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Two 3D supramolecules with helices constructed by hydrogen bonds based on p-thioacetatebenzoic acid ligand

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Abstract

p-Thioacetatebenzoic acid (H2L) and a combination of N-donor ligands such as 4,4′-bipyridine (4,4′-bipy) and 1,3-bi(4-pyridyl)propane (bpp) with metal ions Mn(II) and Ni(II) give rise to two coordination polymers, namely, [Mn(HL)2(bpp)2(H2O)2] n (1), [NiL (4,4′-bipy)(H2O)3] n ·nH2O (2). 1 features an unusual “8” shaped double layer by hydrogen bonds and two different types of helical chains are arrayed alternatively in the 2D double layer framework, which further extends into a 3D supramolecular structure through C–H···O hydrogen bonds. 2 consists of 1D chains which further connect with each other via hydrogen bonds to form the final 3D framework including two different types of helical structure. Photoluminescence study reveals that 1 displays intense structure-related fluorescent emission bands (λex = 369 nm) at 414 nm in the solid state at room temperature. Electrochemical property of 2 reveals that the process of the redox is irreversible.

Index abstract

p-Thioacetatebenzoic acid (H2L) and a combination of N-donor ligands such as 4,4′-bipyridine (4,4′-bipy) and 1,3-bi(4-pyridyl)propane (bpp) with metal ions Mn(II) and Ni(II) give rise to two coordination polymers with two different helices, namely, [Mn(HL)2(bpp)2(H2O)2] n (1), [NiL (4,4′-bipy)(H2O)3] n ·nH2O (2).

