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The Effects of Grafting and Crosslinking Aliphatic Dicarboxylic Acids onto Polyurethane on the Tensile Stress and Shape Recovery

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Abstract

The aliphatic dicarboxylic acid, glutaric acid or dodecanedioic acid, were used for the grafting onto polyurethane (PU) or cross-linking of PUs to gauge its impact on the hydrophilicity, tensile stress, and shape recovery properties of PU. The cross-link density and solution viscosity gradually increased, but the maximum tensile stress and shape recovery sharply increased with the increase of diacid content due to the chemical linking using the grafted diacid. The soft segment melting and glass transition were not substantially affected by the grafting of diacid. The water swelling of the diacid-grafted PUs gradually improved with time. The low temperature flexibility of PU slightly improved by the grafted glutaric acid compared with the control series PU. Therefore, the grafted dicarboxylic acid could enhance the hydrophilicity, maximum tensile stress, shape recovery, and low temperature flexibility of PU.

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References

  1. M. A. Pujana, L. Pérez-Álvarez, L. C. C. Iturbe, and I. Katime, Polymer, 53, 3107 (2012).

    Article  CAS  Google Scholar 

  2. W. Lv, Y. El-Hebshi, B. Li, Y. Xia, R. Xu, and X. Chen, Polym. Test., 32, 353 (2013).

    Article  CAS  Google Scholar 

  3. Z. Jia, W. Shi, Y. Wang, and J. Wang, Colloid Surf., 494, 101 (2016).

    Article  CAS  Google Scholar 

  4. Z. S. Petrović and J. Ferguson, Prog. Polym. Sci., 16, 695 (1991).

    Article  Google Scholar 

  5. R. B. Seymour and G. B. Kauffman, J. Chem. Ed., 69, 909 (1992).

    Article  CAS  Google Scholar 

  6. H. W. Engels, H. G. Pirkl, R. Albers, R. W. Albach, J. Krause, A. Hoffmann, H. Casselmann, and J. Dormish, Angew. Chem. Int. Ed., 52, 9422 (2013).

    Article  CAS  Google Scholar 

  7. B. C. Chun, M. H. Chong, and Y. C. Chung, J. Mater. Sci., 42, 6524 (2007).

    Article  CAS  Google Scholar 

  8. Y. C. Chung, T. K. Cho, and B. C. Chun, J. Appl. Polym. Sci., 112, 2800 (2009).

    Article  CAS  Google Scholar 

  9. C. P. Buckley, C. Prisacariu, and A. Caraculacu, Polymer, 48, 1388 (2007).

    Article  CAS  Google Scholar 

  10. Y. C. Chung, N. D. Khiem, J. W. Choi, and B. C. Chun, Fiber Polym., 16, 492 (2015).

    Article  CAS  Google Scholar 

  11. Y. C. Chung, H. Y. Kim, J. H. Yu, and B. C. Chun, Macromol. Res., 23, 350 (2015).

    Article  CAS  Google Scholar 

  12. P. Alves, J. F. J. Coelho, J. Haack, A. Rota, A. Bruinink, and M. H. Gil, Eur. Polym. J., 45, 1412 (2009).

    Article  CAS  Google Scholar 

  13. K. Tan and S. K. Obendorf, J. Membr. Sci., 289, 199 (2007).

    Article  CAS  Google Scholar 

  14. C. He, M. Wang, X. Cai, X. Huang, L. Li, H. Zhu, J. Shen, and J. Yuan, Appl. Surf. Sci., 258, 755 (2011).

    Article  CAS  Google Scholar 

  15. S. M. Seyed Mohaghegh, M. Barikani, and A. A. Entezami, Colloid Surf. A, 276, 95 (2006).

    Article  CAS  Google Scholar 

  16. Z. Su, Q. Li, Y. Liu, G. H. Hu, and C. Wu, Eur. Polym. J., 45, 2428 (2009).

    Article  CAS  Google Scholar 

  17. Y. C. Chung, S. H. Jo, H. Y. Kim, and B. C. Chun, Polym.-Plast. Technol., 55, 356 (2016).

    Article  CAS  Google Scholar 

  18. Y. Swolfs, E. Bertels, I. Verpoest, and B. Goderis, Polymer, 81, 1 (2015).

    Article  CAS  Google Scholar 

  19. T. Hatakeyama, Y. Izuta, S. Hirose, and H. Hatakeyama, Polymer, 43, 1177 (2002).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Nano Engineering, Inje University, Gimhae, Gyeongnam, 50834, Korea

    Jin Cheol Bae & Byoung Chul Chun

  2. Department of Chemistry, The University of Suwon, Hwaseong, Gyeonggi, 18323, Korea

    Yong-Chan Chung & Cheol Hoon Jang

Authors
  1. Yong-Chan Chung
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  2. Cheol Hoon Jang
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  3. Jin Cheol Bae
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  4. Byoung Chul Chun
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Correspondence to Byoung Chul Chun.

Additional information

Acknowledgments: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2016R1D1A1B01014308).

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Chung, YC., Jang, C.H., Bae, J.C. et al. The Effects of Grafting and Crosslinking Aliphatic Dicarboxylic Acids onto Polyurethane on the Tensile Stress and Shape Recovery. Macromol. Res. 26, 825–830 (2018). https://doi.org/10.1007/s13233-018-6105-1

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  • DOI: https://doi.org/10.1007/s13233-018-6105-1

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