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Infrared spectra of Hoffmann-T d -type benzene clathrates

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Abstract

Six new title compounds in the form of Cd(cyclobutylamine)2M′(CN)4 · 2G (M′ = Cd or Hg; G = benzene, 1,2-dichlorobenzene, or 1,3-dichlorobenzene) have been prepared in powder form. Their spectral data were found to be consistent with the structure of the Hofmann-T d -type clathrates.

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References

  • Akyüz, S., & Davies, J. E. D. (1982). Solid-state vibrational spectroscopy. Part 11. An infrared and raman vibrational spectroscopic study of metal(II) halide aniline complexes. Journal of Molecular Structure 95, 157–168. DOI: 10.1016/0022-2860(82)90141-7.

    Article  Google Scholar 

  • Bayarı, S., Kantarcı, Z., & Akyüz, S. (1994). An infrared and Raman spectroscopic study of T d-type 4,4′-bipyridylcadmium(II) tetracyanometallate(II) benzene (1/2) clahrates: Cd(C10H8N2)Cd(CN)4 · 2C6H6 and Cd(C10H8N2)Hg(CN)4 · 2C6H6. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 17, 291–302. DOI: 10.1007/BF00708788.

    Article  Google Scholar 

  • Ekici, N., Kantarcı, Z., & Akyüz, S. (1991). An infrared and Raman spectroscopic study of pyrazinecadmium(II) tetracyanometallate(II) benzene (1/1) clathrates: Cd(C4H4N2) Cd(CN)4 · C6H6 and Cd(C4H4N2)Hg(CN)4 · C6H6. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 10, 9–18. DOI: 10.1007/BF01041635.

    Article  CAS  Google Scholar 

  • Gerlach, P. N., & Powell, B. M. (1986). Crystal structures and phase transition of the cyanospinel K2Hg(CN)4. Journal of Chemical Physics, 85, 6004–6009. DOI: 10.1063/1.451514.

    Article  CAS  Google Scholar 

  • Green, J. H. S. (1970a). Vibrational spectra of benzene derivatives-VIII. m-Disubstituted compounds. Spectrochimica Acta, 26A, 1523–1533. DOI: 10.1016/0584-8539(70)80213-6.

    Google Scholar 

  • Green, J. H. S. (1970b). Vibrational spectra of benzene derivatives-IX. o-Disubstituted compounds. Spectrochimica Acta, 26A, 1913–1923. DOI: 10.1016/0584-8539(70)80129-5.

    Google Scholar 

  • Iwamoto, T. (1996). Past, present and future of the clathrates inclusion compounds built of cyanometallate hosts. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 24, 61–132. DOI: 10.1007/BF01053426.

    Article  CAS  Google Scholar 

  • Iwamoto, T. (1984). The Hofmann-type and related inclusion compounds. In J. L. Atwood, J. E. D. Davies, & D. D. Mac Nicols (Eds.), Inclusion compounds (pp. 29–57). New York: Academic Press.

    Google Scholar 

  • Iwamoto, T., Kiyoki, M., Ohtsu, Y., & Takeshige-Kato, Y. (1978). The analogs of Hofmann type clathrate formed between diammine-or diaminemetal(II) tetracyanometallate(II) host and aromatic guest molecule. Bulletin of the Chemical Society of Japan, 51, 488–491. DOI: 10.1246/bcsj.51.488.

    Article  CAS  Google Scholar 

  • Jones, L. H. (1961). Vibrational spectrum and structure of metal cyanide complexes in the solid state-V: K2Zn(CN)4, K2Cd(CN)4 and K2Hg(CN)4. Spectrochimica Acta, 17, 188–200. DOI: 10.1016/0371-1951(61)80064-7.

    Article  CAS  Google Scholar 

  • Kalasinsky, V. F., Guirgis, G. A., & Durig, J. R. (1977). Spectra and structure of small ring compounds: Part XXXV. Vibrational spectra and ring-puckering and torsional potential functions of cyclobutylamine. Journal of Molecular Structure, 39, 51–65. DOI: 10.1016/0022-2860(77)85034-5.

    Article  CAS  Google Scholar 

  • Kantarcı, Z., & Bayrak, C. (1998). Vibrational spectroscopic studies on the tn-Td-type Mn(tn)Zn(CN)4 · 2C6H6 and the Chelated tn-Td-type Zn(tn)Zn(CN)4 · 2C6H6 clathrates. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 30, 59–68. DOI: 10.1023/A:1007957029816.

    Article  Google Scholar 

  • Kantarcı, Z., Bayrak, C., & Bayar, S. (1997). An infrared and Raman spectroscopic study on the Hofmann-T d-type complexes: ML2M′(CN)4, M = Mn or Zn, M′ = Zn, Cd or Hg, L = pyridine, α-, β-or γ-picoline. Journal of Molecular Structure, 407, 155–163. DOI: 10.1016/S0022-2860(96)09739-6.

