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New coordination polymers of silver(I) based on dodecahydro-closo-dodecaborate anion: Synthesis and structure

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Abstract

It has been demonstrated that the reaction of Cat[Ag[B12H12]] or [Ag2[B12H12]] with chelating ligands L (L = bipy, phen) leads to the selective formation of stable [(Ag2(L)2[B12H12]] n 1D polymers irrespective of the nature of cation (Cat) in the starting reagent, the ratio of the reaction components, and the solvent used. The structures of [Ag2(bipy)2[B12H12]] n · 2CH3CN and [Ag2(phen)2[B12H12]] n · DMF have been determined by X-ray crystallography. It has been demonstrated that the [B12H12]2− anion in polymer chains acts as a bridging ligand coordinated to silver atoms through edges or through an edge and a vertex of the icosahedron. The Ag–B(H) and Ag–H(B) distances are within 2.638(3)–3.074(3) and 1.90–2.80 Å, respectively. These complexes are the first examples of 1D coordination polymers based on the [B12H12]2− anion and azaheterocyclic ligands L.

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References

  1. Malinina, E.A., Avdeeva, V.V., Goeva, L.V., Polyakova, I.N., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2011, vol. 56. No. 5, pp. 687–697.

    Article  CAS  Google Scholar 

  2. Goeva, L.V., Skachkova, V.K., Avdeeva, V.V., Malinina, E.A., Grachev, A.V., Shaulov, A.Yu., Berlin, A.A., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2014, vol. 59, no. 2, pp. 107–110.

    Article  CAS  Google Scholar 

  3. Skachkova, V.K., Goeva, L.V., Grachev, A.V., Avdeeva, V.V., Malinina, E.A., Shaulov, A.Yu., Berlin, A.A., and Kuznetsov, N.T., Inorg. Mater., 2015, vol. 51, no. 5, pp. 498–502.

    Article  CAS  Google Scholar 

  4. Skachkova, V.K., Goeva, L.V., Grachev, A.V., Avdeeva, V.V., Malinina, E.A., Shaulov, A.Yu., Berlin, A.A., and Kuznetsov, N.T., Inorg. Mater., 2015, vol. 51, no. 7, pp. 736–740.

    Article  CAS  Google Scholar 

  5. Goeva, L.V., Malinina, E.A., Avdeeva, V.V., Kuznetsov, N.T., Skachkova, V.K., Grachev, A.V., Shaulov, A.Yu., and Berlin, A.A., Patent RF2550156, Byul. Izobret., 2015.

  6. Drozdova, V.V., Malinina, E.A., Belousova, O.N., Polyakova, I.N., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2008, vol. 53, no. 7, pp. 1024–1033.

    Article  Google Scholar 

  7. Volkov, O., Hu, Ch., and Paetzold, P., Z. Anorg. Allg. Chem., 2005, vol. 631, no. 6/7, pp. 1107–1112.

    Article  CAS  Google Scholar 

  8. Avdeeva, V.V., Malinina, E.A., Belousova, O.N., Goeva, L.V., Polyakova, I.N., and Kuznetsov, N.T., Russ. J. Inorg. Chem., 2011, vol. 56, no. 4. pp. 524–529.

    Article  CAS  Google Scholar 

  9. Bruker AXS, Inc., Madison, Wis, 2008/2009.

  10. Sheldrick, G.M., Acta Crystallogr. Sect. A, 2008, vol. 64, no. 1, pp. 112–122.

    Article  CAS  Google Scholar 

  11. Altomare, A., Cascarano, G., Giacovazzo, C., and Guagliardi, A., J. Appl. Cryst., 1993, vol. 26, pp. 343–350.

    Article  Google Scholar 

  12. Sheldrick, G.M., Acta Crystallogr., Sect. C, 2015, vol. 71, no. 1, pp. 3–8.

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    I. K. Kochneva, I. N. Polyakova, L. V. Goeva, V. V. Avdeeva, E. A. Malinina & N. T. Kuznetsov

Authors
  1. I. K. Kochneva
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  2. I. N. Polyakova
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  3. L. V. Goeva
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  4. V. V. Avdeeva
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  5. E. A. Malinina
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  6. N. T. Kuznetsov
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Corresponding authors

Correspondence to V. V. Avdeeva or E. A. Malinina.

Additional information

Original Russian Text © I.K. Kochneva, I.N. Polyakova, L.V. Goeva, V.V. Avdeeva, E.A. Malinina, N.T. Kuznetsov, 2017, published in Doklady Akademii Nauk, 2017, Vol. 475, No. 5, pp. 524–527.

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Kochneva, I.K., Polyakova, I.N., Goeva, L.V. et al. New coordination polymers of silver(I) based on dodecahydro-closo-dodecaborate anion: Synthesis and structure. Dokl Chem 475, 164–167 (2017). https://doi.org/10.1134/S0012500817080055

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  • DOI: https://doi.org/10.1134/S0012500817080055

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