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Extraction of Actinides and Lanthanides from Nitric Acid Solutions with Polyphosphinylbenzenes

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Abstract

The extraction of trace amounts of U(VI), Th(IV), Am(III), and lanthanides(III) from nitric acid solutions with polyphosphinylbenzenes was studied. The stoichiometry of the extracted complexes was determined, and the influence of the extractant structure, the HNO3 concentration in the aqueous phase, and the nature of organic solvents on the efficiency of metal ions extraction into the organic phase was considered. It was found that compounds with diphenylphosphoryl groups attached directly to the benzene ring in the ortho position in their molecules have the highest extraction ability with respect to actinides and lanthanides.

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Funding

The work was supported by the Ministry of Education and Science of the Russian Federation within the framework of the state assignment for the Yu.A. Osipyan Institute of Solid State Physics of RAS, Institute for Problems of Technology of Microelectronics and High-Purity Materials of RAS, A.N. Nesmeyanov Institute of Organoelement Compounds of RAS, and the A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of RAS for 2022, and also the Russian Science Foundation (grant no. 20-13-00329, synthesis of the studied compounds).

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Authors and Affiliations

  1. Yu.A. Ossipyan Institute of Solid State Physics of the Russian Academy of Sciences, 142432, Chernogolovka, Russia

    A. N. Taranov

  2. Institute of Problems of Microelectronics Technology and Especially Pure Materials of the Russian Academy of Sciences, 142432, Chernogolovka, Russia

    V. K. Karandashev

  3. A.N. Nesmeaynov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Moscow, Russia

    O. I. Artyushin & V. K. Brel

  4. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, 119991, Moscow, Russia

    G. V. Kostikova & A. M. Fedoseev

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  1. A. N. Taranov
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  2. V. K. Karandashev
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  3. O. I. Artyushin
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  4. G. V. Kostikova
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  5. A. M. Fedoseev
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  6. V. K. Brel
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Correspondence to V. K. Brel.

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V.K. Brel is a member of the editorial board of the Journal of General Chemistry. The other authors declare no conflicts of interest.

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Taranov, A.N., Karandashev, V.K., Artyushin, O.I. et al. Extraction of Actinides and Lanthanides from Nitric Acid Solutions with Polyphosphinylbenzenes. Russ J Gen Chem 92, 1479–1487 (2022). https://doi.org/10.1134/S1070363222080163

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  • DOI: https://doi.org/10.1134/S1070363222080163

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