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References

  1. Rao CNR, Natarajan S, Vaidhyanathan R (2004) Angew Chem Int Ed 43:1466

    Article  CAS  Google Scholar 

  2. Würthner F, You CC, Saha-Möller CR (2004) Chem Soc Rev 33:133

    Article  Google Scholar 

  3. Hosseini MW (2005) Acc Chem Res 38:313

    Article  CAS  Google Scholar 

  4. Rowsell JLC, Yaghi OM (2005) Angew Chem Int Ed 44:4670

    Article  CAS  Google Scholar 

  5. Nitschke JR (2007) Acc Chem Res 40:103

    Article  CAS  Google Scholar 

  6. Pitt MA, Johnson DW (2007) Chem Soc Rev 36:1441

    Article  CAS  Google Scholar 

  7. Thomas JA (2007) Chem Soc Rev 36:856

    Article  CAS  Google Scholar 

  8. Zaworotko MJ (2007) Cryst Growth Des 7:124

    Article  Google Scholar 

  9. Batten SR (2001) Curr Opin Solid State Mater Sci 5:107

    Article  CAS  Google Scholar 

  10. Janiak C (2003) Dalton Trans 2781

  11. Carlucci L, Ciani G, Proserpio DM (2003) Coord Chem Rev 246:247

    Article  CAS  Google Scholar 

  12. Brammer L (2004) Chem Soc Rev 33:476

    Article  CAS  Google Scholar 

  13. Sieklucka B, Podgajny R, Przychodzen P, Korzeniak T (2005) Coord Chem Rev 249:2203

    Article  CAS  Google Scholar 

  14. Hong MC (2007) Cryst Growth Des 7:10

    Article  CAS  Google Scholar 

  15. Real JA, Andrss E, MuToz MC, Julve M, Granier T, Bousseksou A, Varret F (1995) Science 268:265

    Article  CAS  Google Scholar 

  16. Albrecht M, Lutz M, Spek AL, Koten GV (2000) Nature 406:970

    Article  CAS  Google Scholar 

  17. Beauvais LG, Shores MP, Long JR (2000) J Am Chem Soc 122:2763

    Article  CAS  Google Scholar 

  18. Evans OR, Lin W (2002) Acc Chem Res 35:511

    Article  CAS  Google Scholar 

  19. Deacon GB, Forsyth CM, Behrsing T, Konstas K, Forsyth M (2002) Chem Commun 2820

  20. Batten SR, Murray KS (2003) Coord Chem Rev 246:103

    Article  CAS  Google Scholar 

  21. Rodríguez A, Kivekās R, Colacio E (2005) Chem Commun 5228

  22. Ye Q, Song YM, Wang GX, Chen K, Fu DW, Chan PWH, Zhu JS, Huang SD, Xiong RG (2006) J Am Chem Soc 128:6554

    Article  CAS  Google Scholar 

  23. Zhu WH, Wang ZM, Gao S (2007) Inorg Chem 46:1337

    Article  CAS  Google Scholar 

  24. Sawaki T, Aoyama Y (1999) J Am Chem Soc 121:4793

    Article  CAS  Google Scholar 

  25. Seo JS, Whang DM, Lee HY, Jun SI, Oh JH, Jeon YJ, Kim K (2000) Nature 404:982

    Article  CAS  Google Scholar 

  26. Lee SJ, Lin W (2002) J Am Chem Soc 124:4554

    Article  CAS  Google Scholar 

  27. Zou RQ, Sakurai H, Xu Q (2006) Angew Chem Int Ed 45:2542

    Article  CAS  Google Scholar 

  28. Eddaoudi M, Moler DB, Li H, Chen B, Reineke T, O’Keeffe M, Yaghi OM (2001) Acc Chem Res 34:319

    Article  CAS  Google Scholar 

  29. Biradha K (2003) CrystEngComm 5:374

    Article  CAS  Google Scholar 

  30. Kitagawa S, Kitaura R, Noro S (2004) Angew Chem Int Ed 43:2334

    Article  CAS  Google Scholar 

  31. Braga D, Brammer L, Champness NR (2005) CrystEngComm 7:1

    Article  CAS  Google Scholar 

  32. Ockwig NW, Delgado-Friedrichs O, O’Keeffe M, Yaghi OM (2005) Acc Chem Res 38:176

    Article  CAS  Google Scholar 

  33. Yaghi OM, O’Keeffe M, Ockwing NW, Chae HK, Eddaoudi M, Kim J (2003) Nature 423:705

    Article  CAS  Google Scholar 

  34. Xu HB, Su ZM, Shao KZ, Zhao YH, Xing Y, Liang YC, Zhu HJDX (2004) Inorg Chem Commun 7:260

    Article  CAS  Google Scholar 

  35. Go YB, Wang XQ, Anokhina EV, Jacobson AJ (2004) Inorg Chem 43:5360

    Article  CAS  Google Scholar 

  36. Dan M, Rao CNR (2006) Angew Chem Int Ed 45:281

    Article  CAS  Google Scholar 

  37. Cheetham AK, Rao CNR, Feller RK (2006) Chem Commun 4780

  38. He YH, Feng YL, Lan YZ, Wen YH (2008) Cryst Growth Des 8:3586

    Article  CAS  Google Scholar 

  39. He YH, Lan YZ, Zhan CH, Feng YL, Su H (2009) Inorg Chim Acta 362:1952

    Article  CAS  Google Scholar 

  40. Bao M, Liu BD, Ning ZGJ (1994) Northeast Norm Univ 2:50

    Google Scholar 

  41. Sheldrick GM (1997) SHELXS-97, program for X-ray crystal structure solution. University of Göttingen, Göttingen, Germany

    Google Scholar 

  42. Sheldrick GM (1997) SHELXL-97, program for X-ray crystal structure refinement. University of Göttingen, Göttingen, Germany

    Google Scholar 

  43. Hu X, Guo JX, Liu C, Zen H, Wang YJ, Du WJ (2009) Inorg Chim Acta 362:3421

    Article  CAS  Google Scholar 

  44. Li CH, Huang KL, Dou JM, Chi YN, Xu YQ, Shen L, Wang DQ, Hu CW (2008) Cryst Growth Des 8:3141

    Article  CAS  Google Scholar 

  45. Zhou XX, Cai YP, Zhu SZ, Zhan QG, Liu MS, Zhou ZY, Chen L (2008) Cryst Growth Des 8:2076

    Article  CAS  Google Scholar 

  46. Santos IC, Vilas-Boas M, Piedade MFM, Freire C, Duarte MT (2000) Polyhedron 19:655

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, 321004, Jinhua, Zhejiang, People’s Republic of China

    Cai-Hong Zhan & Yun-Long Feng

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  1. Cai-Hong Zhan
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  2. Yun-Long Feng
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Correspondence to Yun-Long Feng.

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Zhan, CH., Feng, YL. Two 3D supramolecules with helices constructed by hydrogen bonds based on p-thioacetatebenzoic acid ligand. Struct Chem 21, 893–899 (2010). https://doi.org/10.1007/s11224-010-9628-4

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