Skip to main content
SpringerLink
Log in

Synthesis, spectral characterization, biological and fluorescence studies of lanthanum(III) complexes with 3-substituted-4-amino-5-hydrazino-1,2,4-triazole Schiff bases

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Some lanthanum(III) complexes have been synthesized by reacting lanthanum(III) nitrate with Schiff bases derived from 3-substituted-4-amino-5-hydrazino-1,2,4-triazole and substituted salicylaldehydes. All these complexes are soluble in DMF and DMSO and the low molar conductance values observed indicates that they are non-electrolytes. Elemental analyses suggest the complexes have 1:1 stoichiometry of the type La · L · NO3 · H2O, and they were characterized further by spectral and thermogravimetric methods. Fluorescence spectra of one of the representative Schiff bases (II) and its lanthanum(III) complex were investigated in various solvents; the complexes were evaluated for their biological activity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S.A. Patil B.M. Badiger S.M. Kudari V.H. Kulkarni (1983) Transition Met. Chem. 8 238 Occurrence Handle1:CAS:528:DyaL3sXmt1Cjtrc%3D Occurrence Handle10.1007/BF00620701

    Article  CAS  Google Scholar 

  2. B.M. Badiger S.A. Patil S.M. Kudari V.H. Kulkarni (1986) Rev. Roum. Chim. 31 849 Occurrence Handle1:CAS:528:DyaL2sXpsVyktw%3D%3D

    CAS  Google Scholar 

  3. A.Y. Naik S.D. Angadi V.H. Kulkarni (1994) Oriental J. Chem. 10 23 Occurrence Handle1:CAS:528:DyaK2MXps1ahsw%3D%3D

    CAS  Google Scholar 

  4. M.S. Yadawe S.A. Patil (1997) Transition Met. Chem. 22 220 Occurrence Handle1:CAS:528:DyaK2sXktF2mu7o%3D Occurrence Handle10.1023/A:1018400121316

    Article  CAS  Google Scholar 

  5. S.N. Dubey B. Kaushik (1985) Indian J. Chem. 24A 950 Occurrence Handle1:CAS:528:DyaL28Xhs1Sqs7k%3D

    CAS  Google Scholar 

  6. J.P. Corhnelissen J.H. Diemen ParticleVan L.R. Groeneveld J.G. Haasnoot A.L. Spek J. Reedisk (1992) Inorg. Chem. 31 198 Occurrence Handle10.1021/ic00028a014

    Article  Google Scholar 

  7. A.K. Sengupta O.P. Bajaj U. Chandra (1978) J. India Chem. Soc. 55 962 Occurrence Handle1:CAS:528:DyaE1MXnt1Wiug%3D%3D

    CAS  Google Scholar 

  8. H. Singh L.D.S. Yadav P.K. Bhattacharya (1979) J. Indian Chem. Soc. 56 1013 Occurrence Handle1:CAS:528:DyaL3cXlsFSitbY%3D

    CAS  Google Scholar 

  9. G. Tanara, Jpn, Kokai, 973, 7495 (1974). Chem. Abs., 82. 156320h (1975)

  10. S. Giri H. Singh L.D.S. Yadew (1978) J. Indian Chem. Soc. 55 168 Occurrence Handle1:CAS:528:DyaE1MXit12jtQ%3D%3D

    CAS  Google Scholar 

  11. R.K. Shikkargol N.N. Mallikarjuna K. Siddappa V.H. Kulkarni S.D. Angadi (2001) J. Indian Chem. Soc. 78 148 Occurrence Handle1:CAS:528:DC%2BD3MXivFOjtLs%3D

    CAS  Google Scholar 

  12. L. Misra A.K. Yadaw (2000) Indian J. Chem. 39A 660–663

    Google Scholar 

  13. (a) L.A. Sousa and J. M. Lasson, J. Am. Chem. Soc., 99 307 (1977); (b) A.W. Czarnik, Acc. Chem. Res., 279, 302 (1994)

  14. (a) J.P. Konopelski, F.K. Hibert, J.M. Lehn, J.P. Desvergne, F. Fages, A. castellan and H.B. Laurent, J. Chem. Soc. Chem. Commun., 433 (1985); (b) F. Fages, J.P. Desvergne, H.B. Laurent, J.M. Konopelski, P. Marsau and Y.J. Barrans, Chem. Soc. Chem. Commun., 655 (1990); (c) P. Ghosh, P.K. Bharadwaj, S. Mandal and S. Ghosh, J. Am. Chem. Soc., 118, 1553 (1996)

