Skip to main content
Log in

Thermophysical Properties of a New HPDC Mg–RE-Based Alloy: Comparative Study to Conventional AE44 Alloy

  • Original Research Article
  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

In this work, the thermophysical properties of a novel high pressure die casting (HPDC) Mg–RE (Mg–6Y–3Zn–1Al, WZA631 in wt pct) alloy are well investigated at the range of 298–673 K, compared with common HPDC AE44 alloy. Results show that the thermal expansion coefficients and thermal conductivity of AE44 and WZA631 alloys have similar temperature dependence, i.e., their values increase with temperature. At the same condition, the AE44 alloy exhibits higher thermal conductivity, while the WZA631 alloy has a lower expansion coefficient (better thermal stability). The lower thermal expansion coefficient of the WZA631 alloy is associated with the improved matrix deformability due to Y atoms and the strong barrier effect provided by the uniformly distributed long period stacking ordered (LPSO) phase. For the higher thermal conductivity of the AE44 alloy, trace cell boundary defects and solute-induced weak lattice distortions are major contributors. The numerical thermal conductivity models for both alloys are established based on Matthiessen’s rule, which presents reasonable consistency with experimental data, having correlation factors of R2 = 0.99. Also, with respect to some available gravity casting/die casting Mg alloys, the developed die casting WZA631 alloy demonstrates great merits from aspects of thermophysical properties, strength, and plasticity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. L. Ye, Y. Liu, D.S. Zhao, Y.L. Zhuang, S.B. Gao, X.Q. Liu, J.P. Zhou, J.N. Gui, and J.B. Wang: Mater. Sci. Eng. A, 2018, vol. 724, pp. 121–30.

    Article  CAS  Google Scholar 

  2. V.E. Bazhenov, A.V. Koltygin, M.C. Sung, S.H. Park, Y.V. Tselovalnik, A.A. Stepashkin, A.A. Rizhsky, M.V. Belov, V.D. Belov, and K.V. Malyutin: J. Magnes. Alloys, 2021, vol. 9, pp. 1567–77.

    Article  CAS  Google Scholar 

  3. Y.F. Liu, X.G. Qiao, Z.T. Li, Z.H. Xia, and M.Y. Zheng: J. Alloy. Compd., 2020, vol. 830, p. 154570.

    Article  CAS  Google Scholar 

  4. L. Liu, X. Chen, J. Wang, L. Qiao, S. Gao, K. Song, C. Zhao, X. Liu, D. Zhao, and F. Pan: J. Mater. Sci. Technol., 2019, vol. 35, pp. 1074–80.

    Article  CAS  Google Scholar 

  5. Y. Bai, B. Ye, L. Wang, B. Zhao, X. Yu, Y. Lu, X. Kong, and W. Ding: Mater. Sci. Eng. A, 2021, vol. 802, p. 140655.

    Article  CAS  Google Scholar 

  6. T. Ying, H. Chi, M. Zheng, Z. Li, and C. Uher: Acta Mater., 2014, vol. 80, pp. 288–95.

    Article  CAS  Google Scholar 

  7. Z. Wu, R. Ahmad, B. Yin, S. Sandlöbes, and W.A. Curtin: Science, 2018, vol. 359, pp. 447–52.

    Article  CAS  Google Scholar 

  8. C. Su, D. Li, J. Wang, R. Shi, A.A. Luo, X. Zeng, Z. Lin, and J. Chen: Mater. Sci. Eng. A, 2020, vol. 773, p. 138870.

    Article  CAS  Google Scholar 

  9. S. Li, X. Yang, J. Hou, and W. Du: J. Magnes. Alloys, 2020, vol. 8, pp. 78–90.

    Article  CAS  Google Scholar 

  10. G. Li, J. Zhang, R. Wu, Y. Feng, S. Liu, X. Wang, Y. Jiao, Q. Yang, and J. Meng: J. Mater. Sci. Technol., 2018, vol. 34, pp. 1076–84.

