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Adsorption behavior and mechanism of action of magnetic MIL-100(Fe) on MB

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Abstract

Dye wastewater seriously affects human living environment and human health. This experiment develops green and efficient recyclable Fe3O4@MIL-100(Fe) under room temperature conditions. The microscopic morphology, chemical structure and magnetic properties of Fe3O4@MIL-100 (Fe) were characterized by SEM, FT-IR, XRD and VSM, and the adsorption capacity and adsorption mechanism of the adsorbent on methylene blue (MB) were investigated. The results showed that MIL-100(Fe) was successfully grown on Fe3O4, and the composite had excellent crystalline shape and morphology and good magnetic response. The specific surface area of Fe3O4@MIL-100(Fe) is 1203.18 m2 g−1 by N2 adsorption isothermal curve, and MIL-100(Fe) still has high specific surface area after compounding with magnetic particles. The adsorption process follows the quasi-level kinetic equation and the Langmuir isothermal model, according to which the adsorption capacity of Fe3O4@MIL-100 (Fe) on MB can be up to 487.8 mg g−1 for a single molecular layer. The thermodynamic experiments show that the adsorption of MB by the adsorbent is a spontaneous heat absorption process. In addition, the adsorption amount of Fe3O4@MIL-100 (Fe) on MB was still maintained at 88.4% after 6 cycles with good reusability, and its crystalline shape did not change significantly, indicating that Fe3O4@MIL-100 (Fe) can be used as an efficient and regenerable adsorbent for the treatment of printing and dyeing wastewater.

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Acknowledgements

The authors acknowledge the following: Thanks to Professor Wu Ying for her help in all aspects. Acknowledgement of support for the project on efficient degradation of ammonia and nitrogen contaminants in urban drinking water (1120018).

Funding

This study was supported by a research project on the efficient degradation of ammonia and nitrogen contaminants in urban drinking water (1120018). The South Xinjiang Innovation and Development Program of Key Industries of Xinjiang Production and Construction Corps (Grant No. 2020DB002).

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Authors and Affiliations

  1. Key Laboratory of Protection and Utilization of Biological Resources in Tarim Basin, Xinjiang Production and Construction Corps, Xinjiang, 843300, Alar, China

    Qiaofang Fu & Ying Wu

  2. College of Life Science and Technology, Tarim University, Alar, 843300, Xinjiang, China

    Qiaofang Fu

  3. College of Chemistry and Chemical Engineering, Tarim University, Alar, 843300, Xinjiang, China

    Ying Wu

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  1. Qiaofang Fu
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QF conceived, drafted and approved this research article. Conceptualization: YW. Data compilation: QF. Funding acquisition: YW. Methodology: QF. Role/writing—original draft: QF. Writing—review and editing: QF and YW. All authors read and approved the manuscript.

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Correspondence to Ying Wu.

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Fu, Q., Wu, Y. Adsorption behavior and mechanism of action of magnetic MIL-100(Fe) on MB. Environ Monit Assess 195, 745 (2023). https://doi.org/10.1007/s10661-023-11282-x

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