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Extraction of f-elements from nitric acid solutions with phosphoryl ketones

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Abstract

The extraction ability and selectivity of a series of phosphoryl ketones Ph2P(O)CH2C(O)Me, and Ph2P(O)CRR’CH2C(O)Me (R = H, Me; R’ = H, Me, n-C5H11, Ph, 2-thienyl, 2-furyl) towards trivalent lanthanides (LaIII, NdIII, HoIII, YbIII) and actinides (UVI, ThIV) were studied. The efficiency and selectivity of the new ligands in the extraction of f-elements from nitric acid solutions into chloroform were compared to those of model phosphine oxide Ph2P(O)Bu and known extractants: tributyl phosphate (BuO)3P(O), trioctylphosphine oxide (C8H17)3P(O), and carbamoylmethyl phosphine oxide Ph2P(O)CH2C(O)NBu2.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. G. Matveeva, G. V. Bodrin, E. I. Goryunov, I. B. Goryunova & E. E. Nifant’ev

  2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    A. M. Thu & O. A. Sinegribova

  3. “United Chemical Company Uralchem” Open Joint Stock Company, 10 Presnenskaya nab., 123317, Moscow, Russian Federation

    A. M. Safiulina

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  1. A. G. Matveeva
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  2. A. M. Thu
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  3. A. M. Safiulina
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  4. G. V. Bodrin
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  5. E. I. Goryunov
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  6. I. B. Goryunova
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  7. O. A. Sinegribova
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  8. E. E. Nifant’ev
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Correspondence to A. G. Matveeva.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1309–1316, June, 2013.

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Matveeva, A.G., Thu, A.M., Safiulina, A.M. et al. Extraction of f-elements from nitric acid solutions with phosphoryl ketones. Russ Chem Bull 62, 1309–1316 (2013). https://doi.org/10.1007/s11172-013-0184-0

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  • DOI: https://doi.org/10.1007/s11172-013-0184-0

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