Abstract
The effect of Cr on the kinetics of ferrite growth from austenite was studied using the technique of controlled decarburization over the temperature range 850 °C to 775 °C. At 850 °C, the observed ferrite growth kinetics is in excellent agreement with the predictions of the local equilibrium negligible partition (LENP) model. At temperatures below 850 °C, the growth kinetics becomes increasingly slower than the predictions of the LENP model. This was interpreted in terms of the solute-drag effect of Cr, and the cross-boundary diffusion coefficient of Cr was estimated.
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H.K.D.H. Bhadeshia: Prog. Mater. Sci., 1985, vol. 29, pp. 321–86
A. Van der Ven, L. Delaey: Prog. Mater. Sci., 1996, vol. 40, pp. 181–264
G.R. Purdy, J.S. Kirkaldy: Trans. AIME, 1963, vol. 227, pp. 1255–66
S. Crusius, L. Hoglund, U. Knoop, G. Inden, J. Ågren: Z. Metallkd., 1992, vol. 83, pp. 729–38
Available from Thermo-Calc Software, http://www.thermocalc.com
J. Ågren: Acta Metall., 1982, vol. 30, pp. 841–51
J. Ågren: Scripta Metall., 1986, vol. 20, pp. 1507–10
G.R. Purdy, D.H. Weichert, J.S. Kirkaldy: Trans. AIME, 1964, vol. 230, pp. 1025–34
H.I. Aaronson, H.A. Domian: Trans. AIME, 1966, vol. 236, pp. 781–96
J.B. Gilmour, G.R. Purdy, J.S. Kirkaldy: Metall. Trans., 1972, vol. 3, pp. 3213–22
M. Hillert: “Paraequilibrium,” Internal Report, Swedish Institute of Metals, Stockholm, Sweden, 1953
J.S. Kirkaldy: Can. J. Phys., 1958, vol. 36, pp. 907–17
M. Hillert: The Mechanism of Phase Transformation in Crystalline Solids, Institute of Metals, London, 1969, pp. 231–47
A. Phillion, H.S. Zurob, C.R. Hutchinson, H. Guo, D.V. Malakhov, J. Nakano, G.R. Purdy: Metall. Mater. Trans. A, 2004, vol. 35A, pp. 1237–42
C.R. Hutchinson, H.S. Zurob, Y. Brechet: Metall. Mater. Trans. A, 2006, vol. 37A, pp. 1711–20
H.S. Zurob, C.R. Hutchinson, Y. Bréchet, and G.R. Purdy: in Solid-Solid Phase Transformations in Inorganic Materials, TMS, Warrendale, PA, 2005, pp. 111–16
W.D. Murry, F. Landis: Trans. ASME, 1959, vol. 81D, pp. 106–12
B. Jönsson: Z. Metallkd., 1992, vol. 83, pp. 349–55
J.W. Cahn: Acta Metall., 1962, vol. 10, pp. 789–98
M. Hillert, B. Sundman: Acta Metall., 1976, vol. 24, pp. 731–43
G.R. Purdy, Y.J.M. Brechet: Acta Metall. Mater., 1995, vol. 43, pp. 3763–74
C.R. Hutchinson, A. Fuchsmann, Y. Brechet: Metall. Mater. Trans. A, 2004, vol. 35A, pp. 1211–21
E.D. Hondros, M.P. Seah: Int. Met. Rev., 1977, vol. 22, pp. 262–301
Smithells Metals Reference Book, 8th ed., W.F. Gale and T.C. Totemeier, eds., Elsevier, New York, NY, 2004
P. Maugis, G. Martin: Phys. Rev. B: Condens. Matter Mater. Phys., 1994, vol. 49, pp. 11580–87
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One of the authors (HSZ) gratefully acknowledges the financial support of the Natural Science and Engineering Research Council of Canada.
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Manuscript submitted March 1, 2007.
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Béché, A., Zurob, H. & Hutchinson, C. Quantifying the Solute Drag Effect of Cr on Ferrite Growth Using Controlled Decarburization Experiments. Metall Mater Trans A 38, 2950–2955 (2007). https://doi.org/10.1007/s11661-007-9353-9
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DOI: https://doi.org/10.1007/s11661-007-9353-9