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High Temperature Corrosion Performance of HVOF and D-gun Formulated Cr3C2-NiCr and Rare Earth Element Doped Cr3C2-NiCr Coating on TP347H Austenite Steel

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Abstract

The present research evaluates the microstructure and hot corrosion performance of HVOF and D-gun sprayed Cr3C2-25NiCr, and ceria (0.4 wt.%) blended Cr3C2-25NiCr coatings on TP347H superheater tube material. All the specimens were subjected to Na2SO4-60%V2O5 environment for 50 cycles at 900 °C. The corroded samples were evaluated using thermogravimetric analysis, XRD, scanning electron microscopy with energy dispersive spectroscopy, and x-ray mapping. Moreover, the weight gain versus oxidation time and oxide scale growth rate was subsequently examined. Microstructural results revealed that the ceria-added coating with the D-gun method provided better coating features, such as microhardness, surface roughness, and microporosity than its counterparts. Among the four coatings, D-gun sprayed Ce 0.4 wt.% added Cr3C2-25NiCr coating (D2) proved to be better due to the thin and dense oxide scale of Cr2O3, Cr23C6, NiCr2O4, Ce2O3, and CeVO4. Moreover, the presence of ceria in the carbide coating reduces the development of the NiCr2O4 phase resulting in compact oxide scale of Cr2O3 developed on the coating surface.

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  1. Yadavindra Department of Engineering, Punjabi University Guru Kashi Campus, Talwandi Sabo, Punjab, 151302, India

    Harkulvinder Singh & Sukhpal Singh Chatha

  2. Maharaja Ranjit Singh Punjab Technical University, Bathinda, Punjab, 151001, India

    Buta Singh Sidhu

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Singh, H., Chatha, S.S. & Sidhu, B.S. High Temperature Corrosion Performance of HVOF and D-gun Formulated Cr3C2-NiCr and Rare Earth Element Doped Cr3C2-NiCr Coating on TP347H Austenite Steel. J Fail. Anal. and Preven. (2024). https://doi.org/10.1007/s11668-024-01932-8

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