Abstract
Acid and neutral CoII, CuII, NiII, ZnII, FeII, and FeIII maleates, fumarates, and itaconates were obtained and characterized. The methods for their synthesis were optimized, and the valence state and coordination of metals were studied. CoII and FeII hydrogen maleates, CoII maleate, and CoII fumarate were examined by X-ray diffraction analysis. The ligands based on unsaturated dicarboxylic acids can be mono-, bi-, and tetradentate, which results in the formation of acid salts, chain and three-dimensional coordination polymers, whose double bond is not involved in the coordination. The strong antiferromagnetic exchange (μelf=1.41 and 0.34 μB at 290 and 80 K, respectively) was detected in CuII itaconate. Based on the data of Mössbauer spectroscopy, the partial reduction of FeIII to FeII during the synthesis of FeIII maleate was shown to occur: δFe=0.43 and 1.27 mm s−1, ΔE Q=0.57 and 3.13 mm s−1 and Γ=0.37 and 0.28 mm s−1 atT=298 K for FeIII and FeII, respectively.
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L. Mu, V. Y. Young, and N. B. Comerford,J. Chem. and Eng. Data, 1993,38, 481.
H. R. Zelsmann and Z. Mielkef,Spectrochimica Acta, 1988,44A, 705.
T. A. Krasovskaya, S. B. Pirkes, and A. S. Molotkov,Zh. Neorg. Khim., 1984,29, 1964 [Russ. J. Inorgan. Chem., 1984,29 (Engl. Transl.)].
G. N. Makusheva, B. L. Faifel', S. B. Pirkes, A. V. Lapitskaya, and L. V. Bessudnova,Zh. Neorg. Khim., 1989,34, 628 [Russ. J. Inorgan. Chem., 1988,34 (Engl. Transl.)].
F. T. Chuk, M. Koleva, and C. Mikhailova,Farmatsiya [Pharmacy], 1988,38, 16 (in Russian).
K. M. Alam, F. M. Kaniz, and A. Gulzar,Pakistan J. Sci. and Ind. Res., 1987,30, 707.
Q. -X. Yang and Q. -L. Zhou,Adhes. Chem.: Dev. and Trends. Proc. Symp. Recent Dev., Seattle, Wash., March 21–23, 1983, New York, London, 1984, 799.
L. M. Demchenko, D. F. Kutepov, and A. D. Volgin,Tr. MKhTI im. D. I. Mendeleeva [Proc. D. I. Mendeleev Moscow Institute of Chemical Technology], 1975,86, 130 (in Russian).
A. D. Pomogailo and V. S. Savost'yanov,Metallosoderzhashchie monomery i polimery na ikh osnove [Metal-Containing Monomers and Polymers Based on Them], Khimiya, Moscow, 1988, 383 pp. (in Russian).
N. P. Porollo, G. I. Dzhardimalieva, I. E. Uflyand, and A. D. Pomogailo,Tez. dokl. VI Vseros. konf. po metallo-organicheskoi khimii [Proc. VI All-Russian Conf. on Organometallic Chemistry], Nizhinii Novgorod, 1995, 99 (in Russian).
C. K. Prout, J. R. Carruthers, and F. J. Rossotti,J Chem. Soc. (A), 1971, 3342.
I. Vansco-Szmercsanyi and A. Kallo,J. Polym. Sci.: Polym. Chem. Ed., 1982,20, 639.
K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley and Sons, New York, 1987.
J. R. Allan, J. G. Bonner, A. R. Werninck, H. J. Bowley, and D. L. Gerrard,Thermochimica Acta, 1987,122 295.
M. L. Post and J. Trotter,J. Chem. Soc., Dalton Trans., 1974, 674.
A. Hempel and S. E. Hull,Acta Cryst., 1979,B35, 2215.
A. S. Antsyshkina, M. A. Porai-Koshits, and M. G. Guseinov,Izv. Akad. Nauk SSSR, Ser. Khim., 1974, 273 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1974,33 (Engl. Transl.)].
M. P. Gupta and B. Mahata,Cryst. Struct. Comm., 1978, 179.
G. M. Sheldrick,J. Appl. Cryst., 1993,26, 593.
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For Part 46, seeIzv. Akad. Nauk, Ser. Khim., 1996, 2922 [Russ. Chem. Bull., 1996,45, 2773 (Engl. Transl.)].
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 375–382, February, 1997.
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Porollo, N.P., Aliev, Z.G., Dzhardimalieva, G.I. et al. Synthesis and reactivity of metal-containing monomers. Russ Chem Bull 46, 362–370 (1997). https://doi.org/10.1007/BF02494382
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DOI: https://doi.org/10.1007/BF02494382