  15. (a) L.R. Sousa and J.M. Larson, J. Am. Chem. Soc., 99, 307 (1977); (b) S. Ghosh, M. Petrin, A.H. Maki and L.R. Sousa, J. Chem. Phys., 87, 4315 (1987)

  16. M.E. Hoston K.W. Haider A.W. Czarnik (1988) J. Am. Chem. Soc. 110 4460 Occurrence Handle10.1021/ja00221a083

    Article  Google Scholar 

  17. J.C. Duff, J. Chem. Soc., 547 (1941)

  18. L.F. Audriceth E.S. Scott P.S. Kipper (1954) J. Org. Chem. 19 733 Occurrence Handle10.1021/jo01370a006

    Article  Google Scholar 

  19. K.S. Dhaka Jag Mohan V.K. Chadha H.K. Pujari (1974) Indian J. Chem. 12 288

    Google Scholar 

  20. A.I. Vogel (1962) A Text Book of Quantitative Inorganic Analysis EditionNumber3 ELBS Longman’s Green and Co. Ltd. London

    Google Scholar 

  21. M. Akbar Ali R. Bose (1977) J. Inorg. Nucl. Chem. 39 265 Occurrence Handle10.1016/0022-1902(77)80011-0

    Article  Google Scholar 

  22. R.C. Agarwal D.S.S.V. Prasadrao (1982) Indian. J. Chem. 21A 735

    Google Scholar 

  23. R.C. Das M.K. Mishra P.N. Bohidar (1983) J. Indian Chem. Soc. 60 284

    Google Scholar 

  24. J.R. During R. Layton D.N. Sink B.R. Mitchell (1965) Spectrochem. Acta. 21 1326

    Google Scholar 

  25. K. Nakamoto, Advances in the Chemistry of Coordination Compounds, S. Kirschner (ed.), Mc Millan, New York, p. 437 (1961)

  26. K. Ueno A.E. Martell (1956) J. Phys. Chem. 60 1270 Occurrence Handle1:CAS:528:DyaG2sXhtFGltQ%3D%3D Occurrence Handle10.1021/j150543a029

    Article  CAS  Google Scholar 

  27. K. Nakamoto (1978) Infrared and Raman Spectra of Inorganic Coordination Compounds EditionNumber3 John Wiley New York 308

    Google Scholar 

  28. G. Percy (1976) Spectrochem.Acta. 32A 1287 Occurrence Handle1:CAS:528:DyaE28Xls12jtLo%3D Occurrence Handle10.1016/0584-8539(76)80167-5

    Article  CAS  Google Scholar 

  29. E.S. Freeman B. Corroll (1958) J. Phys. Chem. 62 394 Occurrence Handle1:CAS:528:DyaG1cXnsFGgtg%3D%3D Occurrence Handle10.1021/j150562a003

    Article  CAS  Google Scholar 

  30. J.C. Vincent and M.W. Vincent, Proc. Soc. Expt. Biiol., 55, 162 (1944)

  31. S. Mukherjee (1987) Indian J. Chem. 26 1002

    Google Scholar 

  32. H. Beens K.H. Grellmann M. Gurr A.H. Weller (1965) Disc. Faraday Soc. 39 183 Occurrence Handle10.1039/df9653900183

    Article  Google Scholar 

  33. A.W. Czarnik (1995) Chem. Biol. 2 423 Occurrence Handle1:CAS:528:DyaK2MXntlGjtb8%3D Occurrence Handle10.1016/1074-5521(95)90257-0

    Article  CAS  Google Scholar 

  34. A.W. Varnes R.B. Dodson E.L. Wehry (1972) J. Am. Chem. Soc. 94 946 Occurrence Handle1:CAS:528:DyaE38Xos1Srsw%3D%3D Occurrence Handle10.1021/ja00758a037

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. P.G. Department of Chemistry, Karnatak University, Dharwad, 580003, India

    Prakash Gouda Avaji, B. Nagaraja Reddy & Sangamesh A. Patil

  2. Department of Chemistry, Shri Sharanabasaveshwar College of Science, Gulbarga, 585 102, India

    Prema S. Badami

Authors
  1. Prakash Gouda Avaji
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Nagaraja Reddy
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sangamesh A. Patil
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Prema S. Badami
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sangamesh A. Patil.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Avaji, P.G., Reddy, B.N., Patil, S.A. et al. Synthesis, spectral characterization, biological and fluorescence studies of lanthanum(III) complexes with 3-substituted-4-amino-5-hydrazino-1,2,4-triazole Schiff bases. Transition Met Chem 31, 842–848 (2006). https://doi.org/10.1007/s11243-006-0066-5

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-006-0066-5

Keywords

Search

Navigation