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Deformation and phase transformations during the cyclic oxidation of Ni−Al and Ni−Pt−Al

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Abstract

The reversible high-temperature γ′ to β phase transformation may be critical to explaining the unusual high-temperature oxidation behavior of (Ni,Pt)Al alloys and coatings. During high-temperature, high-frequency (1 h) cyclic oxidation in dry, flowing O2, unprecedented macroscopic deformation was observed in two-phase (γ′+β) cast specimens of Hf-doped Ni−Al at 1,150°C and Hf-doped Ni−Pt−Al at 1,100° and 1,150°C, Outside of this two-phase field or when the cycle frequency was decreased to 100h, no deformation was observed. Using high-temperaturex-ray diffraction in an inert environment, the β-to-γ′ phase ratio was observed to increase above 1,000°C, causing a 2.5% volume change. The addition of platinum appeared to lower the transformation temperature consistent with the deformation observed in castalloys and rumpling of simple and platinum-modified aluminide coatings.

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Authors and Affiliations

  1. the Metals and Ceramics Division at Oak Ridge National Laboratory in Oak Ridge, Tennessee

    B. A. Pint, S. A. Speakman & C. J. Rawn

  2. Department of Mechanical Engineering at Tennessee Technological University in Cookeville, Tennessee

    Y. Zhang

Authors
  1. B. A. Pint
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  2. S. A. Speakman
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  3. C. J. Rawn
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  4. Y. Zhang
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Pint, B.A., Speakman, S.A., Rawn, C.J. et al. Deformation and phase transformations during the cyclic oxidation of Ni−Al and Ni−Pt−Al. JOM 58, 47–52 (2006). https://doi.org/10.1007/s11837-006-0068-y

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