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Influence of organic carboxylic acids on self-assembly of silver(I) complexes containing 1,2-bis(4-pyridyl)ethane ligands

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Abstract

Four silver(I) complexes, namely [Ag2(bpe)2](bdc)·8H2O (1), [Ag2(bpe)2(da)]·4H2O (2), [Ag4(bpe)3(bptc)]·9H2O (3), and Ag(bpe)2(bpdc)2 (4), have been successfully synthesized by the reactions between AgNO3, 1,2-bis(4-pyridyl)ethane (bpe) and different carboxylic acids, including 1,3-benzenedicarboxylic acid (H2bdc), diphenic acid (H2da), 3,3′,4,4′-biphenyltetracarboxylic acid (H4bptc), and 2,2′-bipyridine-3,3′-dicarboxylic acid (H2bpdc). All four compounds were characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. In (1), the Ag(I) atoms, in linear geometry, are joined into 1-D infinite cationic bpe-silver chains, and discrete bdc2− anions compensate the charge of the crystal structure. In (2), the Ag(I) atoms, adopting tetrahedral and trigonal geometries, are linked by bpe and da2− ligands into neutral double chains. In (3), the Ag(I) atoms, in T-shaped and linear environments, are coordinated by bpe and multidentate bptc4− ligands to construct a 2-D network. And in (4), the Ag(I) atoms, with trigonal and T-shaped coordination geometries, are coordinated by bpe and bpdc2− ligands to build up a 3-D framework. The different anions play different and important roles in directing the final crystal structures.

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Acknowledgments

The study was financially supported by Funding Project for Academic Human Resources Development in Institutions of Higher Learning Under the Jurisdiction of Beijing Municipality (Grant No. PHR201008372 and PHR201106124) and Open Research Fund Program of Key Laboratory of Urban Stormwater System and Water Environment (Beijing University of Civil Engineering and Architecture), Ministry of Education (Grant No. YH201101003).

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  1. Key Laboratory of Urban Stormwater System and Water Environment (Ministry of Education), Beijing University of Civil Engineering and Architecture, Beijing, 100044, China

    Chong-chen Wang, Peng Wang & Li–li Feng

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  1. Chong-chen Wang
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  2. Peng Wang
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Correspondence to Chong-chen Wang.

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Wang, Cc., Wang, P. & Feng, L. Influence of organic carboxylic acids on self-assembly of silver(I) complexes containing 1,2-bis(4-pyridyl)ethane ligands. Transition Met Chem 37, 225–234 (2012). https://doi.org/10.1007/s11243-012-9582-7

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  • DOI: https://doi.org/10.1007/s11243-012-9582-7

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