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Nitrogen-Doped Carbon Nanotubes as an Effective Support of Heterogeneous Catalysts for Selective Alkene Oxidation

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Abstract

Nitrogen-doped carbon nanotubes (N-CNTs) with different degrees of nitrogen doping were synthesized. The effects of nitrogen in the N-CNTs on the hydrophilic–hydrophobic properties of carbon nanotubes and their activity in the decomposition of Н2О2 were studied. Various approaches to the surface modification of N-CNTs by alkyl groups were studied, and the high resistance of N-CNTs to alkylation was found. Heterogeneous catalysts based on the polyoxometallate [PO4{WO(O2)2}4]3– and N-CNTs with a low degree of nitrogen doping (≤1.8 at %) were successfully synthesized. The high efficiency of the catalysts in the liquid-phase reactions of selective oxidation of alkenes using H2O2 as a green oxidizer was found, and the heterogeneous nature of catalysis was confirmed.

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ACKNOWLEDGMENTS

We are grateful to O.A. Nikolaeva for studying the samples by a TPO method.

Funding

This work was supported by the Russian Foundation for Basic Research (grant no. 18-33-00764) and the Ministry of Science and Higher Education (project no. AAAA-A17-117041710084-2). The studies were carried out using the equipment of the Center of Collective Use “National Center for Catalyst Research.”

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. N. Suboch, V. Yu. Evtushok, L. S. Kibis, O. A. Kholdeeva & O. Yu. Podyacheva

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  1. A. N. Suboch
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  2. V. Yu. Evtushok
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  3. L. S. Kibis
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  4. O. A. Kholdeeva
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  5. O. Yu. Podyacheva
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Correspondence to A. N. Suboch.

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Translated by V. Makhlyarchuk

Abbreviations and designations: CNTs, carbon nanotubes; N‑CNTs, nitrogen-containing carbon nanotubes; POMs, polyoxometallates; PW4, the tetranuclear phosphotungstate [PO4{WO(O2)2}4]3–; NPy, NPyr, NQ, and NOx, pyridine-like, pyrrole, graphite-like, and oxidized structural positions, respectively; TG, thermogravimetry; DTA, differential thermal analysis; DSC, differential scanning calorimetry; TPO, temperature-programmed oxidation; XPS, X-ray photoelectron spectroscopy.

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Suboch, A.N., Evtushok, V.Y., Kibis, L.S. et al. Nitrogen-Doped Carbon Nanotubes as an Effective Support of Heterogeneous Catalysts for Selective Alkene Oxidation. Kinet Catal 62, 288–298 (2021). https://doi.org/10.1134/S0023158421020105

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