Abstract
Nitric oxide (NO) as the major constituent of nitrogen oxides (NOx), which is mainly emitted from combustion processes, is responsible for several environmental and health issues, and the control of its emission is a global concern. In this regard, this study investigates low-temperature oxidative uptake of NO on alkali-modified biochar. Rubber seed shell was utilized as a locally available lignocellulosic waste to develop biochar through slow pyrolysis. The porosity attributes and surface chemistry of the developed biochar were then improved through alkali modification. The NO capture capacity of KOH, NaOH, K2CO3 and Na2CO3-activated biochars was 63.0, 59.3, 59.0 and 58.5 mg/g, respectively, which was considerably higher than that of the pristine biochar, 17.8 mg/g. This considerable improvement was mainly attributed to the introduction of more oxygen functionalities, improvement of microporosity and creation of more carbon defects in the biochar, after alkali modification. With some investigations on the alkali agent/biochar impregnation ratio, the adsorption capacity of the KOH-activated biochar (at a ratio of 2:1 (w/w)) could be improved to 87.0 mg/g at 30 °C. Characterization studies using FTIR and XPS suggested that the adsorbed species on the biochar surface was in the form of monodentate nitrito (–O–N=O), which was formed from the oxidation of NO on the surface-oxidized groups. Kinetic studies using pseudo-first, pseudo-second and Elovich models indicated that the adsorption of NO on KOH-activated biochar surface was mainly controlled by a physisorption or a weak chemisorption process, with a low activation energy of − 29 kJ/mol.
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References
Abdulrasheed A, Jalil A, Triwahyono S, Zaini M, Gambo Y, Ibrahim M (2018) Surface modification of activated carbon for adsorption of SO2 and NOX: a review of existing and emerging technologies. Renew Sustain Energy Rev 94:1067–1085. https://doi.org/10.1016/j.rser.2018.07.011
Adapa S, Gaur V, Verma N (2006) Catalytic oxidation of NO by activated carbon fiber (ACF). Chem Eng J 116(1):25–37. https://doi.org/10.1016/j.cej.2005.10.007
Ahmad M, Lee SS, Rajapaksha AU, Vithanage M, Zhang M, Cho JS, Lee S-E, Ok YS (2013) Trichloroethylene adsorption by pine needle biochars produced at various pyrolysis temperatures. Bioresour Technol 143:615–622. https://doi.org/10.1016/j.biortech.2013.06.033
Al-Rahbi AS, Williams PT (2016) Production of activated carbons from waste tyres for low temperature NOx control. Waste Manag 49:188–195. https://doi.org/10.1016/j.wasman.2016.01.030
Alcañiz-Monge J, Bueno-López A, Lillo-Rodenas MÁ, Illán-Gómez MJ (2008) NO adsorption on activated carbon fibers from iron-containing pitch. Microporous Mesoporous Mater 108(1–3):294–302. https://doi.org/10.1016/j.micromeso.2007.04.011
Andreoli E, Cullum L, Barron AR (2015) Carbon dioxide absorption by polyethylenimine-functionalized nanocarbons: a kinetic study. Ind Eng Chem Res 54(3):878–889. https://doi.org/10.1021/ie504277s
Anthonysamy SI, Lahijani P, Mohammadi M, Mohamed AR (2020) Low temperature adsorption of nitric oxide on cerium impregnated biomass-derived biochar. Korean J Chem Eng 37(1):130–140. https://doi.org/10.1007/s11814-019-0405-9
Bakar NA, Othman N, Yunus ZM, Altowayti WAH, Tahir M, Fitriani N, Mohd-Salleh SNA (2021) An insight review of lignocellulosic materials as activated carbon precursor for textile wastewater treatment. Environ Technol Innov. https://doi.org/10.1016/j.eti.2021.101445
Belhachemi M, Jeguirim M, Limousy L, Addoun F (2014) Comparison of NO2 removal using date pits activated carbon and modified commercialized activated carbon via different preparation methods: effect of porosity and surface chemistry. Chem Eng J 253:121–129. https://doi.org/10.1016/j.cej.2014.05.004
Cao F, Chen J, Ni M, Song H, Xiao G, Wu W, Gao X, Cen K (2014) Adsorption of NO on ordered mesoporous carbon and its improvement by cerium. RSC Adv 4(31):16281–16289. https://doi.org/10.1039/C4RA01409J
Chen J, Cao F, Chen S, Ni M, Gao X, Cen K (2014a) Adsorption kinetics of NO on ordered mesoporous carbon (OMC) and cerium-containing OMC (Ce-OMC). Appl Surf Sci 317:26–34. https://doi.org/10.1016/j.apsusc.2014.08.067
