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Effects of Microstructure and Material Composition on the Formation Kinetics of Passive Film and Pitting Behavior of Super 13Cr Stainless Steel

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Abstract

The effects of the microstructure and material composition on the formation kinetics of passive film and pitting behavior of super 13Cr stainless steel (S13Cr SS) were investigated and compared with those of 2Cr13 stainless steel (2Cr13 SS). The results indicated that the passive film formed on S13Cr SS surface quickly reached a stable state, which was attributed to two reasons. The small grain size coupled with the high dislocations density increased the number of nucleation sites for passive film formation, and the high material composition enhanced the Cr and Mo compound contents in the passive film. The passive film on S13Cr SS was more compact and thicker than that on 2Cr13 SS. The pit depth on S13Cr SS was relatively shallow after potentiodynamic polarization. Therefore, the protective properties of the passive film on S13Cr SS increased, and the pitting corrosion resistance of S13Cr SS was enhanced.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 51571027) and the National Key R&D Program of China (No. 2016YFE0203600).

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Authors and Affiliations

  1. Corrosion and Protection Center, Institute for Advanced Materials and Technology, University of Science and Technology, Beijing, Beijing, 100083, P.R. China

    Yonggang Zhao, Wei Liu, Baojun Dong, Yutao Wang, Yueming Fan, Tianyi Zhang & Wongpat Banthukul

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  1. Yonggang Zhao
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Correspondence to Wei Liu.

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Manuscript submitted October 7, 2020; accepted February 13, 2021.

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Zhao, Y., Liu, W., Dong, B. et al. Effects of Microstructure and Material Composition on the Formation Kinetics of Passive Film and Pitting Behavior of Super 13Cr Stainless Steel. Metall Mater Trans A 52, 1985–1998 (2021). https://doi.org/10.1007/s11661-021-06208-6

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