Skip to main content

Advertisement

Log in

Structure and Hot Corrosion Behavior of an Al-Co-Y Co-deposited Coating on TiAl Alloy

  • Technical Article
  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

The hot corrosion behavior of Al-Co-Y co-deposited coatings on TiAl alloy was investigated in 25% NaCl + 75% K2SO4 molten salt at 850 °C. Results show that O, S and other corrosive media are preferentially corroded by the α2 phase of the TiAl matrix, generating corrosion products with poor density and adhesion, resulting in rapid corrosion. The Al-Co-Y co-deposited coating specimens form a dense Al2O3 film during the hot corrosion incubation, which effectively improves the anti-hot corrosion performance of TiAl alloy. During hot corrosion, the Al2O3 film is dissolved and ruptured under the action of mixed salts, losing its protective properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. M. Yamaguchi, H. Inui and K. Ito, High-Temperature Structural Intermetallics, Acta Mater., 2000, 48, p 307–322.

    Article  CAS  Google Scholar 

  2. M. Yoshihara and Y.W. Kim, Oxidation Behavior of Gamma Alloys Designed for High Temperature Applications, Intermetallics, 2005, 13, p 952–958.

    Article  CAS  Google Scholar 

  3. Y.J. Xi, Y.J. Liu, Z.X. Wang and J.B. Lu, Effects of TiAl Coating on Hot Corrosion and Electrochemical Corrosion of Ti3Al Alloy, J. Mater. Eng., 2009, 30, p 49–52.

    CAS  Google Scholar 

  4. X.Q. Long, Mechanism of Hot Corrosion in High Temperature Parts of Aeroengine, Total Corros. Control, 2003, 17, p 9–14.

    Google Scholar 

  5. C.L. Zeng, J.Q. Zhang, W.T. Wu, J.S. Wu, G.H. Qiu and D. Li, Effect of Alloying Elements on Hot Corrosion Resistance of Ti3Al Intermetallic Compound, Corros. Sci. Prot. Tech., 1995, 7, p 29–34.

    CAS  Google Scholar 

  6. E. Godlewska, M. Mitoraj and M. Leszczynska, Hot Corrosion of Ti-46Al-8Ta (at.%) Intermetallic Alloy, Corros. Sci., 2014, 78, p 63–70.

    Article  CAS  Google Scholar 

  7. K. Zhang, Z.W. Li and W. Gao, Hot Corrosion Behaviour of Ti-Al Based Intermetallics, Mater. Lett., 2002, 57, p 834–843.

    Article  CAS  Google Scholar 

  8. G.X. Jin, L.J. Qiao and K.W. Gao, Effect of Mn and V on Hot Corrosion of TiAl Alloy, Acta Metall. Sin., 2004, 40, p 179–184.

    CAS  Google Scholar 

  9. W. Gao, K. Zhang and J. Liang, Molten Salt Vapour Corrosion of Ti-Al-Ag Intermetallics, Intermetallics, 2004, 12, p 539–544.

    Article  Google Scholar 

  10. B.L. Rem, Q. Miu, W.P. Liang, J.J. Xia and R.Y. Hu, Effects of NaCl Salt on Hot Corrosion Behaviors of Aluminized Layer Prepared on Ti2AlNb Alloy, Chin. Surf. Eng., 2016, 29, p 41–47.

    Google Scholar 

  11. B.L. Ren, W.P. Liang, Q. Miu, W. Liu, W.B. Chen, J.J. Xia and Y. Huang, Thermal Corrosion Resistance of Ti2AlNb Alloy Surface Deposited with Al Coating, J. Mater. Prot., 2016, 49, p 1–4.

    Google Scholar 

  12. M.P. Bacos, M. Thomas, J.L. Raviart, A. Morel, S. Mercier and P. Josso, Influence of an Oxidation Protective Coating upon Hot Corrosion and Mechanical Behaviour of Ti-48Al-2Cr-2Nb Alloy, Intermetallics, 2011, 19, p 1120–1129.

    Article  CAS  Google Scholar 

  13. Y.J. Xi, Y.J. Liu, Z.X. Wang and J.B. Lu, Effect of TiAl Coating on Hot Corrosion Protection of Ti3Al Alloy, Nonferrous Met. (Extractive Metallurgy), 2011, 6, p 29–32.