    Article  CAS  Google Scholar 

  11. T. Ying, M.Y. Zheng, Z.T. Li, X.G. Qiao, and S.W. Xu: J. Alloys Compd., 2015, vol. 621, pp. 250–55.

    Article  CAS  Google Scholar 

  12. T. Ying, M.Y. Zheng, Z.T. Li, and X.G. Qiao: J. Alloys Compd., 2014, vol. 608, pp. 19–24.

    Article  CAS  Google Scholar 

  13. C.J. Chen, Q.D. Wang, and D.D. Yin: J. Alloys Compd., 2009, vol. 487, pp. 560–63.

    Article  CAS  Google Scholar 

  14. J. Peng, L. Zhong, Y. Wang, J. Yang, Y. Lu, and F. Pan: J. Alloys Compd., 2015, vol. 639, pp. 556–62.

    Article  CAS  Google Scholar 

  15. M. Yamasaki and Y. Kawamura: Scr. Mater., 2009, vol. 60, pp. 264–67.

    Article  CAS  Google Scholar 

  16. T. Guo, S. Wu, X. Zhou, S. Lü, and L. Xia: Mater. Chem. Phys., 2020, vol. 253, p. 123260.

    Article  CAS  Google Scholar 

  17. H. Ma, Z. Li, and J. Wang: Mater. Res. Express, 2021, vol. 8, p. 076518.

    Article  CAS  Google Scholar 

  18. H. Pan, F. Pan, R. Yang, J. Peng, C. Zhao, J. She, Z. Gao, and A. Tang: J. Mater. Sci., 2014, vol. 49, pp. 3107–24.

    Article  CAS  Google Scholar 

  19. L. Zhong, Y. Wang, M. Gong, X. Zheng, and J. Peng: Mater. Charact., 2018, vol. 138, pp. 284–88.

    Article  CAS  Google Scholar 

  20. L. Zhong, J. Peng, S. Sun, Y. Wang, Y. Lu, and F. Pan: J. Mater. Sci. Technol., 2017, vol. 33, pp. 1240–48.

    Article  CAS  Google Scholar 

  21. C. Su, D. Li, T. Ying, L. Zhou, L. Li, and X. Zeng: J. Alloys Compd., 2016, vol. 685, pp. 114–21.

    Article  CAS  Google Scholar 

  22. H. Li, X. Zhu, Y. Zhang, W. Tang, D. Ma, J. Wang, and Q. Chen: JOM, 2019, vol. 72, pp. 1580–88.

    Article  Google Scholar 

  23. W. Zhang, M. Ma, J. Yuan, G. Shi, Y. Li, X. Li, and K. Zhang: Trans. Nonferrous Met. Soc. China, 2020, vol. 30, pp. 1803–15.

    Article  CAS  Google Scholar 

  24. Y.F. Liu, X.J. Jia, X.G. Qiao, S.W. Xu, and M.Y. Zheng: J. Alloys Compd., 2019, vol. 806, pp. 71–78.

    Article  CAS  Google Scholar 

  25. J. Peng, L. Zhong, Y. Wang, Y. Lu, and F. Pan: Mater. Des., 2015, vol. 87, pp. 914–19.

    Article  CAS  Google Scholar 

  26. J. Yuan, K. Zhang, X. Zhang, X. Li, T. Li, Y. Li, M. Ma, and G. Shi: J. Alloys Compd., 2013, vol. 578, pp. 32–36.

    Article  CAS  Google Scholar 

  27. L.F. Hu, Q.F. Gu, Q. Li, J.Y. Zhang, and G.X. Wu: J. Alloys Compd., 2018, vol. 741, pp. 1222–28.

    Article  CAS  Google Scholar 

  28. G. Yuan, G. You, S. Bai, and W. Guo: J. Alloys Compd., 2018, vol. 766, pp. 410–16.

    Article  CAS  Google Scholar 

  29. J. Rong, W. Xiao, X. Zhao, Y. Fu, H. Liao, C. Ma, M. Chen, and C. Huang: J. Alloys Compd., 2022, vol. 896, p. 162943.

    Article  CAS  Google Scholar 

  30. Y. Ming, G. You, X. Xu, H. Wen, and J. Zhao: Metall. Mater. Trans. A, 2019, vol. 50, pp. 5969–76.

    Article  CAS  Google Scholar 

  31. C. Su, D. Li, A.A. Luo, R. Shi, and X. Zeng: Metall. Mater. Trans. A, 2019, vol. 50, pp. 1970–84.

    Article  CAS  Google Scholar 

  32. W. Yue, L. Jianping, Y. Zhong, G. Yongchun, M. Zhijun, L. Minxian, Y. Tong, and T. Dong: Metall. Mater. Trans. A, 2019, vol. 50, pp. 3697–3704.

    Article  CAS  Google Scholar 

  33. Q. Yang, K. Guan, F. Bu, Y. Zhang, X. Qiu, T. Zheng, X. Liu, and J. Meng: Mater. Charact., 2016, vol. 113, pp. 180–88.

