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Two Schiff-base complexes of cadmium and manganese on modified MCM-41 as practical, recyclable and selective nanocatalysts for the synthesis of sulfoxides

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Abstract

In this work, 2-Hydroxy-5-nitrobenzaldehyde Schiff-base complexes of cadmium and manganese on MCM-41 (Cd-5NSA-MCM-41 and Mn-5NSA-MCM-41) have been investigated as stable, efficient, environment friendly, reusable, and chemoselective nanocatalysts. These catalysts were characterized by various techniques such as X-ray diffraction (XRD), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET), Fourier transform-infrared spectroscopy (FT-IR) and atomic absorption spectroscopy (AAS). Sulfoxide derivatives were synthesized in the presence of Cd-5NSA-MCM-41 and Mn-5NSA-MCM-41 through mild and selective oxidation of sulfides and all sulfoxide products were obtained in good yields within acceptable times. In order to synthesis of sulfoxides, hydrogen peroxide (H2O2) was used as an environmentally friendly, non-toxic, available and inexpensive oxidant. These catalysts can recovered and reused for several times without significant loss in catalytic activities. In addition the recovered catalysts was characterized with several techniques such as XRD diffraction, AAS analysis and FT-IR spectroscopy, which are shown a good agreement to fresh catalysts. Comparison of reused and un-reused catalysts were confirmed the heterogeneous nature and good stability of these catalysts.

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Acknowledgement

Authors thank the research facilities of Ilam University, Ilam, Iran, for financial support of this research project.Also, financial support for this work by the research affairs of Islamic Azad University, Qeshm Branch, Qeshm, Iran is gratefully acknowledged.

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Authors and Affiliations

  1. Department Of Chemistry, Qeshm Branch, Islamic Azad University, Qeshm, Iran

    Arida Jabbari

  2. Department of Chemistry, Ilam University, P.O. Box 69315516, Ilam, Iran

    Mohsen Nikoorazm & Parisa Moradi

Authors
  1. Arida Jabbari
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  2. Mohsen Nikoorazm
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  3. Parisa Moradi
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Contributions

AJ: Data Collection, Methodology and Investigation. MN: Supervision. PM: Writing - original draft , Writing-review & editing.

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Correspondence to Arida Jabbari or Mohsen Nikoorazm.

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Jabbari, A., Nikoorazm, M. & Moradi, P. Two Schiff-base complexes of cadmium and manganese on modified MCM-41 as practical, recyclable and selective nanocatalysts for the synthesis of sulfoxides. J Porous Mater 30, 1395–1402 (2023). https://doi.org/10.1007/s10934-023-01427-1

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  • DOI: https://doi.org/10.1007/s10934-023-01427-1

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