    Google Scholar 

  14. Z.J. Tian, X.S. Gao, Y.H. Huang, Z.D. Liu, D.L. Shen and D.S. Wang, Study on Hot Corrosion Behavior of Plasma-Sprayed NiCoCrAl-Y2O3 Coating on TiAl Alloy Surface, Rare Met. Mater. Eng., 2010, 39, p 1439–1442.

    CAS  Google Scholar 

  15. Z.L. Tang, F.H. Wang and W.T. Wu, Effect of Al2O3 and Enamel Coatings on 900 °C Oxidation and Hot Corrosion Behaviors of Gamma-TiAl, Mater. Sci. Eng. A, 2000, 1, p 70–75.

    Article  Google Scholar 

  16. C.H. Guan, Z.L. Tang and F.H. Wang, Effect of Enamel Coating on Oxidation and Hot Corrosion Resistance of Ti-24Al-14Nb-3V, Chin. J. Mater. Res., 2000, 14, p 75–80.

    Google Scholar 

  17. X.X. Ma, Y.H. He, J.P. Lin, D.R. Wang and J. Zhang, Effect of a Magnetron Sputtered (Al2O3–Y2O3)/(Pt–Au) Laminated Coating on Hot Corrosion Resistance of 8Nb-TiAl Alloy, Surf. Coat. Technol., 2012, 206, p 2690–2697.

    Article  CAS  Google Scholar 

  18. Z.L. Tang, F.H. Wang and W.T. Wu, Effect of a Sputtered TiAlCr Coating on Hot Corrosion Resistance of Gamma-TiAl, Intermetallics, 1999, 7, p 1271–1274.

    Article  CAS  Google Scholar 

  19. X.Y. Lu, D.Q. Yu, S.M. Jiang, S.C. Liu, J. Gong and C. Sun, Hot Corrosion Behavior of a (NiCoCrAlYSiB + AlSiY) Composite Coating, Acta Metall. Sin., 2012, 48, p 461–468.

    Article  CAS  Google Scholar 

  20. P. Zhang and X.P. Guo, Effect of Al Content on the Structure and Oxidation Resistance of Y and Al Modified Silicide Coatings Prepared on Nb-Ti-Si Based Alloy, Corros. Sci., 2013, 71, p 10–19.

    Article  CAS  Google Scholar 

  21. X.Q. Xie, X. Li, W. Lv, S. Lai, Y. Liu, J.J. Li and W.L. Xie, Effect of Co on Microstructure and High Temperature Oxidation Resistance of Ti45Al-8Nb-03Y Alloy, J. Mater. Eng., 2022, 50, p 101–108.

    Google Scholar 

  22. Y.Q. Li, F.Q. Xie and X.Q. Wu, Microstructure and High Temperature Oxidation Resistance of Si-Y Co-deposition Coatings Prepared on TiAl Alloy by Pack Cementation Process, Trans. Nonferrous Met. Soc. China, 2015, 25, p 803–810.

    Article  CAS  Google Scholar 

  23. P. Zhang and X.P. Guo, A comparative Study of Two Kinds of Y and Al Modified Silicide Coatings on an Nb-Ti-Si Based Alloy Prepared by Pack Cementation Technique, Corros. Sci., 2011, 53, p 4291–4299.

    Article  CAS  Google Scholar 

  24. Y.Q. Li, J.L. Li, C. Qin, L. Jiang and G.H. Geng, Microstructure and Hot Corrosion Behavior of Al-Ce-Y Coatings on DZ125 Nickel-Based Alloy Prepared by Pack Cementation Process, J. Cent. South Univ., 2020, 27, p 381–387.

    Article  CAS  Google Scholar 

  25. M. Qiao and C.G. Zhou, Hot Corrosion Behavior of Co Modified NiAl Coating on Nickel Base Superalloys, Corros. Sci., 2012, 63, p 239–245.

    Article  CAS  Google Scholar 

  26. G.L. Chen, X.T. Wang, S.M. Hao and J.J. Ding, Investigation on the 1000, 1150 and 1400 °C Isothermal Section of the Ti-Al-Nb System, Intermetallics, 1996, 4, p 13–22.

    Article  CAS  Google Scholar 

  27. W.Y. Zhao, B.W. Xu, Y. Ma and S.K. Gong, Inter-Phase Selective Corrosion of γ-TiAl Alloy in Molten Salt Environment at High Temperature, Prog. Nat. Sci. Mater. Int., 2011, 21, p 322–329.

