Skip to main content
SpringerLink
Log in

Synthesis, characterization, infrared studies, and thermal analysis of Mn0.6Zn0.4Fe2(C4H2O4)3·6N2H4 and its decomposition product Mn0.6Zn0.4Fe2O4

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Manganese zinc ferrous fumarato–hydrazinate precursor, Mn0.6Zn0.4Fe2(C4H2O4)3·6N2H4 was synthesized for the first time and characterized by chemical analysis, infrared spectral studies, and thermal analysis. Infrared studies show band at 977 cm−1 indicating bidentate bridging nature of the hydrazine in the complex. Thermogravimetric (TG) studies show two steps dehydrazination followed by two steps total decarboxylation. The precursor on touching with burning splinter undergoes self propagating autocatalytic decomposition yielding ultrafine Mn0.6Zn0.4Fe2O4. XRD studies confirms single phase formation as well as nanosize nature of “as prepared” Mn0.6Zn0.4Fe2O4. The saturation magnetization of the “as prepared” Mn0.6Zn0.4Fe2O4 was found to be 31.46 emu gm−1, which is lower than the reported, confirms the ultrafine nature of the oxide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Dalvi BD, Chavan AM. J Therm Anal. 1978;14:331.

    Article  CAS  Google Scholar 

  2. Langbein H, Eichhorn P. J Therm Anal. 1991;37:993.

    Article  Google Scholar 

  3. Poroilo NP, Alley ZG, D’zhardimaliem GL, IvleJa LN, Uflyand LE, Pomogailo AD, et al. Russ Chem Bull. 1997;46(2):362.

    Article  Google Scholar 

  4. Dahale ND, Chawla KL, Jayadevan NC, Venugopal V. Thermochim Acta. 1997;293:163.

    Article  CAS  Google Scholar 

  5. Bhosale DN, Patil VY, Rane KS, Mahajan RR, Bakare PP, Sawant SR. Thermochim Acta. 1998;316:159.

    Article  CAS  Google Scholar 

  6. Rosenberg AS, Aleksandrova EL, Ivleva NP, Dzhardimalieva GL, Raevskff AV, Kolesova OL, et al. Russ Chem Bull. 1998;47(2):259.

    Article  CAS  Google Scholar 

  7. Petrochenkova NV, Bukvetskii BV, Mirochnik AG, Karasev VE. Russ J Co-ord Chem. 2002;28(1):64.

    Article  CAS  Google Scholar 

  8. Deb N. J Therm Anal Calorim. 2005;81:61.

    Article  CAS  Google Scholar 

  9. Li X, Zou Y-Q. J Chem Cryst. 2005;35(5):351.

    Article  CAS  Google Scholar 

  10. Badea M, Olar R, Marinescu D, Vasile G. J Therm Anal Calorim. 2005;80:683.

    Article  CAS  Google Scholar 

  11. Ghodake SR, Ghodake UA, Sawant SR, Suryavanshi SS, Bakare PP. J Magn Magn Mater. 2006;305:110.

    Article  CAS  Google Scholar 

  12. Randhawa BS, Gandotra K. J Therm Anal Calorim. 2006;85:417.

    Article  CAS  Google Scholar 

  13. Randhawa BS, Kaur M. J Therm Anal Calorim. 2007;89:251.

    Article  CAS  Google Scholar 

  14. Jiji ER, Aravindakshan KK. J Therm Anal. 1995;44:65.

    Article  CAS  Google Scholar 

  15. Kishore K. Indian J Chem. 1969;7:153.

    CAS  Google Scholar 

  16. Verenkar VMS, Rane KS, Sawant PY. J Mater Sci Mater Electr. 1999;10:133.

    Article  Google Scholar 

  17. Rane KS, Verenkar VMS, Pednekar RM, Sawant PY. J Mater Sci Mater Electr. 1999;10:121.

    Article  CAS  Google Scholar 

  18. Borkar V, Rane KS, Kamat Dalal VN. J Mater Sci Mater Electr. 1993;4:241.

    Google Scholar 

  19. Gajapathy D, Patil KC. Mater Chem Phys. 1983;9:423.

    Article  CAS  Google Scholar 

  20. More A, Verenkar VMS. In: Bahadur D, Vitta S, Prakash O, editors. Inorganic materials: recent advances. New Delhi: Narosa Publishing House; 2006. p. 230.

  21. Sawant SY, Kannan KR, Verenkar VMS. In: Pillai CGS, Ramakumar KL, Ravindran PV, Venugopal V, editors. Proceedings of the 13th national symposium on thermal analysis, B.A.R.C., Mumbai. Mumbai: Indian Thermal Analysis Society; 2002. p. 154.

  22. Porob RA, Sawant SY, Kannan KR, Verenkar VMS. In: Singh KD, Bharadwaj MS, Ravindran PV, Sali SK, Venugopal V, editors. Proceedings of the 14th national symposium on thermal analysis, Baroda. Mumbai: Indian Thermal Analysis Society; 2004. p. 335.

  23. Porob R, Khan SZ, Mojumdar SC, Verenkar VMS. 15th Canadian thermal analysis society’s annual workshop and exhibition. Boucherville, Quebec, Canada: National Research Council Canada; 2005.

  24. Sawant SY, Mojumdar SC, Verenkar VMS. 16th Canadian thermal analysis society’s annual workshop and exhibition, Canada; 2006.

