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A Review of Recent Progress on Nano MnO2: Synthesis, Surface Modification and Applications

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Abstract

This review highlights the synthesis, structure modification, morphology, and properties of nano manganese dioxide (MnO2). Though MnO2 has been widely employed for electrode materials due to its superior electrochemica1 performance, abundant storage, low cost, and environmental friendly nature, the usage in bioapplications and dye mineralisation studies have started since few decades only. Currently, nano MnO2 plays an important role in solar cell devices and gas sensing as it can be easily tunable into desired polymerphic structure and morphology. Herein, the use of nano MnO2 as advanced material in energy, gas sensing, biological application and wastewater remediation are described. Based on the recent research, the available preparation procedures, surface modification and applications of nanostructured MnO2 are systematically presented. Also, structure stabilization and performance improvement of nano MnO2 by doping or composite formation with metals, carbon materials, and conductive polymers are summerised. According to the latest research progress, new trends and strategies of nano MnO2 towards specific applications besides energy storage application are focused in this review, as well as a brief overview of the challenges and future perspectives of MnO2, synthetic methodologies, and their state-of-the-art applications in different fields are presented.

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Fig. 1
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Adapted with permission from Ref. [46] Copyright (2008) American Chemical Society

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Adapted from Ref. [49]

Fig. 5

Reproduced from Ref. [53] with permission from the Royal Society of Chemistry

Fig. 6

Reprinted from Ref. [55], Copyright (2015), with permission from Elsevier

Fig. 7

Adapted with permission from Ref. [69] Copyright (2016) American Chemical Society

Fig. 8

Reprinted from Ref. [76]. Copyright (2013), with permission from Elsevier

Fig. 9

Adapted with permission from Ref. [102]. Copyright (2017) American Chemical Society

Fig. 10

Adapted from Ref. [110]

Fig. 11

Reprinted from Ref. [119], Copyright (2009), with permission from Elsevier

Fig. 12

Adapted from Ref. [131]

Fig. 13

Reprinted from Ref. [140], Copyright (2017), with permission from Elsevier

Fig. 14

Adapted from Ref. [141]

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Adapted from Ref. [14]

Fig. 16

Adapted from Ref. [35]

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Adapted from Ref. [168]

Fig. 18

Reprinted with permission from Ref. [197]. Copyright (2014) American Chemical Society

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Acknowledgements

G. Zhang acknowledges the financial support provided by Key R & D plan of Yunnan Province (Item Code 2018IB020). Authors are thankful to National Natural Science Foundation of China (No. 51964032) for the financial support. A. Baral is grateful to Kunming University of Science and Technology for Post-Doctoral Fellowship.

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Authors and Affiliations

  1. Faculty of Metallurgy & Energy Engineering, Kunming University of Science & Technology, Kunming, 650093, Yunnan, China

    Ayonbala Baral & Shaohua Ju

  2. Department of Chemistry, Ravenshaw University, Cuttack, Odisha, 753003, India

    Lakkoji Satish

  3. Yunnan Province Energy Research Insititute Co Ltd, Kunming, 650000, China

    Guoying Zhang

  4. Hydro & Electrometallurgy Department, CSIR-Institute of Minerals and Materials Technology, Bhubaneswar, Odisha, 751013, India

    Malay K. Ghosh

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Baral, A., Satish, L., Zhang, G. et al. A Review of Recent Progress on Nano MnO2: Synthesis, Surface Modification and Applications. J Inorg Organomet Polym 31, 899–922 (2021). https://doi.org/10.1007/s10904-020-01823-z

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