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Facile approach to glycidyl methacrylate-based polyHIPE monoliths with high epoxy-group content

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Abstract

This paper reports a facile approach to glycidyl methacrylate (GMA)-based polyHIPE monoliths with high epoxy-group content, which are fabricated using a high internal phase emulsion (HIPE) template via radiation-induced polymerization at room temperature. The effects of the polymerization temperature and the pore sizes of polyHIPE monoliths on the content of epoxy groups are investigated. Results show that the polymerization temperature is the most important factor in influencing the content of epoxy groups in GMA-based polyHIPE monoliths. To prove their superiority over monoliths with low epoxy-group contents, the as-prepared polyHIPE monoliths are applied in phenol removal from cigarette smoke through a reaction between the epoxy group and phenol. The results show that the higher the content of epoxy groups in the polyHIPE monoliths, the higher the rate of phenol removal, indicating their high performance in these specific applications for the polyHIPE monoliths with high epoxy-group contents.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (51003122, 50873096), the National Science and Technology Project of China (322012AK0030), and the Key Science and Technology Projects of CNTC (312010AA0040).

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Authors and Affiliations

  1. Key Laboratory of Tobacco Chemistry, Zhengzhou Tobacco Research Institute of CNTC, Zhengzhou, 450001, People’s Republic of China

    Song Yang, Yipeng Wang, Xuehui Sun, Peijian Sun, Huimin Liu & Cong Nie

  2. Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, 230026, People’s Republic of China

    Lai Zeng & Huarong Liu

Authors
  1. Song Yang
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  2. Lai Zeng
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  3. Yipeng Wang
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  4. Xuehui Sun
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  5. Peijian Sun
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  6. Huimin Liu
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  7. Cong Nie
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  8. Huarong Liu
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Correspondence to Cong Nie or Huarong Liu.

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Yang, S., Zeng, L., Wang, Y. et al. Facile approach to glycidyl methacrylate-based polyHIPE monoliths with high epoxy-group content. Colloid Polym Sci 292, 2563–2570 (2014). https://doi.org/10.1007/s00396-014-3295-8

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  • DOI: https://doi.org/10.1007/s00396-014-3295-8

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