  25. Sail GM, Verenkar VMS. 3rd national symposium in chemistry. Chandigarh, India: Punjab University; 2001. p. 133.

    Google Scholar 

  26. Ravindranathan P, Patil KC. Thermochim Acta. 1983;71:53.

    Article  CAS  Google Scholar 

  27. Jiji ER, Aravindakshan KK. Indian J Chem Soc. 1993;70:67.

    CAS  Google Scholar 

  28. Mahesh GV, Patil KC. Thermochim Acta. 1986;99:188.

    Article  Google Scholar 

  29. Patil KC, Gajapathy D, Pai Verneker VR. Mater Res Bull. 1982;17:29.

    Article  CAS  Google Scholar 

  30. Sharov VA, Nikonenko EA. Russ J Inorg Chem. 1980;25(2):310.

    Google Scholar 

  31. Sivasankar BN, Govindarajan S. Synth React Inorg Met-Org Chem. 1994;24:1573.

    Google Scholar 

  32. Sivasankar BN. J Therm Anal Calorim. 2006;86(2):385.

    Article  CAS  Google Scholar 

  33. Verenkar VMS, Rane KS. In: Dharwadkar SR, Bharadwaj SR, Mukherjee SK, Sood DD, editors. Proceedings of the 10th national symposium on thermal analysis, DMSRDE; Kanpur. Mumbai: Indian Thermal Analysis Society; 1995. p. 171.

  34. Verenkar VMS, Rane KS. In: Dharwadkar SR, Bharadwaj SR, Mukherjee SK, Sood DD, editors. Proceedings of the 10th national symposium on thermal analysis, DMSRDE; Kanpur, 1995. Mumbai: Indian Thermal Analysis Society; 1995. p. 175.

  35. Rane KS, Verenkar VMS. Bull Mater Sci. 2001;24:39.

    Article  CAS  Google Scholar 

  36. Verenkar VMS, Rane KS. In: Ravindran PV, Sundersanan M, Misra NL, Venugopal V, editors. Proceedings of the 12th national symposium on thermal analysis, Gorakhpur. Mumbai: Indian Thermal Analysis Society; 2000. p. 194.

  37. Sawant SY, Verenkar VMS, Mojumdar SC. J Therm Anal Calorim. 2007;90:669.

    Article  CAS  Google Scholar 

  38. Gawas U, Bhattacharya S, More A, Verenkar VMS. In: Lokhande Dr CD, editor. Proceedings of the international conference on advanced materials and applications. Kolhapur, India; 2007. p. 86.

  39. Porob RA, Khan SZ, Mojumdar SC, Verenkar VMS. J Therm Anal Calorim. 2006;86:605.

    Article  CAS  Google Scholar 

  40. More A, Verenkar VMS, Mojumdar SC. 18th Canadian thermal analysis society’s annual workshop and exhibition, Canada; 2008. p. 28.

  41. Gawas UB, Verenker VMS, Mojumdar SC. 18th Canadian thermal analysis society’s annual workshop and exhibition, Canada; 2008. p. 47.

  42. More A, Verenkar VMS, Mojumdar SC. J Therm Anal Calorim. 2008;94:63.

    Article  CAS  Google Scholar 

  43. Gawas UB, Mojumdar SC, Verenker VMS. J Therm Anal Calorim. 2009;96(1):49.

    Article  CAS  Google Scholar 

  44. Gonsalves LR, Verenker VMS, Mojumdar SC. J Therm Anal Calorim. 2009;96(1):53.

    Article  CAS  Google Scholar 

  45. Vogel’s, Text book of quantitative inorganic analysis (Revised by Jeffery GH, Bassettv, Mendham J and Denney RC), 5th edn. Longman, UK; 1989. p. 402.

  46. Likhite SD, Radhakrishnamurthy C, Sahasrabudhe PW. Rev Sci Instr. 1965;25:302.

    Google Scholar 

  47. Braibanti A, Dallavalle F, Pellinghelli MA, Leporati E. Inorg Chem. 1968;7:1430.

    Article  CAS  Google Scholar 

  48. Tsuchiya R, Yonemura M, Uehera A, Kyuno E. Bull Chem Soc Jpn. 1974;47(3):660.

    Article  CAS  Google Scholar 

  49. Sivasankar BN, Govindarajan S. Z Naturforsch B. 1994;49(7):950.

    CAS  Google Scholar 

  50. Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds. New York: Wiley; 1978.

    Google Scholar 

  51. Tangsali RB, Keluskar SH, Naik GK, Budkuley JS. Int J Nanosci. 2004;3(4–5):589.

    Article  CAS  Google Scholar 

  52. Srivastava P, Kumar J. In: Bahadur D, Vitta S, Prakash O, editors. Inorganic materials: recent advances. New Delhi: Narosa Publishing House; 2006; p. 423.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Goa University, Taleigao Plateau, Goa, 403206, India

    U. B. Gawas & V. M. S. Verenkar

  2. Department of Engineering, University of New Brunswick, Saint John, NB, E2L 4L5, Canada

    S. C. Mojumdar

Authors
  1. U. B. Gawas
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. C. Mojumdar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. S. Verenkar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. C. Mojumdar.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gawas, U.B., Mojumdar, S.C. & Verenkar, V.M.S. Synthesis, characterization, infrared studies, and thermal analysis of Mn0.6Zn0.4Fe2(C4H2O4)3·6N2H4 and its decomposition product Mn0.6Zn0.4Fe2O4 . J Therm Anal Calorim 100, 867–871 (2010). https://doi.org/10.1007/s10973-010-0720-1

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-010-0720-1

Keywords

Search

Navigation