Cheng D, Ngo HH, Guo W, Chang SW, Nguyen DD, Zhang X, Varjani S, Liu Y (2020) Feasibility study on a new pomelo peel derived biochar for tetracycline antibiotics removal in swine wastewater. Sci Total Environ. https://doi.org/10.1016/j.scitotenv.2020.137662
Dehkhoda AM, Ellis N, Gyenge E (2014) Electrosorption on activated biochar: effect of thermo-chemical activation treatment on the electric double layer capacitance. J Appl Electrochem 44(1):141–157. https://doi.org/10.1007/s10800-013-0616-4
Deng W, Tao C, Cobb K, Zhou H, Su Y, Ruan R (2020) Catalytic oxidation of NO at ambient temperature over the chars from pyrolysis of sewage sludge. Chemosphere 251:126429. https://doi.org/10.1016/j.chemosphere.2020.126429
Dıaz-Terán J, Nevskaia D, Fierro J, López-Peinado A, Jerez A (2003) Study of chemical activation process of a lignocellulosic material with KOH by XPS and XRD. Microporous Mesoporous Mater 60(1–3):173–181. https://doi.org/10.1016/S1387-1811(03)00338-X
Ding S, Liu Y (2020) Adsorption of CO2 from flue gas by novel seaweed-based KOH-activated porous biochars. Fuel 260:116382. https://doi.org/10.1016/j.fuel.2019.116382
Gargiulo V, Gomis-Berenguer A, Giudicianni P, Ania CO, Ragucci R, Alfè M (2018) Assessing the potential of biochars prepared by steam-assisted slow pyrolysis for CO2 adsorption and separation. Energy Fuels 32(10):10218–10227. https://doi.org/10.1021/acs.energyfuels.8b01058
Ghafari M, Atkinson JD (2016) Catalytic NO oxidation in the presence of moisture using porous polymers and activated carbon. Environ Sci Technol 50(10):5189–5196. https://doi.org/10.1021/acs.est.5b05443
Guo Y, Li Y, Zhu T, Ye M (2015) Investigation of SO2 and NO adsorption species on activated carbon and the mechanism of NO promotion effect on SO2. Fuel 143:536–542. https://doi.org/10.1016/j.fuel.2014.11.084
Herath A, Layne CA, Perez F, Hassan EB, Pittman CU Jr, Mlsna TE (2020) KOH-activated high surface area Douglas Fir biochar for adsorbing aqueous Cr (VI), Pb (II) and Cd (II). Chemosphere. https://doi.org/10.1016/j.chemosphere.2020.128409
Inyinbor A, Adekola F, Olatunji GA (2016) Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp. Water Resour Ind 15:14–27. https://doi.org/10.1016/j.wri.2016.06.001
Jjagwe J, Olupot PW, Menya E, Kalibbala HM (2021) Synthesis and application of granular activated carbon from biomass waste materials for water treatment: a review. J Bioresour Bioprod. https://doi.org/10.1016/j.jobab.2021.03.003
Juang R-S, Chen M-L (1997) Application of the Elovich equation to the kinetics of metal sorption with solvent-impregnated resins. Ind Eng Chem Res 36(3):813–820. https://doi.org/10.1021/ie960351f
Kong M, Liu Q, Guo F, Jiang L, Yao L, Ren S, Yang J (2018) Physicochemical properties of pine-derived bio-chars modified by metal oxides and their performance in the removal of NO. J Energy Inst 91(3):467–472. https://doi.org/10.1016/j.joei.2017.01.006
Kudahi SN, Noorpoor AR, Mahmoodi NM (2017) Determination and analysis of CO2 capture kinetics and mechanisms on the novel graphene-based adsorbents. J CO2 Util 21:17–29. https://doi.org/10.1016/j.jcou.2017.06.010
Lahijani P, Mohammadi M, Mohamed AR (2019) Catalytic CO2 gasification of rubber seed shell-derived hydrochar: reactivity and kinetic studies. Environ Sci Pollution Res 26(12):11767–11780. https://doi.org/10.1007/s11356-019-04613-4
Lahijani P, Zainal ZA, Mohammadi M, Mohamed AR (2015) Conversion of the greenhouse gas CO2 to the fuel gas CO via the Boudouard reaction: a review. Renew Sustain Energy Rev 41:615–632. https://doi.org/10.1016/j.rser.2014.08.034
Lee Y-W, Choi D-K, Park J-W (2002) Performance of fixed-bed KOH impregnated activated carbon adsorber for NO and NO2 removal in the presence of oxygen. Carbon 40(9):1409–1417. https://doi.org/10.1016/S0008-6223(01)00312-8
Li X, Dong Z, Dou J, Yu J, Tahmasebi A (2016) Catalytic reduction of NO using iron oxide impregnated biomass and lignite char for flue gas treatment. Fuel Process Technol 148:91–98. https://doi.org/10.1016/j.fuproc.2016.02.030
Li Y, Xing B, Ding Y, Han X, Wang S (2020) A critical review of the production and advanced utilization of biochar via selective pyrolysis of lignocellulosic biomass. Bioresour Technol. https://doi.org/10.1016/j.biortech.2020.123614
Nayl A, Elkhashab R, Malah T, Yakout S, El-Khateeb M, Ali M, Ali H (2017) Adsorption studies on the removal of COD and BOD from treated sewage using activated carbon prepared from date palm waste. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-017-9878-4
