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One-step synthesis of manganese dioxide/polystyrene nanocomposite foams via high internal phase emulsion and study of their catalytic activity

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Abstract

This paper is devoted to the preparation of manganese dioxide/polystyrene nanocomposite foams via a novel and facile one-step method using high internal phase emulsion as templates. Scanning electron microscopy (SEM), Fourier transform infrared spectrometer (FT-IR), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analyses (TGA) techniques were used to characterize the resulting composites. SEM measurements revealed the porous network structure, the average pore diameters ranged from 3.8 to 30.4 μm. The presence of manganese dioxide was identified by XPS pattern, XRD, pattern and FT-IR spectra of the resulting composites. The TGA thermograms showed that the maximum content of manganese dioxide in the nanocomposite foams reached about 15.5%. The applications of the nanocomposite in the oxidative degradation of methylene blue exhibited good catalytic activity in the presence of H2O2 as an oxidant.

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References

  1. Corma A (1997) Chem Rev 97:2373

    Article  CAS  Google Scholar 

  2. Gier TE, Bu X, Feng P, Stucky GD (1998) Nature 395:154

    Article  CAS  Google Scholar 

  3. Beck JS (1992) J Am Chem Soc 114:10834

    Article  CAS  Google Scholar 

  4. Kim SH (2006) J Porous Mater 13:201–205

    Article  CAS  Google Scholar 

  5. Velev OD, Jede TA, Lobo RF, Lenhoff AM (1997) Nature 389:448

    Article  Google Scholar 

  6. Holland BT, Blanford CF, Stein A (1998) Science 281:538

    Article  CAS  Google Scholar 

  7. Imhof A, Pine J (1997) Nature 389:948

    Article  CAS  Google Scholar 

  8. Breulmann M, Davis SA, Mann S, Hentze HP, Antonietti M (2000) Adv Mater 12:502

    Article  CAS  Google Scholar 

  9. Antonelli DM (1999) Microporous Mesoporous Mater 33:209

    Article  CAS  Google Scholar 

  10. Sepulveda P, Binner GPJ (1999) Eur Ceram Soc 19:2059

    Article  CAS  Google Scholar 

  11. Davis SA, Burkett SL, Mendelson NH, Mann S (1997) Nature 385:420

    Article  CAS  Google Scholar 

  12. Menner A (2008) J Polym Sci Pol Chem 46(16):5708–5714

    Article  CAS  Google Scholar 

  13. Barbetta A, Dentini M, Zannoni EM, De Stefano ME (2005) Langmuir 21:12333–12341

    Article  CAS  Google Scholar 

  14. Barbetta A, Dentini M, De Vecchis MS, Filippini P, Formisano G, Caiazza S (2005) Adv Funct Mater 15:118–124

    Article  CAS  Google Scholar 

  15. Kovacic S, Stefanec D, Krajnc P (2007) Macromolecules 40:8056–8060

    Article  CAS  Google Scholar 

  16. Krajnc P, Stefanec D, Pulko I (2005) Macromol Rapid Commun 26:1289–1293

    Article  CAS  Google Scholar 

  17. Menner A (2006) Polymer 47:7628–7635

    Article  CAS  Google Scholar 

  18. Lissant KJ (1970) J Soc Cosmet Chem 21:141–154

    CAS  Google Scholar 

  19. Cameron NR, Sherrington DC (1997) J Mater Chem 112:209–2212

    Google Scholar 

  20. Barbetta A, Cameron NR, Cooper SJ (2000) Chem Commun 221–222

  21. Cameron NR (2005) Polymer 46:1439–1449

    Article  CAS  Google Scholar 

  22. Williams JM, Wrobleski DA (1988) Langmuir 4:656–662

    Article  CAS  Google Scholar 

  23. Williams JM (1991) Langmuir 71:370–1377

    Google Scholar 

  24. Aronson MP, Petko MF (1993) J Colloid Interface Sci 159:134

    Article  CAS  Google Scholar 

  25. Kent P, Saunders BP (2001) J Colloid Interface Sci 242:437

    Article  CAS  Google Scholar 

  26. Tai H, Sergienko A, Silverstein MS (2001) Polymer 42:4473–4482

    Article  CAS  Google Scholar 

  27. Gemeay AH et al (2007) J Colloid Interface Sci 308:385–394

    Article  CAS  Google Scholar 

  28. Echigo S, Yamada H, Matsui S, Kawanishi S, Shishida K (1996) Water Sci Tech 34:81

    CAS  Google Scholar 

  29. Balcioglu IA, Arslan I, Sacan MT (2001) Environ Technol 22:813

    Article  CAS  Google Scholar 

  30. Haghighi-Podeh MR, Sarhadi M, Ghoreishi SM (2001) Water Qual Res J Can 36:605

    CAS  Google Scholar 

  31. Aplin R, Waite TD (2000) Water Sci Technol 42:345

    CAS  Google Scholar 

  32. Gemeay AH, Mansour IA, El-Sharkawy RG, Zaki AB (2001) J Mol Catal A-Chem 193:109–120

    Article  Google Scholar 

  33. Gemeay AH, Mansour IA, El-Sharkawy RG, Zaki AB (2004) J Chem Technol Biotechnol 79:85–96

    Article  CAS  Google Scholar 

  34. Gemeay AH, Mansour IA, El-Sharkawy RG, Zaki AB (2003) J Colloid Interface Sci 263:228–236

    Article  CAS  Google Scholar 

  35. Fung FC, Sin KM, Tsui SM (2000) J Soc Dyes Colorist 116-170

  36. Zwinter C, Krimmel FH (2000) Water Res 341:881

    Google Scholar 

  37. Ulusoy B, Ebrutalkayab C, Fusun S (2004) J Hazard Mater B 114:159–166

    Article  Google Scholar 

  38. Amit S, Rupali G (2004) Desalination 167:55–63

    Article  Google Scholar 

  39. Vautier M, Guillard C, Hermann JM (2001) J Catal 201:46–59

    Article  CAS  Google Scholar 

  40. Wang X, Zhang Z (2006) Radiat Phys Chem 75:1001–1005

    Article  CAS  Google Scholar 

  41. Liu YP et al (1997) Mater Res Bull 32:1055–1062

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We thank the National Natural Science Foundation of China (Project No. 50873096) for financial support.

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Correspondence to Zhicheng Zhang.

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Wang, S., Zhang, Z., Liu, H. et al. One-step synthesis of manganese dioxide/polystyrene nanocomposite foams via high internal phase emulsion and study of their catalytic activity. Colloid Polym Sci 288, 1031–1039 (2010). https://doi.org/10.1007/s00396-010-2236-4

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  • DOI: https://doi.org/10.1007/s00396-010-2236-4

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