Skip to main content
Log in

CO2 gas sensing properties of La2O3 thin films deposited at various substrate temperatures

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Carbon dioxide gas (CO2) sensing properties of La2O3 thin films synthesized by spray pyrolysis method are reported. La2O3 thin films deposited at different substrate temperatures (573–623 K) are characterized for their structural, surface morphology, optical and electrical properties and used for CO2 gas response measurements. SEM analyses indicate porous surface morphology. The deposited La2O3 films are crystalline with pronounced orientation along (110) plane, uniform and adhere to the glass substrate. From optical absorbance studies, the optical band gap is found to be 4.2 eV. With porous surface morphology, the maximum response of 18% at 623 K substrate temperature is recorded on exposure of 350 ppm of CO2 gas.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. R.N. Bulakhe, C.D. Lokhande, Chemically deposited cubic structured CdO thin films: use in liquefied petroleum gas sensor. Sens. Actuators B 200, 245–250, (2014)

    Article  Google Scholar 

  2. Q. Wan, Q.H. Li, Y.J. Chen, T.H. Wang, X.L. He, J.P. Li, C.L. Lin, Fabrication and ethanol sensing characteristics of ZnO nanowire gas sensors. Appl. Phys. Lett. 84, 3654–3656 (2004)

    Article  Google Scholar 

  3. H.J. Kim, K.I. Choi, A. Pan, I.D. Kim, H.R. Kim, K.M. Kim, C.W. Na, G. Cao, J.H. Lee, Template free solvothermal synthesis of hollow hematite spheres and their applications in gas sensors and Li ion batteries. J. Mater. Chem. 11, 6549–6555 (2011)

    Article  Google Scholar 

  4. D. Gopalakrishna, K. Vijayalakshmi, C. Ravidhas, Effect of pyrolytic temperature on the properties of nano-structured Cuo optimized for ethanol sensing applications. J. Mater. Sci. 14, 1004–1011 (2013)

    Google Scholar 

  5. C. Sun, X. Su, F. Xiao, C. Niu, J. Wang, Synthesis of nearly monodisperse Co3O4 nanocubes via a microwave-assisted solvothermal process and their gas sensing properties. Sens. Actuators B 157, 681–685 (2011)

    Article  Google Scholar 

  6. D. Zhang, Z. Liu, C. Li, T. Tang, X. Liu, S. Han, B. Lei, C. Zhou, Detection of NO2 down to ppb levels using individual and multiple In2O3 nanowire devices. Nano Lett. 4, 1919–1924 (2004)

    Article  Google Scholar 

  7. N.H. Al-Hardan, M.J. Abdullah, A.A. Aziz, Sensing mechanism of hydrogen gas sensor based on RF-sputtered ZnO thin films. Int. J. Hydrog. Energy 35, 4428–4436 (2010)

    Article  Google Scholar 

  8. B. Liu, D. Cai, Y. Liu, H. Li, C. Weng, G. Zeng, Q. Li, T. Wang, High-performance room-temperature hydrogen sensors based on combined effects of Pd decoration and Schottky barriers. Nanoscale 5, 2505–2510 (2013)

    Article  Google Scholar 

  9. S.J. Patil, A.C. Lokhande, A.A. Yadav, C.D. Lokhande, Polyaniline/Cu2ZnSnS4 heterojunction based room temperature LPG sensor. J. Mater. Sci. 27, 7505–7508 (2016)

    Google Scholar 

  10. P. Menini, F. Parret, M. Guerrero, K. Soulantica, L. Erades, A. Maisonnat, B. Chaudret, CO response of a nanostructured SnO2 gas sensor doped with palladium and platinum, Sens, Actuators, B, 123, 111–114 (2003)

    Google Scholar 

  11. A. Kolmakov, D.O. Klenov, Y. Lilach, S. Stemmer, M. Moskovits, Enhanced gas sensing by individual SnO2 nanowires and nanobelts functionalized with Pd catalyst particles. Nano Lett. 5, 667–673 (2005)

    Article  Google Scholar 

  12. N. Barsan, U. Weimar, Conduction model of metal oxide gas sensors. J. Electroceram, 7, 143–167 (2001)

    Article  Google Scholar 

  13. J.X. Wang, X.W. Sun, Y. Yang, K.K.A. Kyaw, X.Y. Huang, J.Z. Yin, J. Wei, H.V. Demir, Free-standing ZnO–CuO composite nanowire array films and their gas sensing properties. Nanotechnology 22, 325704–325707 (2011)

    Article  Google Scholar 

  14. S.H. Lim, B. Radha, J.Y. Chan, M.S.M. Saifullah, G.U. Kulkarni, G.W. Ho, Flexible palladium based H2 sensor with fast response and low leakage detection by nanoimprint lithography. ACS Appl. Mater. Interfaces 5, 7274–7284 (2013)

