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Extensions of a structural model for binary silicate systems

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Abstract

Our earlier structural model for binary silicate melts and glasses is extended. More general expressions for the enthalpy and nonconfigurational entropy are given. Expressions for partial thermodynamic properties are derived. A least-squares optimization program permits all available thermodynamic and phase diagram data to be optimized simultaneously within experimental error limits. The model is extended from MO-SiO2 to M2O-SiO2 solutions. Data in acidic melts is well represented for the Na2O-SiO2 system. Examples of optimizations for the MnO-SiO2, CaO-SiO2, and Na2O-SiO2 systems are presented. The model is extended to include sulfide ion. Good predictions of sulfide capacities are obtained.

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Authors and Affiliations

  1. Division de Ingenieria Metalurgica, E.S.I.Q.I.E.-I.P.N., C.P. 07300, Mexico

    Antonio Romero-Serrano (Assistant Professor)

  2. Centre for Research in Computational Thermochemistry, Ecole Polytechnique, H3C 3A7, Montreal, PQ, Canada

    Arthur D. Pelton (Professor and Co-Director)

Authors
  1. Antonio Romero-Serrano
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  2. Arthur D. Pelton
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Formerly Graduate Student, Centre for Research in Computational Thermochemistry, Ecole Polytechnique

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Romero-Serrano, A., Pelton, A.D. Extensions of a structural model for binary silicate systems. Metall Mater Trans B 26, 305–315 (1995). https://doi.org/10.1007/BF02660973

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  • DOI: https://doi.org/10.1007/BF02660973

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