    Article  Google Scholar 

  28. Y. Li, J.T. Guo, C. Yuan, H.C. Yang, N. Xu and Z.M. Shen, Hot Corrosion of Nickel-Base Superalloy K35 at 800 °C, J. Chin. Soc. Corros. Prot., 2005, 25, p 250–255.

    CAS  Google Scholar 

  29. N. Eliaz, G. Shemesh and R.M. Latanision, Hot Corrosion in Gas Turbine Components, Eng. Fail. Anal., 2002, 9, p 31–43.

    Article  CAS  Google Scholar 

  30. N.S. Bornstein and M.A. Decrescente, The Role of Sodium in the Accelerated Oxidation Phenomenon Termed Sulfidation, Metall. Trans., 1971, 2, p 2875–2883.

    Article  CAS  Google Scholar 

  31. D.L. Guan, H.Z. Lu, Y.T. Xiao and C.X. Shi, The Effect of Cobalt on the Hot Corrosion Behavior of Ni-Base Superalloys, J. Chin. Soc. Corros. Protect., 1981, 1, p 49–60.

    Google Scholar 

  32. Z.L. Tang, F.H. Wang and W.T. Wu, Hot Corrosion Behavior of TiAl Intermetallics in Molten Salts, J. Chin. Soc. Corros. Prot., 1997, 17, p 233–236.

    CAS  Google Scholar 

  33. G.X. Jin, J.X. Li, H.B. Qi, L.J. Qiao and K.W. Gao, Investigation of Hot Corrosion of (Al, Mn)3Ti-2V Intermetallics, Acta Metall. Sin., 2004, 40, p 185–190.

    CAS  Google Scholar 

  34. H.Y. He, Z.J. Liu, W. Wang and C.G. Zhou, Microstructure and Hot Corrosion Behavior of Co-Si Modified Aluminide Coating on Nickel Based Superalloys, Corros. Sci., 2015, 100, p 466–473.

    Article  CAS  Google Scholar 

  35. Z. Yao and M. Marck, NaCl-Induced Hot Corrosion of a Titanium Aluminide Alloy, Mater. Sci. Eng. A, 1995, 192, p 994–1000.

    Article  Google Scholar 

  36. Z.X. Shi, S.Z. Liu and J.R. Li, Effect of Yttrium on Gas Hot Corrosion Resistance of Single Crystal Superalloy, Chin. Rare Earths, 2016, 37, p 81–85.

    Google Scholar 

  37. V. Babic, C. Geers and I. Panas, Reactive Element Effects in High-Temperature Alloys Disentangled, Oxid. Met., 2020, 93, p 229–245.

    Article  CAS  Google Scholar 

  38. H.X. Li, M. Qiao and C.G. Zhou, Formation and Cyclic Oxidation Resistance of Hf-Co-Modified Aluminide Coatings on Nickel Base Superalloys, Mater. Chem. Phys., 2014, 143, p 915–920.

    Article  CAS  Google Scholar 

  39. M. Qiao and C.G. Zhou, Codeposition of Co-Al-Y on Nickel Base Superalloys by Pack Cementation Process, Corros. Sci., 2013, 75, p 454–460.

    Article  CAS  Google Scholar 

  40. X.S. Zhao and C.G. Zhou, Effect of Y2O3 Content in the Pack on Microstructure and Hot Corrosion Resistance of Y-Co-modified Aluminide Coating, Corros. Sci., 2014, 86, p 223–230.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 51961003), the Major Project of Science and Technology Department of Sichuan province (No. 2022YFSY0036), the Major Project of Science and Technology Department of Shaanxi Province (No. 2020GY-324), the Project of Science and Technology Department of Yibin (No. 2021GY-006), the Project of Yibin Vocational and Technical College (YBZYSC18-12, ZRKY21ZD-09), and the Project of the Key Laboratory of Mechanical Structure Optimization & Material Application Technology of Luzhou (SCHYZSA-2022-01, SB-2022-01, SCHYZSB-2022-02)

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xuan Li.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wei, Z., Li, X., Lv, W. et al. Structure and Hot Corrosion Behavior of an Al-Co-Y Co-deposited Coating on TiAl Alloy. J. of Materi Eng and Perform 32, 4796–4806 (2023). https://doi.org/10.1007/s11665-022-07481-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-022-07481-1

Keywords

Navigation