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Facile synthesis of amine-functionalized MIL-53(Al) by ultrasound microwave method and application for CO2 capture

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Abstract

An amine functional MIL-53(Al) material was prepared through a clean, rapid, energy-efficient method of microwave and ultrasound irradiation. The pure phase NH2-MIL-53(Al) can be formed in 25 min, utilizing the synergistic effect of microwave and ultrasound irradiation. The dramatic acceleration in reaction rates suggested that the removal of a passivation coating on the substrate particles and the resultant enhancement in mass and heat transfer. The porous MOFs exhibited a high thermal and chemical stability, decomposing at temperatures above 410 °C in air. The NH2-MIL-53(Al) performed an excellent adsorption for CO2. The CO2 capacities up to 33.86 cm3 g−1 at 298 K at low pressures, which suggests chemisorption between CO2 and pendan amine groups. Measurement of CO2 adsorption cycles proved that the functionalized materials show good regenerability and stability.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (21371002, 21303002, 21406003), Anhui Provincial Natural Science Foundation (No. 1408085MB22), and the National “211 Project” of Anhui University.

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Authors and Affiliations

  1. Laboratory of Advanced Porous Materials, School of Chemistry and Chemical Engineering, Anhui University, Hefei, 230601, People’s Republic of China

    Jinlong Ge, Lingli Liu, Lingguang Qiu, Xia Jiang & Yuhua Shen

  2. Department of Applied Chemistry and Environmental Engineering, Bengbu University, Bengbu, 233030, People’s Republic of China

    Jinlong Ge

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  1. Jinlong Ge
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  2. Lingli Liu
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Correspondence to Lingguang Qiu.

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Ge, J., Liu, L., Qiu, L. et al. Facile synthesis of amine-functionalized MIL-53(Al) by ultrasound microwave method and application for CO2 capture. J Porous Mater 23, 857–865 (2016). https://doi.org/10.1007/s10934-016-0142-y

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