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Effect of Hydrolysis Conditions of Organosolv Pulp from Kenaf Fibers on the Physicochemical Properties of the Obtained Nanocellulose

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Theoretical and Experimental Chemistry Aims and scope

The possibility of obtaining nanocellulose from organosolv pulp from kenaf fibers by hydrolysis with sulfuric acid of a lower concentration (43%) compared with the traditional conditions (60%-65%) is demonstrated. The structure and properties of the nanocellulose were studied by SEM, FT-IR, XRD, TEM, AFM, and TGA. It was found that the product has a degree of crystallinity of up to 80%, and forms a porous network of particles with diameters of 10-28 nm. The nanocellulose films have a density of 1.39 g/cm3, transparency of up to 76%, and tensile strength of 40 MPa.

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References

  1. D. Klemm, F. Kramer, S. Moritz, et al., Angew. Chem. Int. Ed., No. 50, 5438-5466 (2011).

  2. H. P. S. Abdul Khalil, A. H. Bhat, and A. F. Ireana Yusra, Carbohydr. Polym., 87, No. 2, 963-979 (2012).

    Article  CAS  Google Scholar 

  3. Y. H. Jung, T.-H. Chang, H. Zhang, et al., Nat. Commun., No. 6, 7170 (2015). doi:10.1038/ncomms8170.

  4. K. J. Nagarajan and A. N. Balaji, Int. J. Polym. Anal. Charact., 21, No. 5, 387-395 (2016).

    Article  CAS  Google Scholar 

  5. M. Szczêsna-Antczak, J. Kazimierczak, and T. Antczak, Fibres Textiles in Eastern Europe, 20, No. 2(91), 8-12 (2012).

  6. J. Majoinen, E. Kontturi, O. Ikkala, and D. G. Gray, Cellulose, No. 19, 1599-1605 (2012).

  7. H. P. Abdul-Khalil, Y. Davoudpour, M. Nazuruyl Islam, et al., Carbohydr. Polym., 99, 649-665 (2014).

    Article  CAS  PubMed  Google Scholar 

  8. K. L. Spence, R. A. Venditti, O. J. Rojas, et al., Cellulose, 18, No. 4, 1097-1111 (2011).

    Article  CAS  Google Scholar 

  9. I. Siro and D. Plackett, Cellulose, 17, No. 3, 459-494 (2010).

    Article  CAS  Google Scholar 

  10. M. Paakko, M. Ankerfors, H. Kosonen, et al., Biomacromolecules, No. 8, 1934-1941 (2007).

  11. W. Sridach, Suranaree J. Sci. Technol., 17, No. 2, 105-123 (2010).

    Google Scholar 

  12. S. Abad, V. Santos, and J. C. Parajü, Holzforschung, 54, No. 6, 544-552 (2000).

    CAS  Google Scholar 

  13. V. Barbash, V. Poyda, and I. Deykun, Cell. Chem. Technol., 45, Nos. 9/10, 613-618 (2011).

    CAS  Google Scholar 

  14. R. Sánchez, E. Espinosa, J. Domínguez-Roblesa, et al., Int. J. Biol. Macromol., No. 92, 1025-1033 (2016).

  15. J. P. S. Morais, M. D. F. Rosa, M. D. S. M. de Souza Filho, et al., Carbohydr. Polym., 91, No. 1, 229-235 (2013).

    Article  CAS  PubMed  Google Scholar 

  16. O. L. M. Kamoga, J. K. Byaruhanga, J. B. Kirabira, Int. J. Chem. Eng. Appl., 4, No. 3, 144-148 (2013). doi:https://doi.org/10.7763/IJCEA. 2013.V4.281

  17. W. Chunhong, B. Suyue, Y. Xinmin, et al., Fibers Polymers, 17, No. 11, 1757-1764 (2016). doi:https://doi.org/10.1007/s12221-016-6703-5.

    Article  CAS  Google Scholar 

  18. TAPPI Test Methods, Tappi Press, Atlanta, Georgia (2004).

    Google Scholar 

  19. V. Barbash, O. Yashchenko, and A. Kedrovska, J. Sci. Res. Rep., No. 16(1), 1-10 (2017).

  20. M. Ioelovich, J. Chem. Edu. Res. Prac., No. 1, 1-7 (2017).

  21. L. A. Costa, A. F. Fonseca, F. V. Pereira, and J. I. Druzian, Cell. Chem. Technol., No. 49, 127-133 (2015).

  22. R. A. Ilyas, S. M. Sapuan, M. R. Ishak, and E. S. Zainudin, BioResources, 12, No. 4, 8734-8754 (2017).

    CAS  Google Scholar 

  23. L. Ping and H. You-Lo, Carbohydr. Polym., No. 82, 329-336 (2010).

  24. V. A. Barbash, O. V. Yaschenko, and O. M. Shniruk, Nanoscale Res. Lett., No. 12, 241 (2017). doi:10.1186/s11671-017-2001-4.

  25. N. Lin and A. Dufresne, Nanoscale, 6, 5384-5393 (2014).

    Article  CAS  PubMed  Google Scholar 

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Correspondence to V. A. Barbash.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 54, No. 3, pp. 175-180, May-June, 2018.

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Barbash, V.A., Yashchenko, O.V. & Opolsky, V.O. Effect of Hydrolysis Conditions of Organosolv Pulp from Kenaf Fibers on the Physicochemical Properties of the Obtained Nanocellulose. Theor Exp Chem 54, 193–198 (2018). https://doi.org/10.1007/s11237-018-9561-y

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  • DOI: https://doi.org/10.1007/s11237-018-9561-y

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