Skip to main content
Log in

Hydroxyphenyl-s-triazines: advanced multipurpose UV-absorbers for coatings

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

In recent years, the industry has succeeded in achieving adequate performance of coatings for automotive, industrial, and decorative applications, both in terms of mechanical and aesthetical properties. Nevertheless, there is an increasing demand for novel light stabilizers which can meet even today’s higher performance and quality requirements as well as cost pressures. It is well known, for example in the automotive industry, that UV-absorbers (UVA) based on hydroxyphenyl-s-triazines (HPT) are capable of fulfilling these requirements where 2-(2-hydroxyphenyl)-benzotriazoles (BTZ) tend to fail or show inferior properties. Besides the well-known HPT for automotive applications, other high-performance products have been developed for an even broader range of applications comprising, for example, thin- or reduced-film applications, powder coatings, and extremely durable wood coatings. New encapsulation techniques make it even possible to convert most of these hydrophobic products into highly compatible and stable water-based product forms. This opens the door for the advanced HPT UVA for a broad range of possible waterborne and solventborne applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Valet, A, Light Stabilizers for Paints, pp. 45–128, CR Vincentz Verlag, Hannover, (1997) ISBN 3 87870 443 7

  2. Pospisil J, Nespurek S (2000) Photostabilisation of Coatings. Mechanisms and Performance. Prog. Polym. Sci. 25(9):1261–1335

    Article  CAS  Google Scholar 

  3. Bauer DR (1995) Kinetics of Photooxidation and Photostabilisation in Cross-linked Polymer Coatings. Polym. Degrad. Stabil. 48:259–267

    Article  CAS  Google Scholar 

  4. Klemchuk P, Gande M, Cordola E (1990) Hindered Amine Mechanisms. III: Investigations Using Isotopic Labeling. Polym. Degrad. Stabil. 27:65–74

    Article  CAS  Google Scholar 

  5. Pospisil, J, Klemchuk, PP, “Oxidative Deterioration Processes in Organic Materials.” In: Pospisil, J, Klemchuk, PP (eds) Oxidation Inhibition in Organic Materials, vol. 1, pp. 1–10. Boca Raton: CRC Press (1990)

  6. Mielewski DF, Bauer DR, Gerlock JL(1993) Determination of Hydroperoxide Concentrations in Cross-linked Polymer Coatings Containing Hindered Amine Light Stabilizers. Polym. Degrad. Stabil. 41:323–331

    Article  CAS  Google Scholar 

  7. Kramer HEA (1990) Wirkungsweise von Stabilisatoren in Polymeren unter Berücksichtigung der 2-Hydroxyphenylbenzotriazole. Die Angewandte Makromolekulare Chemie 183(1):67–101

    Article  CAS  Google Scholar 

  8. Fairgrieve SP, MacCallum JR (1984) Hindered Amine Light Stabilisers: A Proposed Photo-stabilisation Mechanism. Polym. Degrad. Stabil. 8:107–121

    Article  CAS  Google Scholar 

  9. Gerlock JL, Bauer DR, Briggs LM, Dickie RA (1985) A Rapid Method of Predicting Coating Durability Using Electron Spin Resonance. J. Coat. Technol. 57(722):37–46

    Google Scholar 

  10. Keck, J, Stüber, GJ, Kramer, HEA, “Deactivation Processes of 2-Hydroxyphenyl-1,3,5-Triazines: Polymeric and Monomeric UV Absorbers of the Benzotriazole and Triazine Class.” Angewandte Macromolekulare Chemie, 252 119–138 (1997)

    Google Scholar 

  11. Decker C, Biry S, Zahouily K (1995) Photostabilisation of Organic Coatings. Polym. Degrad. Stabil. 49:111–119

    Article  CAS  Google Scholar 

  12. Stährfeld, A, Braig, A, “Advanced UV Protection of Automotive Clear Coatings.” Proceedings from XXVI FATIPEC Congress, Dresden, Germany, 2002

  13. Peter, W, Schellenberg, C, Rogez, D, Schaller, C, Kalscheur, G, “New Concepts for Improved Durability of Water-Borne Wood Coatings.” Proceedings from the Coating Wood and Wood Composites Conference, Charlotte, NC, 2005

  14. Peter, W, Schaller, C, Schellenberg, C, Rogez, D, “A New Concept of Aqueous Additive Preparations for Water-Borne Coatings.” Proceedings from the Water-borne and High-solids Coatings Conference, Brussels, Belgium, 2006

  15. Cliff, N, Adamson, K, Yaneff, P, “Reactable Light Stabilisers for Automotive Coatings Over Plastics.” Proceedings from the International Coatings for Plastics Symposium, Troy, MI, 2001

  16. Cliff, N, Peters, C, “The Use of Reactable Light Stabilisers to Prevent Migration and Improve Durability of Coatings on Plastic Substrates.” Proceedings from the International Coatings for Plastics Symposium, Troy, MI, 2003

  17. Zeren, S, “UV Stabilisation of Powder Clear Coats.” Proceedings from the XXVI FATIPEC Congress, Dresden, Germany, 2002

  18. Rogez, D, “Colour Stabilisation of Wood and Durability Improvement of Wood Coatings.” Proceedings form the 2nd Wood Coatings Congress, The Hague, Netherlands, 2000

  19. Hayoz, P, Peter, W, Rogez, D, “Improved Photo-protection of Wood and Durability Improvement of Wood Coatings.” Proceedings from the 3rd Wood Coatings Congress, The Hague, Netherlands, 2002

  20. Rogez, D, “Colour Stabilisation of Wood and Durability Improvement of Wood Coatings.” Paint Coating Indust. Magazine, www.pcimag.com (site checked 21st July 2006), March 2002

  21. Leary GJ (1994) Recent Progress in Understanding and Inhibiting the Light-induced Yellowing of Mechanical Pulps. J. Pulp Paper Sci. 20(6):154–160

    CAS  Google Scholar 

  22. Hayoz P, Peter W, Rogez D (2003) Colour and Light Stabilisation of Untreated and Stained Wood for Indoor Use. Farbe Lack 109(7):26–33

    CAS  Google Scholar 

  23. Hayoz P, Peter W, Rogez D (2003) Improved Photoprotection of Wood Substrates Part I: Colour Stabilisation of Natural and Stained Wood for Indoor Applications. Asia Pacific Coat. J. 16(2):14–20

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to C. Schaller.

Additional information

Presented at XXVIIIth FATIPEC Congress, organized jointly by the Hungarian Chemical Society (MKE) and the Polish Association of Chemical Engineers (SITPCHEM), in Budapest, Hungary, June 12–14, 2006.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schaller, C., Rogez, D. & Braig, A. Hydroxyphenyl-s-triazines: advanced multipurpose UV-absorbers for coatings. J Coat Technol Res 5, 25–31 (2008). https://doi.org/10.1007/s11998-007-9025-0

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-007-9025-0

Keywords

Navigation