    Article  CAS  Google Scholar 

  34. L.N. Zhang, R. Jia, D. Li, W. Zhang, and F. Guo: J. Mater. Sci. Technol., 2015, vol. 31, pp. 504–11.

    Article  CAS  Google Scholar 

  35. C.Y. Jiang, X.Q. Li, B. Wan, D.Z. Zhu, S.G. Qu, and C. Yang: Intermetallics, 2022, vol. 142, p. 107468.

    Article  CAS  Google Scholar 

  36. D.D. Yin, Q.D. Wang, Y. Gao, C.J. Chen, and J. Zheng: J. Alloys Compd., 2011, vol. 509, pp. 1696–1704.

    Article  CAS  Google Scholar 

  37. Y.M. Zhu, A.J. Morton, and J.F. Nie: Acta Mater., 2010, vol. 58, pp. 2936–47.

    Article  CAS  Google Scholar 

  38. J. Hao, J. Zhang, B. Li, and R. Xie: Mater. Sci. Eng. A, 2021, vol. 804, p. 140727.

    Article  CAS  Google Scholar 

  39. R. Przeliorz, M. Goral, G. Moskal, and L. Swadzba: J. Achiev. Mater. Manuf. Eng., 2007, vol. 21, pp. 48–50.

    Google Scholar 

  40. A.V. Granato, D.M. Joncich, and V.A. Khonik: Appl. Phys. Lett., 2010, vol. 97, 171911.

    Article  Google Scholar 

  41. W.A. Uju and I.N.A. Oguocha: Mater. Des., 2012, vol. 33, pp. 503–09.

    Article  CAS  Google Scholar 

  42. T. Jiang, C. Yu, B. Xu, H. Cheng, and G. Xu: J. Mater. Sci.: Mater. Electron., 2019, vol. 30, pp. 19362–73.

    CAS  Google Scholar 

  43. R.K. Sabat, A.P. Brahme, R.K. Mishra, K. Inal, and S. Suwas: Acta Mater., 2018, vol. 161, pp. 246–57.

    Article  CAS  Google Scholar 

  44. M. Watanabe, M. Adachi, M. Uchikoshi, and H. Fukuyama: Metall. Mater. Trans. A, 2019, vol. 50, pp. 3295–3300.

    Article  CAS  Google Scholar 

  45. Y. Wang and J. Zhao: J. Nucl. Mater., 2020, vol. 529, p. 151931.

    Article  CAS  Google Scholar 

  46. M.C. Karamargin, C.A. Reynolds, F.P. Lipschultz, and P.G. Klemens: Phys. Rev. B, 1972, vol. 6, pp. 3624–33.

    Article  CAS  Google Scholar 

  47. G. Wang and Y. Li: J. Appl. Phys., 2019, vol. 126, p. 125118.

    Article  Google Scholar 

  48. Y. Bai, B. Ye, J. Guo, L. Wang, X. Kong, and W. Ding: Mater. Charact., 2020, vol. 164, p. 110301.

    Article  CAS  Google Scholar 

  49. V.E. Bazhenov, A.V. Koltygin, M.C. Sung, S.H. Park, A.Y. Titov, V.A. Bautin, S.V. Matveev, M.V. Belov, V.D. Belov, and K.V. Malyutin: J. Magnes. Alloys, 2020, vol. 8, pp. 184–91.

    Article  CAS  Google Scholar 

  50. X. Wu, C. Xu, Z. Zhang, W. Yang, J. Zhang, and W. Zhang: Adv. Eng. Mater., 2020, vol. 22, p. 1900964.

    Article  CAS  Google Scholar 

  51. E. Zhang, D. Yin, L. Xu, L. Yang, and K. Yang: Mater. Sci. Eng. C, 2009, vol. 29, pp. 987–93.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Key Research and Development Program of China [Grant Numbers 2016YFB0301001 and 2016YFB0700502]. The authors also thank Prof. Shoumei Xiong from the School of Materials Science and Engineering, Tsinghua University, for his help in alloy preparation and data processing.

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bing Ye.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bai, Y., Ye, B., Yu, X. et al. Thermophysical Properties of a New HPDC Mg–RE-Based Alloy: Comparative Study to Conventional AE44 Alloy. Metall Mater Trans A 53, 4258–4271 (2022). https://doi.org/10.1007/s11661-022-06820-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-022-06820-0

Navigation