–1432 (2006)

    Article  CAS  Google Scholar 

  20. C. Ghosh, A. Paul, Acta Mater. 55, 1927–1939 (2007)

    Article  CAS  Google Scholar 

  21. C. Ghosh, A. Paul, Acta Mater. 57, 493–502 (2009)

    Article  CAS  Google Scholar 

  22. H. Numakura, T. Ikeda, M. Koiwa, A. Amazouzi, Phil. Mag. A 77, 887–909 (1998)

    Article  CAS  Google Scholar 

  23. A. Paul, A.A. Kodentsov, F.J.J. van Loo, Z. Metallkunde 95, 913–920 (2004)

    CAS  Google Scholar 

  24. A. Paul, Scripta Mater. 61, 561–563 (2009)

    Article  CAS  Google Scholar 

  25. A. Paul, The Kirkendall Effect in Solid State Diffusion, PhD thesis, Eindhoven University of Technology, The Netherlands, (2004)

  26. D.A. Porter, K.E. Easterling, M.Y. Sherif, Phase Transformations in Metals and Alloys, 3rd edn. (CRC Press, Boca Raton, 2009)

    Google Scholar 

  27. A. Paul, C. Ghosh, W.J. Boettinger, Metall. Mat. Trans. A 42A, 952–963 (2011)

    Article  Google Scholar 

  28. A. Paul, A.A. Kodentsov, G. de With, F.J.J. van Loo, Intermetallics 11, 1195–1203 (2003)

    Article  CAS  Google Scholar 

  29. S. Prasad, A. Paul, Acta Mater. 59, 1577–1585 (2011)

    Article  CAS  Google Scholar 

  30. S. Prasad, A. Paul, Intermetallics 19, 1191–1200 (2011)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Engineering, Indian Institute of Science, Bangalore, India

    Raju Ravi & Aloke Paul

Authors
  1. Raju Ravi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Aloke Paul
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Aloke Paul.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ravi, R., Paul, A. Diffusion and growth mechanism of phases in the Pd-Sn system. J Mater Sci: Mater Electron 23, 2306–2310 (2012). https://doi.org/10.1007/s10854-012-0832-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-012-0832-4

Keywords

Search

Navigation