Abstract
This work primarily focused on the design of electrochemical and modified analytical sensors by two highly conductive and powerful modifiers including titanium oxide nanotubes/single wall carbon nanotubes (TiO2-SWCNTs) and 1-hexyl 3-methyl imidazolium hexafluorophosphate (HMH) to detect bisphenol A (BPA) in the well water, municipal water, and soft drinks. In this regard, carbon paste electrode (CPE) was amplified with HMH and TiO2-SWCNTs, and then it was utilized for voltammetric sensing of bisphenol A in aqueous solution. The ability of sensor for determination of bisphenol A was assessed by chronoamperometric, cyclic voltammetric and differential pulse voltammetric (DPV) methods. At optimal condition of pH=5.0, TiO2-SWCNTs/HMH/CPE offered a powerful catalytic effect on oxidation signal of bisphenol A and enhanced its current about 7.77 times. Using DP voltammetric method, the TiO2-SWCNTs/HMH/CPE showed a linear dynamic range of 3.0 nM – 450 µM, and a good limit of detection of 1.0 nM. Moreover, TiO2-SWCNTs/HMH/CPE provided acceptable recovery data for determination of bisphenol A in real samples such as well water, Urban water and soft drink.
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Nasehi, P., Moghaddam, M.S., Rezaei-savadkouhi, N. et al. Monitoring of Bisphenol A in water and soft drink products using electrochemical sensor amplified with TiO2-SWCNTs and ionic liquid. Food Measure 16, 2440–2445 (2022). https://doi.org/10.1007/s11694-022-01321-5
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DOI: https://doi.org/10.1007/s11694-022-01321-5