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Synthesis and crystal structures of four mixed-ligand silver(I) complexes with sandwich-like structure

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Abstract

The reaction of AgNO3, with combinations of 4,4′-bipyridine (bpy), 1,2-di(4-pyridyl)ethylene (dpe), hexanedioic acid (HA), pyridine-3,5-dicarboxylic acid (pdc) and 3,3′4,4′-biphenyltetracarboxylic acid (bptc) in aqueous alcohol at room temperature produces block-like crystals of [Ag2(bpy)2](HA)2·6H2O, [Ag2(bpy)2(H2O)](pdc)·3H2O, [Ag4(bpy)4](bptc)·14H2O and [Ag2(dpe)2(H2O)2](HA)·6H2O. All four compounds consist of parallel 1D infinite bpy/dpe-silver cationic chains, interspersed with organic anions that play the role of charge compensation in the crystal structure. The lattice water molecules are situated among the framework of the crystal structure and stabilized by rich hydrogen-bonding interactions, which may play a role in the orientation of the organic anions in the crystal packing.

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Acknowledgments

The study was financially supported by National Natural Science Foundation of China, Funding Project for Academic Human Resources Development in Institutions of Higher Learning Under the Jurisdiction of Beijing Municipality (Grant No. PHR201008372) and the Research Fund of Beijing University of Civil Engineering and Architecture (Grant No. 100902602).

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 100029, Beijing, China

    Chong-Chen Wang & Guang-Sheng Guo

  2. School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, 100044, Beijing, China

    Chong-Chen Wang & Peng Wang

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  1. Chong-Chen Wang
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  2. Peng Wang
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  3. Guang-Sheng Guo
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Corresponding authors

Correspondence to Chong-Chen Wang or Guang-Sheng Guo.

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Wang, CC., Wang, P. & Guo, GS. Synthesis and crystal structures of four mixed-ligand silver(I) complexes with sandwich-like structure. Transition Met Chem 35, 721–729 (2010). https://doi.org/10.1007/s11243-010-9385-7

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  • DOI: https://doi.org/10.1007/s11243-010-9385-7

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