    Article  Google Scholar 

  • Kantarcı, Z., Bayrak, C., & Kasap, E. (1999). An infrared and Raman spectroscopic study of pn-Td-type dl-propylenediaminemetal(II) tetracyanometallate(II) benzene clathrates: M(dl-pn)M′(CN)4 · nC6H6 (M = Mn, M′ = Zn, Cd or Hg; M = Cd, M′ = Cd or Hg; 1≤n≤1.5). Journal of Inclusion Phenomena and Macrocyclic Chemistry, 33, 285–294. DOI: 10.1023/A:1008004731695.

    Article  Google Scholar 

  • Kantarcı, Z., Karabacak, M., & Bülbül, M. M. (2001). Infrared spectroscopic study on the Td-type clathrates: Cd(Cyclohexylamine)2M(CN)4 · 2C6H6 (M = Cd or Hg). Journal of Inclusion Phenomena and Macrocyclic Chemistry, 40, 317–321. DOI: 10.1023/A:1013882611133.

    Article  Google Scholar 

  • Kantarcı, Z., Karacan, N., & Davarcıolu, B. (1994). Infrared spectroscopic studies on the Hofmann-T d-type complexes. Journal of Molecular Structure, 323, 53–58. DOI: 10.1016/0022-2860(94)07985-4.

    Article  Google Scholar 

  • Kasap, E., & Kantarcı, Z. (1995). Vibrational spectroscopic studies on the en-T d-type benzene clathrates: M(ethylenediamine)M′(CN)4 · 2C6H6 (M=Mn or Cd, M′=Cd or Hg). Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 23, 1–9. DOI: 10.1007/BF00706944.

    Article  CAS  Google Scholar 

  • Kuroda, R. (1973). A new type clathrate compound: The crystal structure of Cd(NH3)2Hg(CN)4 · 2C6H6. Inorganic and Nuclear Chemistry Letters, 9, 13–18. DOI: 10.1016/0020-1650(73)80078-9.

    Article  CAS  Google Scholar 

  • Nishikiori, S., Iwamoto, T., & Yashino, Y. (1980). Three-dimensional metal complex structures with ambident propylene-diamine ligands serving as the hosts of the aromatic guest molecules. Hofmann-pn and pn-Td type clathrates. Bulletin of the Chemical Society of Japan, 53, 2236–2240. DOI: 10.1246/bcsj.53.2236.

    Article  CAS  Google Scholar 

  • Painter, P. C., & Koening, J. L. (1977). Liquid phase vibrational spectra of 13C-isotops of benzene. Spectrochimica Acta, 33A, 1003–1018. DOI: 10.1016/0584-8539(77)80102-5.

    CAS  Google Scholar 

  • Ruiz, E., Novoa, J. J., & Alvarez, S. (1995). Ab initio study of the intermolecular interactions in the Hofmann clathrates. The Journal of Physical Chemistry, 99, 2296–2306. DOI: 10.1021/j100008a010.

    Article  CAS  Google Scholar 

  • Scherer, J. R., & Evans, J. C. (1963). Vibrational spectra and assignments for sixteen chlorobenzenes. Spectrochimica Acta, 19, 1739–1775. DOI: 10.1016/0371-1951(63)80193-9.

    Article  CAS  Google Scholar 

  • Suzuki, S., Orville-Thomas, W. J., Sopkova, A., & Skorespa, J. (1979). Infrared and Raman studies on the Hofmann-type clathrates Ni(NH3)2Pd(CN)4 · 2C6H6 and Cd(NH3)2Ni(CN)4 · 2C4H4S. Journal of Molecular Structure,, 54, 1–9. DOI: 10.1016/0022-2860(79)80049-6.

    Article  CAS  Google Scholar 

  • Yuge, H., & Iwamoto, T. (1992). Crystal structures ofcatena-[diligatocadmium(II) tetra-µ-cyanocadmate(II)] host clathrates: Diamminecadmium(II) tetracyanocadmate(II)-benzene(1/2), diamminecadmium (II) tetracyanocadmate(II)-aniline(1/2), ethylenediaminecadmium(II) tetracyanocadmate(II)-aniline(1/2), and a novel type bis(aniline)cadmium(II) tetracyano-cadmate(II)-Aniline(2/1). Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 14, 217–235. DOI: 10.1007/BF01045982.

    Article  CAS  Google Scholar 

  • Yuge, H., & Iwamoto, T. (1993). Cyano-linked structures in polymeric cadmium cyanide-pyridine (py) and isoquinoline (iquin) complexes: Crystal structures of [Cd(py)2][Cd(CN)4], [{Cd(CN)(py)2}3][Cd2(CN)7] and [Cd(iquin)2][Cd(CN)3(iquin)2]2. Journal of the Chemical Society, Dalton Transactions, 18, 2841–2847. DOI: 10.1039/DT9930002841.

    Article  Google Scholar 

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  1. Fen Fakültesi, Fizik Bölümü, Yunusemre Kampüsü, Anadolu Üniversitesi, TR26470, Eskişehir, Turkey

    Meryem T. Aytekin & Mustafa Şenyel

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  1. Meryem T. Aytekin
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  2. Mustafa Şenyel
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Correspondence to Meryem T. Aytekin.

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Aytekin, M.T., Şenyel, M. Infrared spectra of Hoffmann-T d -type benzene clathrates. Chem. Pap. 62, 472–479 (2008). https://doi.org/10.2478/s11696-008-0053-8

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