Skip to main content
SpringerLink
Log in

The grafting of phenolphthalein or 4-tritylaniline onto polyurethane and the comparison of their effects on tensile and shape recovery properties and flexibility at low temperature of the resulting polymers

  • Article
  • Published:
Macromolecular Research Aims and scope Submit manuscript

An Erratum to this article was published on 30 January 2018

This article has been updated

Abstract

Phenolphthalein (PP series) or 4-tritylaniline (TA series) was used for grafting onto polyurethane (PU), and the effects of two grafted groups on the soft segment glass transition, tensile strength, recovery to original shape, and flexibility at freezing temperature were investigated. The soft segment melting of PP series and TA series was not significantly affected with increases in phenolphthalein or tritylaniline content. The soft segment glass transition temperature (T g ) of PP series clearly increased as the PP content increased, whereas TA series exhibited a little increase in T g with increases of TA. Solution viscosity, degree of cross-linking, shape recovery at 10 °C, and tensile strength of PP series clearly increased with increases in PP because of cross-linking in the grafted phenolphthalein, whereas TA series did not demonstrate the same degree of enhancement with increases in TA. In contrast to plain PU and TA series, PP series displayed outstanding flexibility below 0 °C. Therefore, compared to plain PU, the grafting of phenolphthalein clearly enhanced the tensile strength, flexibility under freezing, and recovery to original shape of the polymer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Change history

  • 30 January 2018

    Page 66, the Acknowledgments should be corrected as follows: This study was supported by the Korea Electric Power Corporation (KEPCO) Open R&D program (Project No.: R17XH03).

References

  1. R. B. Seymour and G. B. Kauffman, J. Chem. Ed., 69, 909 (1992).

    Article  CAS  Google Scholar 

  2. H. W. Engels, H. G. Pirkl, R. Albers, R. W. Albach, J. Krause, A. Hoffmann, H. Casselmann, and J. Dormish, Angew. Chem. Int. Ed., 52, 9422 (2013).

    Article  CAS  Google Scholar 

  3. R. J. Zdrahala and I. J. Zdrahala, J. Biomater. Appl., 14, 67 (1999).

    Article  CAS  Google Scholar 

  4. S. Sartori, A. Rechichi, G. Vozzi, M. D’Acunto, E. Heine, P. Giusti, and G. Ciardelli, React. Funct. Polym., 68, 809 (2008).

    Article  CAS  Google Scholar 

  5. C. Freij-Larsson and B. Wesslen, J. Appl. Polym. Sci., 50, 345 (1993).

    Article  CAS  Google Scholar 

  6. K. Tan and S. K. Obendorf, J. Membr. Sci., 274 150 (2006).

    Article  CAS  Google Scholar 

  7. K. Tan and S. K. Obendorf, J. Membr. Sci., 289, 199 (2007).

    Article  CAS  Google Scholar 

  8. Y. C. Chung, H. Y. Kim, J. H. Yu, and B. C. Chun, Macromol. Res., 23, 350 (2015).

    Article  CAS  Google Scholar 

  9. Y. C. Chung, H. Y. Kim, J. W. Choi, and B. C. Chun, J. Appl. Polym. Sci., 132, 41676 (2015).

    Article  Google Scholar 

  10. H. Jingjing and X. Weilin, Appl. Surf. Sci. 256, 3921 (2010).

    Article  Google Scholar 

  11. H. Chunli, W. Miao, C. Xianmei, H. Xiaobo, L. Li, Z. Haomiao, S. Jian, and Y. Jiang, Appl. Surf. Sci., 258, 755 (2011).

    Article  Google Scholar 

  12. Y. C. Chung, B. H. Lee, S. H. Jo, and B. C. Chun, Polym.-Plast. Technol., 54, 1066 (2015).

    Article  CAS  Google Scholar 

  13. J. D. Zook, S. DeMoss, D. W. Jordan, and C. B. Rao, US Patent 6172179 B1 (2001).

    Google Scholar 

  14. A. N. Theodore and P. C. Killgoar Jr, US Patent 4853428 A (1987).

  15. J. Liu, G. Chen, J. Guo, N. Mushtaq, and X. Fang, Polymer, 70, 30 (2015).

    Article  Google Scholar 

  16. A. N. Lai, Y. Z. Zhuo, C. X. Lin, Q. G. Zhang, A. M. Zhu, M. L. Ye, and Q. L. Liu, J. Membr. Sci., 502, 94 (2016).

    Article  CAS  Google Scholar 

  17. A. H. N. Rao, H. J. Kim, S. Nam, and T. H. Kim, Polymer, 54, 6918 (2013).

    Article  CAS  Google Scholar 

  18. H. Jang, M. M. Islama, Y. Lima, S. Lee, M. A. Hossain, T. Hong, S. Lee, Y. Hong, and W. G. Kim, Solid State Ionics, 262, 845 (2014).

