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Effect of the nature of substituents at the phosphorus atom on extraction properties of phosphorylketones toward f-elements

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Abstract

Extraction abilities of phosphorylketones with alkyl and cycloalkyl substituents at the phosphorus atom R2P(O)CH2CH2C(O)Me (R = Pri, But) and R2P(O)CHPhCH2C(O)Me (R = Pri, cyclo-C6H11) toward UVI, ThIV, and a series of tervalent lanthanides (LaIII, NdIII, HoIII, YbIII) were studied. The efficiencies and selectivities of recovery of f-elements from nitric acid solutions to chloroform by these ligands were compared with extraction properties of both the model phosphorylketones with phenyl substituents at the phosphorus atom Ph2P(O)CH2CH2C(O)Me and Ph2P(O)CHPhCH2C(O)Me and other known extractants such as tributyl phosphate (BuO)3P(O), trioctylphosphine oxide (C8H17)3P(O), and carbamoylphosphine oxide Ph2P(O)CH2C(O)NBu2.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. G. Matveeva, E. I. Goryunov, I. B. Goryunova, G. V. Bodrin & V. K. Brel

  2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    A. M. Tu & O. A. Sinegribova

  3. “Unitied Chemical Company Uralchem, OJSC”, Inc., 10 Presnenskaya naberezhnaya, 123317, Moscow, Russian Federation

    A. M. Safiulina

  4. “Innovating Chemical Technologies,” Ltd, 10 Vrachebny pr-d, 125367, Moscow, Russian Federation

    A. V. Lesiv

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  1. A. G. Matveeva
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  2. E. I. Goryunov
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  3. A. M. Tu
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  5. I. B. Goryunova
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  8. O. A. Sinegribova
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Correspondence to A. G. Matveeva.

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Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80th birthday and to the 60th anniversary of foundation of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2493—2501, November, 2014.

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Matveeva, A.G., Goryunov, E.I., Tu, A.M. et al. Effect of the nature of substituents at the phosphorus atom on extraction properties of phosphorylketones toward f-elements. Russ Chem Bull 63, 2493–2501 (2014). https://doi.org/10.1007/s11172-014-0767-4

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  • DOI: https://doi.org/10.1007/s11172-014-0767-4

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