Abstract
Two new benzene clathrates of the form Cd(4,4′-bipyridyl)M(CN)4 · 2C6H6, (M=Cd or Hg) have been prepared in powder form. Their spectral data were compared with those of the corresponding host complexes and found to be consistent with the host structure found in Td-type clathrates.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
N. Ekici, Z. Kantarci, and S. Akyüz:J. Incl. Phenom. 10, 9 (1991).
R. Kuroda:Inorg. Nucl. Chem. Lett. 9, 13 (1973).
T. Iwamoto and D.F. Shriver:Inorg. Chem. 11, 2570 (1972).
T. Iwamoto:J. Mol. Struct. 75, 51 (1981).
S. Nishikiori and T. Iwamoto:J. Incl. Phenom. 3, 283 (1985).
A. Sungur, S. Akyüz, and J.E.D. Davies:J. Incl. Phenom. 5, 491 (1987).
A. Sungur: Ph.D. Thesis, Physics Department, Faculty of Science, Hacettepe University, Beytepe, Ankara, Turkey.
H. Kiharo and Y. Gondo:J. Raman Spectrosc. 17, 263 (1986).
V.P. Gupta:Indian J. Pure App. Phys. 11, 775 (1973).
J. Metz, O. Schneider and M. Hanack:Spectrochim. Acta 38A, 1265 (1982).
P.C. Painter and J.L. Koening:Spectrochim. Acta 33A, 103 (1977).
J.E.D. Davies, A.B. Dempster and S. Suzuki:Spectrochim. Acta 30A, 1183 (1974).
E.B. Wilson:Phys. Rev. 45, 706 (1934).
S. Akyüz, A.B. Dempster, and R.L. Morehouse:Spectrochim. Acta 30A, 1989 (1974).
S. Suzuki, W.J. Orville-Thomas, A. Sopkova, and J. Skorsepa:J. Mol. Struct. 54, 1 (1979).
R.D. Kross, V.A. Fassel, and M. Margoshes:J. Am. Chem. Soc. 78, 1332 (1956).
C.A. Coulson:V. Henri Mem. Not.: Desoer, Liège, p. 15 (1948).
J. Duchesne:Bull. Acad. Roy. Belg. 38, 197 (1952).
J.W. Linnett and P.J. Wheatley:Nature 161, 971 (1948)Trans. Faraday Soc. 45, 33 (1949).
T. Iwamoto and Y. Otsu:Chem. Lett., 463 (1972).
L.H. Jones:Spectrochim. Acta 17, 188 (1961).
B. Ziegler and D. Babel:Z. Naturforsch. 46B, 47 (1991).
P.N. Gerlach and B.M. Powell:J. Chem. Phys. 85, 6004 (1986).
H. Yuge and T. Iwamoto:J. Incl. Phenom. 14, 217 (1992).
H. Yuge and T. Iwamoto:J. Chem. Soc. Dalton Trans., 2841 (1993).
Z. Kantarci:Commun. Fac. Sci. Univ. Ankara 37, 53 (1988).
Y. Mathey, C. Mazieres and R. Setton:Inorg. Nucl. Chem. Lett. 13, 1 (1977).
T. Kitazawa, S. Nishikiori, R. Kuroda, and T. Iwamoto:Chem. Lett., 459 (1988).
T. Kitazawa, S. Nishikiori, R. Kuroda, and T. Iwamoto:Chem. Lett., 1729 (1988).
T. Kitazawa, S. Nishikiori, A. Yamagishi, R. Kuroda, and T. Iwamoto:J. Chem. Soc. Chem. Commun., 413 (1990).
B.F. Abrahams, B.F. Hoskins, and R. Robson:J. Chem. Soc. Chem. Commun., 60 (1990).
B.F. Abrahams, B.F. Hoskins, J. Liu, and R. Robson:J. Am. Chem. Soc. 113, 3045 (1991).
J. Kim, D. Whang, J.I. Lee, and K. Kim:J. Chem. Soc. Chem. Commun., 1400 (1993).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bayari, S., Kantarci, Z. & Akyüz, S. An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates: Cd(C10H8N2)Cd(CN)4 · 2C6H6 and Cd(C10H8N2)Hg(CN)4 · 2C6H6 . J Incl Phenom Macrocycl Chem 17, 291–302 (1994). https://doi.org/10.1007/BF00708788
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00708788