    Article  CAS  Google Scholar 

  19. R. T. S. Muthu Lakshmi, J. Meier-Haack, K. Schlenstedt, H. Komber, V. Choudhary, and I. K. Varma, React. Funct. Polym., 66, 634 (2006).

    Article  Google Scholar 

  20. J. Wang, Z. Hu, X. Yin, Y. Li, H. Huo, J. Zhou, and L. Li, Electrochim. Acta, 159, 61 (2015).

    Article  CAS  Google Scholar 

  21. M. Hetzer, C. Fleischmann, B. V. K. J. Schmidt, C. Barner-Kowollik, and H. Ritter, Polymer, 54, 5141 (2013).

    Article  CAS  Google Scholar 

  22. S. Bisoi, A. K. Mandal, V. Padmanabhan, and S. Banerjee, J. Membr. Sci., 522, 77 (2017).

    Article  CAS  Google Scholar 

  23. H. Kern, S. W. Choi, G. Wenz, J. Heinrich, L. Ehrhardt, P. Mischnick, P. Garidel, and A. Blume, Carbohydr. Res., 326, 67 (2000).

    Article  CAS  Google Scholar 

  24. S. M. Seyed Mohaghegh, M. Barikani, and A. A. Entezami, Colloid Surf. A, 276, 95 (2006).

    Article  Google Scholar 

  25. Z. Su, Q. Li, Y. Liu, G. H. Hu, and C. Wu, Eur. Polym. J., 45, 2428 (2009).

    Article  CAS  Google Scholar 

  26. T. Choi, J. Weksler, A. Padsalgikar, and J. Runt, Polymer, 51, 4375 (2010).

    Article  CAS  Google Scholar 

  27. P. Russo, M. Lavorgna, F. Piscitelli, D. Acierno, and L. Di Maio, Eur. Polym. J., 49, 379 (2013).

    Article  CAS  Google Scholar 

  28. Y. C. Chung, K. S. Kang, and B. C. Chun, J. Sol.-Gel. Sci. Technol., 72, 543 (2014).

    Article  CAS  Google Scholar 

  29. Y. C. Chung, N. D. Khiem, J. W. Choi, and B. C. Chun, J. Macromol. Sci. A, 51, 1 (2014).

    Article  Google Scholar 

  30. Y. C. Chung, D. K. Nguyen, and B. C. Chun, Polym. Eng. Sci., 50, 2457 (2010).

    Article  CAS  Google Scholar 

  31. M. D. Ellul, US Patent 5290886 A (1994).

    Google Scholar 

  32. D. Nissen, H. U. Schmidt, W. Straehle, and U. Schuett, and M. Marx, US Patent 4383050 A (1983).

Download references

Author information

Authors and Affiliations

  1. School of Nano Engineering, Inje University, Gimhae, Gyeongnam, 50834, Korea

    Jin Cheol Bae, Jae Won Choi & Byoung Chul Chun

  2. Department of Chemistry, The University of Suwon, Hwaseong, Gyeonggi, 18323, Korea

    Yong-Chan Chung

Authors
  1. Yong-Chan Chung
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jin Cheol Bae
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jae Won Choi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Byoung Chul Chun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Byoung Chul Chun.

Additional information

Acknowledgment: This study was supported by the R&D Center for Valuable Recycling (Global-Top R&BD Program) of the Ministry of Environment (Project No.: R2-11 2016002240004).

An erratum to this article is available at https://doi.org/10.1007/s13233-018-6200-3.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chung, YC., Bae, J.C., Choi, J.W. et al. The grafting of phenolphthalein or 4-tritylaniline onto polyurethane and the comparison of their effects on tensile and shape recovery properties and flexibility at low temperature of the resulting polymers. Macromol. Res. 26, 66–76 (2018). https://doi.org/10.1007/s13233-018-6013-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13233-018-6013-4

Keywords

Search

Navigation