Nowicki P, Pietrzak R, Wachowska H (2010) Sorption properties of active carbons obtained from walnut shells by chemical and physical activation. Catal Today 150(1–2):107–114. https://doi.org/10.1016/j.cattod.2009.11.009
Reshad AS, Tiwari P, Goud VV (2018) Thermo-chemical conversion of waste rubber seed shell to produce fuel and value-added chemicals. J Energy Inst 91(6):940–950. https://doi.org/10.1016/j.joei.2017.09.002
Richter E (1990) Carbon catalysts for pollution control. Catal Today 7(2):93–112. https://doi.org/10.1016/0920-5861(90)85011-C
Richter E, Schmidt HJ, Schecker HG (1990) Adsorption and catalytic reactions of NO and NH3 on activated carbon. Chem Eng Technol 13(1):332–340. https://doi.org/10.1002/ceat.270130146
Rubel AM, Stencel JM (1996) Effect of pressure on NOx adsorption by activated carbons. Energy Fuels 10(3):704–708. https://doi.org/10.1021/ef9501861
Rubel A, Stewart M, Stencel J (1995) Activated carbon for control of nitrogen oxide emissions. J Mater Ees 10(3):562–567. https://doi.org/10.1557/JMR.1995.0562
Shen Y, Ge X, Chen M (2016) Catalytic oxidation of nitric oxide (NO) with carbonaceous materials. RSC Adv 6(10):8469–8482. https://doi.org/10.1039/C5RA24148K
Teng H, Suuberg EM (1993) Chemisorption of nitric oxide on char. 1. Reversible nitric oxide sorption. J Phys Chem 97(2):478–483. https://doi.org/10.1021/j100104a033
Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87(9–10):1051–1069. https://doi.org/10.1515/pac-2014-1117
Tiwari D, Bhunia H, Bajpai PK (2018) Adsorption of CO2 on KOH activated, N-enriched carbon derived from urea formaldehyde resin: kinetics, isotherm and thermodynamic studies. Appl Surf Sci 439:760–771. https://doi.org/10.1016/j.apsusc.2017.12.203
Wu F-C, Tseng R-L, Juang R-S (2009) Characteristics of Elovich equation used for the analysis of adsorption kinetics in dye-chitosan systems. Chem Eng J 150(2–3):366–373. https://doi.org/10.1016/j.cej.2009.01.014
Xiao X, Chen B, Chen Z, Zhu L, Schnoor JL (2018) Insight into multiple and multilevel structures of biochars and their potential environmental applications: a critical review. Environ Sci Technol 52(9):5027–5047. https://doi.org/10.1021/acs.est.7b06487
Yang D-j, Ma X-w, Lv H, Li B, Zhang C-m (2018) NO adsorption and temperature programmed desorption on K2CO3 modified activated carbons. J Cent South Univ 25(10):2339–2348. https://doi.org/10.1007/s11771-018-3918-1
Yang J, Zhou J, Tong W, Zhang T, Kong M, Ren S (2019) Low-temperature flue gas denitration with transition metal oxides supported on biomass char. J Energy Inst 92(4):1158–1166. https://doi.org/10.1016/j.joei.2018.06.002
You F-T, Yu G-W, Wang Y, Xing Z-J, Liu X-J, Li J (2017) Study of nitric oxide catalytic oxidation on manganese oxides-loaded activated carbon at low temperature. Appl Surf Sci 413:387–397. https://doi.org/10.1016/j.apsusc.2017.04.044
You F-T, Yu G-W, Xing Z-J, Li J, Xie S-Y, Li C-X, Wang G, Ren H-Y, Wang Y (2019) Enhancement of NO catalytic oxidation on activated carbon at room temperature by nitric acid hydrothermal treatment. Appl Surf Sci 471:633–644. https://doi.org/10.1016/j.apsusc.2018.12.066
Yu JT, Dehkhoda AM, Ellis N (2011) Development of biochar-based catalyst for transesterification of canola oil. Energy Fuels 25(1):337–344. https://doi.org/10.1021/ef100977d
Zhang W, Rabiei S, Bagreev A, Zhuang M, Rasouli F (2008) Study of NO adsorption on activated carbons. Appl Catal B 83(1–2):63–71. https://doi.org/10.1016/j.apcatb.2008.02.003
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The authors gratefully acknowledge the financial support provided by USM-NanoMITE under the Long-Term Research Grant Scheme (LRGS) (203/PJKIMIA/6720009).
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SIA performed investigation and writing the original draft; PL was involved in visualization, review and editing; MM wrote, reviewed and edited the article; ARM contributed to supervision and funding acquisition.
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Anthonysamy, S.I., Lahijani, P., Mohammadi, M. et al. Alkali-modified biochar as a sustainable adsorbent for the low-temperature uptake of nitric oxide. Int. J. Environ. Sci. Technol. 19, 7127–7140 (2022). https://doi.org/10.1007/s13762-021-03617-3
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DOI: https://doi.org/10.1007/s13762-021-03617-3