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Acetyl-containing phosphine oxides as extractants for actinides and lanthanides

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Abstract

Extraction capability and selectivity of acetyl-containing phosphine oxides R2P(O)CMe2CH2C(O)Me (R = Pr, Bu, n-C5H11, n-C6H13, n-C8H17, Ph) toward actinides (UVI, ThIV) and trivalent lanthanides (LaIII, NdIII, HoIII, YbIII) were studied. The new ligands were shown to be more efficient and selective in the extraction of uranium, thorium, and heavy lanthanides from nitric acid solutions into chloroform as compared to the known extractants such as carbamoylphosphine oxide Ph2P(O)CH2C(O)NBu2, trioctylphosphine oxide (n-C8H17)3P(O), and tributyl phosphate (n-BuO)3P(O).

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119071, Moscow, Russian Federation

    A. M. Safiulina & I. G. Tananaev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. G. Matveeva

  3. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    T. K. Dvoryanchikova, O. A. Sinegribova & A. M. Tu

  4. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    D. A. Tatarinov, A. A. Kostin & V. F. Mironov

Authors
  1. A. M. Safiulina
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  2. A. G. Matveeva
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  3. T. K. Dvoryanchikova
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  4. O. A. Sinegribova
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  5. A. M. Tu
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  6. D. A. Tatarinov
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  7. A. A. Kostin
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  8. V. F. Mironov
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  9. I. G. Tananaev
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Corresponding author

Correspondence to A. M. Safiulina.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 390–396, February, 2012.

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Safiulina, A.M., Matveeva, A.G., Dvoryanchikova, T.K. et al. Acetyl-containing phosphine oxides as extractants for actinides and lanthanides. Russ Chem Bull 61, 392–398 (2012). https://doi.org/10.1007/s11172-012-0055-0

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