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Synthesis and characterization of La- and Ce-codoped polycrystal ZnO prepared by hydrothermal method for 1,2-propanediol

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Abstract

La/Ce-codoped ZnO (La/Ce–ZnO)-based gas sensors are successfully prepared by a simple mild hydrothermal method. And the structures, morphologies and sensing properties are examined by XRD, SEM and XPS, respectively. The 1,2-propanediol gas-sensing analysis reveals that the La/Ce–ZnO-based gas sensor displays the highest response compared with La-doped ZnO and Ce-doped ZnO sensors. La/Ce–ZnO-based gas sensor exhibits an excellent response (681) and possesses good response and recovery property of 11 and 45 s to 100 ppm 1,2-propanediol at 240 °C, respectively. The mechanism of gas sensing and enhanced gas response of La/Ce–ZnO is discussed.

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References

  1. N.F. Hamedani, A.R. Mahjoub, A.A. khodadadi, Y. Mortazavi, CeO2 doped ZnO flower-like nanostructure sensor selective to ethanol in presence of CO and CH4. Sens. Actuators B Chem. 169, 67–73 (2012)

    Article  Google Scholar 

  2. X.L. Xu, Y. Chen, S.Y. Ma, W.Q. Li, Y.Z. Mao, Excellent acetone sensor of La-doped ZnO nanofibers with unique bead-like structures. Sens. Actuators B Chem. 213, 222–233 (2015)

    Article  Google Scholar 

  3. F. Gao, G. Qin, Y. Li, Q. Jiang, L. Luo, K. Zhao, Y. Liu, H. Zhao, One-pot synthesis of La-doped SnO2 layered nanoarrays with an enhanced gas-sensing performance toward acetone. RSC Adv. 6, 10298–10310 (2016)

    Article  Google Scholar 

  4. X.F. Chu, X.H. Zhu, Y.P. Dong, X.T. Ge, S.Q. Zhang, W.Q. Sun, Acetone sensors based on La3+ doped ZnO nano-rods prepared by solvothermal method. J. Mater. Sci. Technol. 28, 200–204 (2012)

    Article  Google Scholar 

  5. H. Xu, A.L. Rosa, T. Frauenheim, R.Q. Zhang, S.T. Lee, Density-functional theory calculations of bare and passivated triangular-shaped ZnO nanowires. Appl. Phys. Lett. 91, 031914 (2007)

    Article  ADS  Google Scholar 

  6. S.P. Huang, H. Xu, I. Bello, R.Q. Zhang, Tuning electronic structures of ZnO nanowires by surface functionalization a first-principles study. J. Phys. Chem. C 114, 8861–8866 (2010)

    Article  Google Scholar 

  7. L.W. Wang, Y.F. Kang, X.H. Liu, S.M. Zhang, W.P. Huang, S.R. Wang, ZnO nanorod gas sensor for ethanol detection. Sens. Actuators B Chem. 162, 237–243 (2012)

    Article  Google Scholar 

  8. S.Q. Tian, Y.P. Zhang, D.W. Zeng, H. Wang, N. Li, C.S. Xie, C.X. Pan, X.J. Zhao, Surface doping of La ions into ZnO nanocrystals to lower the optimal working temperature for HCHO sensing properties. Phy. Chem. Chem. Phys. 17, 27437–27445 (2015)

    Article  Google Scholar 

  9. S. Tian, Y. Zhang, D. Zeng, H. Wang, N. Li, C. Xie, C. Pan, X. Zhao, Surface doping of La ions into ZnO nanocrystals to lower the optimal working temperature for HCHO sensing properties. Phys. Chem. Chem. Phys. 17, 27437–27445 (2015)

    Article  Google Scholar 

  10. X.J. Wang, W. Wang, Y.L. Liu, Enhanced acetone sensing performance of Au nanoparticles functionalized flower-like ZnO. Sens. Actuators B Chem. 168, 39–45 (2012)

    Article  Google Scholar 

  11. S.W. Choi, S.S. Kim, Room temperature CO sensing of selectively grown networked ZnO nanowires by Pd nanodot functionalization. Sens. Actuators B Chem. 168, 8–13 (2012)

    Article  Google Scholar 

  12. J. Mi, G. Feng, L. Han, T. Guo, Y. Zhu, J. Wang, Modified semi-coke-supported cerium oxide-doped zinc ferrites for the removal of H2S from coal gas. Chem. Eng. Technol. 35, 1626–1631 (2012)

    Article  Google Scholar 

  13. W.R. Lu, D.C. Zhu, X. Xiang, Synthesis and properties of Ce-doped ZnO as a sensor for 1,2-propanediol. J. Mater. Sci. Mater. Electron. 28, 18929–18935 (2017)

    Article  Google Scholar 

  14. T. Wang, X. Kou, L. Zhao, P. Sun, C. Liu, Y. Wang, K. Shimanoe, N. Yamazoe, G. Lu, Flower-like ZnO hollow microspheres loaded with CdO nanoparticles as high performance sensing material for gas sensors. Sens. Actuators B Chem. 250, 692–702 (2017)

    Article  Google Scholar 

  15. N.S. Ramgir, P.K. Sharma, N. Datta, M. Kaur, A.K. Debnath, D.K. Aswal, S.K. Gupta, Room temperature H2S sensor based on Au modified ZnO nanowires. Sens. Actuators B Chem. 186, 718–726 (2013)

    Article  Google Scholar 

  16. K. Shingange, Z.P. Tshabalala, O.M. Ntwaeaborwa, D.E. Motaung, G.H. Mhlongo, Highly selective NH3 gas sensor based on Au loaded ZnO nanostructures prepared using microwave-assisted method. J. Colloid Interface Sci. 479, 127–138 (2016)

    Article  ADS  Google Scholar 

  17. X. Xiang, D. Zhu, D. Wang, Enhanced formaldehyde gas sensing properties of La-doped SnO2 nanoparticles prepared by ball-milling solid chemical reaction method. J. Mater. Sci. Mater. Electron. 27, 7425–7432 (2016)

    Article  Google Scholar 

  18. A.A. Yadav, A.C. Lokhande, P.A. Shinde, J.H. Kim, C.D. Lokhande, CO2 gas sensing properties of La2O3 thin films deposited at various substrate temperatures. J. Mater. Sci. Mater. Electron. 28, 13112–13119 (2017)

    Article  Google Scholar 

  19. H.-J. Kim, J.-H. Lee, Highly sensitive and selective gas sensors using p-type oxide semiconductors: overview. Sens. Actuators B Chem. 192, 607–627 (2014)

    Article  Google Scholar 

  20. S. Aygun, D. Cann, Response kinetics of doped CuO/ZnO heterocontacts. J. Phys. Chem. B 109, 7878–7882 (2005)

    Article  Google Scholar 

  21. C. Ge, C. Xie, S. Cai, Preparation and gas-sensing properties of Ce-doped ZnO thin-film sensors by dip-coating. Mater. Sci. Eng. B 137, 53–58 (2007)

    Article  Google Scholar 

  22. C.S. Yang, J.H. Chen, S.J. Dai, Application of ceria and lanthana in catalyst for cleansing exhaust gas of car. J. Rare Earth 22, 232–235 (2004)

    Google Scholar 

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Lu, W., Zhu, D. Synthesis and characterization of La- and Ce-codoped polycrystal ZnO prepared by hydrothermal method for 1,2-propanediol. Appl. Phys. A 125, 68 (2019). https://doi.org/10.1007/s00339-019-2380-8

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