Summary
Several complexes of nickel(II) with Schiff bases derived from 3-substituted-4-amino-5-mercapto-1,2,4-triazoles (H2L) have been synthesised. The complexes have a stoichiometry NiL · 2H2O. The bonding of the ligands has been inferred from i.r. spectroscopy. The ligands preserve the thiol in the complexes. Magnetic moments obtained at room temperature and electronic spectra are consistent with octahedral geometry.
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Patil, S.A., Badiger, B.M., Kudari, S.M. et al. Magnetic and spectral properties of nickel(II) complexes of ligands containing O, N, and S donor atoms. Transition Met Chem 8, 238–240 (1983). https://doi.org/10.1007/BF00620701
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DOI: https://doi.org/10.1007/BF00620701