    Article  Google Scholar 

  15. S.F. Chen, J.P. Li, K. Qian, W.P. Xu, Y. Lu, W.X. Huang, S.H. Yu, Large scale photochemical synthesis of M@TiO nanocomposites (M = Ag, Pd, Au, Pt) and their optical properties, CO oxidation performance, and antibacterial effect. Nano Res. 3, 244–245 (2010)

    Article  Google Scholar 

  16. A. Stanoiu, C.E. Simion, S. Somacescu, NO2 sensing mechanism of ZnO–Eu2O3 binary oxide under humid air conditions. Sens. Actuators B 186, 687–694 (2013)

    Article  Google Scholar 

  17. J. Chen, B. Lim, E.P. Lee, Y. Xia, Shape-controlled synthesis of platinum nanocrystals for catalytic and electrocatalytic applications. Nano Today 4, 81–95 (2009)

    Article  Google Scholar 

  18. K. Suematsu, Y. Shin, Z.Q. Hua, K. Yoshida, M. Yuasa, T. Kida, K. Shimanoe, Nanoparticle cluster gas sensor: controlled clustering of SnO2 nanoparticles for highly sensitive toluene detection. ACS Appl. Mater. Interfaces 6, 5319–5326 (2014)

    Article  Google Scholar 

  19. R.R. Salunkhe, V.R. Shinde, C.D. Lokhande, Liquefied petroleum gas (LPG) sensing properties of nanocrystalline CdO thin films prepared by chemical route: effect of molarities of precursor solution. Sens. Actuators B, 133, 296–301 (2008)

    Article  Google Scholar 

  20. C.L. Zhang, S.H. Yu, Nanoparticles meet electrospinning: recent advances and future prospects. Chem. Soc. Rev. 43, 4423–4435 (2014)

    Article  Google Scholar 

  21. A.A. Yadav, A.C. Lokhande, R.B. Pujari, J.H. Kim, C.D. Lokhande, The synthesis of multifunctional porous honey comb-like La2O3 thin film for supercapacitor and gas sensor applications. J. Colloid. Interface Sci. 484, 51–59, (2016)

    Article  Google Scholar 

  22. K.B. Jinesh, V.A. Dam, J. Swerts, C. Nooijer, S. Elshocht, S.H. Brongersma, M. Crego-Calama, Room-temperature CO2 sensing using metal–insulator–semiconductor capacitors comprising atomic-layer-deposited La2O3 thin film, Sens. Actuators B 156, 276–282 (2011)

    Article  Google Scholar 

  23. Y.M. Hunge, M.A. Mahadik, V.S. Mohite, S.S. Kumbhar, N.G. Deshpande, K.Y. Rajpure, A.V. Moholkar, P.S. Patil, C.H. Bhosale, Photoelectrocatalytic degradation of methyl blue using sprayed WO3 thin films. J. Mater. Sci. 27, 1629–1635 (2016)

    Google Scholar 

  24. Y.M. Hunge, M.A. Mahadik, V.S. Mohite, S.S. Kumbhar, N.G. Deshpande, K.Y. Rajpure, A.V. Moholkar, Photoelectrocatalytic degradation of methyl red using sprayed WO3 thin films under visible light irradiation. J. Mater. Sci. 26, 8404–8412 (2015)

    Google Scholar 

  25. A.A. Yadav, V.S. Kumbhar, S.J. Patil, N.R. Chodankar, C.D. Lokhande, Supercapacitive properties of chemically deposited La2O3 thin film. Ceram. Int. 16, 2079–2082 (2016)

    Article  Google Scholar 

  26. M.K. Zayed, M.A. Mostafa, M. Ebaid, Preparation and structural properties of sprayed lanthanum oxide films from an aqueous precursor. J. Mater. Sci. Eng. 12, 1–8 (2011)

    Google Scholar 

  27. A.A. Yadav, A.C. Lokhande, C.D. Lokhande, Simple chemical route for synthesis of microrods-like La2O3 thin film. Mater. Lett. 160, 500–503 (2015)

    Article  Google Scholar 

  28. A.A. Yadav, A.C. Lokhande, J.H. Kim, C.D. Lokhande, Improvement in CO2 sensing characteristics using Pd nanoparticles decorated La2O3 thin films. J. Ind. Eng. Chem. 49, 76–81 (2017)

    Article  Google Scholar 

  29. A.A. Yadav, A.C. Lokhande, J.H. Kim, C.D. Lokhande, Highly sensitive CO2 sensor based on microrods-like La2O3 thin film electrode. RSC Adv. 6, 106074–106080 (2016)

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Human Resources Development program (No. 20124010203180) of the Korea Institute of Energy Technology Evaluation and Planning (KETEP). Grant funded by the Korea government Ministry of Trade, Industry and Energy and supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (NRF-2015R1A2A2A01006856).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to J. H. Kim or C. D. Lokhande.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yadav, A.A., Lokhande, A.C., Shinde, P.A. et al. CO2 gas sensing properties of La2O3 thin films deposited at various substrate temperatures. J Mater Sci: Mater Electron 28, 13112–13119 (2017). https://doi.org/10.1007/s10854-017-7144-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-7144-7

Navigation