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3D sandwich-like frameworks constructed from silver chains: synthesis and crystal structures of six silver(I) coordination complexes

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Abstract

The reaction of AgNO3 with combinations of 4,4′-bipyridine (bpy), 1,2-di(4-pyridyl)ethane (dpe), 1,3-bis(4-pyridyl)propane (bpp), succinic acid (H2su), terephthalic acid (H2tp), 2,2′-diphenylaminedicarboxylic acid (H2dpadc), and naphthaleneacetic acid (Hnaa) in aqueous alcohol at room temperature produces block-like crystals of [Ag3(bpy)3](su)·10H2O, [Ag2(bpy)2](tp)·6H2O, [Ag2(dpe)2(H2O)2](dpadc)·H2O, [Ag6(dpe)6(H2O)4](tp)3·12H2O, [Ag(bpp)](naa), and [Ag2(bpp)2](dpadc)·6H2O. All six compounds consist of 1D infinite silver-bpy/dpe/bpp cationic chains, interspersed with organic carboxylate anions that provide charge compensation in the crystal structures. The lattice water molecules are situated among the framework of the crystal structure and show rich hydrogen-bonding interactions {except for [Ag(bpp)](naa)}, which help to orientate of the organic carboxylate anions in the crystal packing.

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Acknowledgments

The study was financially supported by Funding Project for Academic Human Resources Development in Institutions of Higher Learning Under the Jurisdiction of Beijing Municipality (Grant No. PHR201008372 and PHR201106124) and Open Research Fund Program of Key Laboratory of Urban Stormwater System and Water Environment (Ministry of Education), Beijing University of Civil Engineering and Architecture (Grant No. YH201101003).

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Authors and Affiliations

  1. Key Laboratory of Urban Stormwater System and Water Environment (Ministry of Education), Beijing University of Civil Engineering and Architecture, Beijing, 100044, China

    Chong-chen Wang, Peng Wang & Guang-Liang Guo

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  1. Chong-chen Wang
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  2. Peng Wang
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  3. Guang-Liang Guo
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Correspondence to Chong-chen Wang.

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Wang, Cc., Wang, P. & Guo, GL. 3D sandwich-like frameworks constructed from silver chains: synthesis and crystal structures of six silver(I) coordination complexes. Transition Met Chem 37, 345–359 (2012). https://doi.org/10.1007/s11243-012-9595-2

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  • DOI: https://doi.org/10.1007/s11243-012-9595-2

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