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Facile Synthesis of Ni2+ Doped MgFe2O4 Spinel Nanoparticles: Structural, Optical, Magnetic, and Dielectric Behavior

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Abstract

Nickel-doped magnesium cubic spinel ferrite nanoparticles (NPs) were prepared through the microwave combustion method (MCM). The structure of magnesium ferrite normal spinel is obtained from XRD analysis. The average crystallite size is between 26 and 17 nm. The elemental compositions and oxidizing states of Ni2+ doped MgFe2O4 ferrites were evaluated by using XPS analysis. The morphology of spinel nanoparticles was studied using HR-SEM images. The energy dispersive X-ray method is used for ensuring the presence of elements and the band gap value 2.09, 2.02, 1.85, and 1.82 eV have been obtained using the tau’c relation. The magnesium spinel structure is confirmed in the band at 434 and 561 cm−1 which corresponds to the stretching vibration of the octahedral site (Mg2+–O2−) and tetrahedral site (Fe3+–O2−) respectively. From the hysteresis loops the magnetic features viz. Hc, Mr, and Ms were determined. Further dielectric studies and AC conductivity of the prepared samples are performed.

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Acknowledgements

The authors extend their sincere appreciation to the Researchers Supporting Project number (RSPD2023R682), King Saud University, Riyadh, Saudi Arabia for the support.

Funding

This study was supported by Researchers Supporting Project number (RSPD2023R682), King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Department of Biotechnology, Periyar University Centre for Post Graduate and Research Studies, Dharmapuri, Tamil Nadu, 635 205, India

    R. Revathi

  2. Department of Applied Physics, Sri Venkateswara College of Engineering, Pennalur, Sriperumbudur, Tamil Nadu, 602 117, India

    M. Sukumar

  3. Department of Chemistry, GLA University, Mathura, 281406, India

    Anuj Kumar

  4. Division of Research and Development, Lovely Professional University, Punjab, India

    Manish Gupta

  5. Department of Physics, Holy Cross College (Autonomous), Nagercoil, Tamilnadu, 629 004, India

    P. Aji Udhaya

  6. Division of Research Innovation, Uttaranchal University, Dehradun, India

    Satbir S. Sehgal

  7. Department of Materials Science and Engineering and Chemical Engineering, Universidad Carlos III de Madrid, Avenida de la Universidad 30, Leganés, 28911, Madrid, Spain

    Bidhan Pandit

  8. PG & Research Department of Physics, Paavendhar College of Arts & Science, M.V. South, Thalaivasal, Salem, Tamilnadu, 636 121, India

    M. Sundararajan

  9. Department of Biochemistry, Dwaraka Doss Goverdhan Doss Vaishnav College, Chennai, Tamilnadu, 600 106, India

    A. Subramani

  10. Department of Electronics and Communication Engineering, Centurion University of Technology and Management, Bhubaneswar, Odisha, 752050, India

    Chandra Sekhar Dash

  11. Department of Chemistry, Graphic Era (Deemed to be University), Bell Road, Clement Town, Dehradun, Uttarakhand, 248002, India

    N. Senthilkumar

  12. Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, 11451, Riyadh, Saudi Arabia

    Mohd Ubaidullah

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  1. R. Revathi
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Contributions

Synthesis: RR, MS. Morphological and elemental analysis: MU, MG, SSS, BP,AK, NS. Magnetic studies: MS, CSD, AS. Dielectric studies: AU, CSD. Paper writing, result interpretation and idea conceived: MS, CSD, MS.

Corresponding authors

Correspondence to M. Sukumar, M. Sundararajan, Chandra Sekhar Dash or Mohd Ubaidullah.

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Revathi, R., Sukumar, M., Kumar, A. et al. Facile Synthesis of Ni2+ Doped MgFe2O4 Spinel Nanoparticles: Structural, Optical, Magnetic, and Dielectric Behavior. J Inorg Organomet Polym 34, 374–386 (2024). https://doi.org/10.1007/s10904-023-02820-8

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