Abstract
The fluorinated copolymer of ethyl methacrylate and butyl acrylate was prepared by one pot, the optimization dosages of the cross-linker and monomer were determined. The structure was characterized by FTIR spectroscopy, and the smooth surface can be observed by SEM. The effect of the hexafluorobutyl methacrylate on the surface properties of the product was investigated by measurement of contact angle. The results revealed the fluorinated copolymer have good hydrophobicity and better anti-aging, which could be easily adjusted by controlling the content of the hexafluorobutyl methacrylate. The maximum value of contact angle was 129°C, while the minimum rate of weight loss of the products was 0.84% after 30 days under UV radiation. The mechanical properties analysis shows that fluorinated copolymer exhibits good compressive strength, and the maximum value is 94.5 MPa.
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REFERENCES
R. Striani, C. Esposito Corcione, G. Dell’anna Muia, and M. Frigione, Prog. Org. Coat. 101, 1 (2016).
G. Pia, C. Esposito Corcione, R. Striani, L. Casnedi, and U. Sanna, Prog. Org. Coat. 94, 105 (2016).
V. Gomes, A. Dionisio, and J. S. Pozo-Antonio, Prog. Org. Coat. 113, 90 (2017).
P. Baglioni, D. Berti, M. Bonini, E. Carretti, L. Dei, E. Fratini, and R. Giorgi, Adv. Colloid Interface Sci. 205, 361 (2014).
E. Carretti, D. Chelazzi, G. Rocchigiani, P. Baglioni, G. Poggi, and L. Dei, Langmuir 29, 9881(2013).
C. E. Corcione, R. Striani, and M. Frigione, Prog. Org. Coat. 77, 1117 (2014).
E. Carretti, L. Dei, and P. Baglioni, Langmuir 19, 7867 (2003).
M. I. Totolin and I. Neamtu, J. Cult. Heritage 12, 392 (2011).
X. Zhang, W. Wen, H. Yu, F. Qiu, Q. Chen, and D. Yang, J. Polym. Res. 23 (4), 1 (2016).
G. Rizzo, L. Ercoli, and B. Megna, Strain 45, 424 (2009).
M. Favaro, R. Mendichi, F. Ossola, U. Russo, S. Simon, P. Tomasin, and P. A. Vigato, Polym. Degrad. Stab. 91, 3083 (2006).
H. Zhang, Q. Liu, T. Liu, and B. Zhang, Prog. Org. Coat. 76, 1127 (2013).
Y. Cao, A. Salvini, and M. Camaiti, Prog. Org. Coat. 111, 164 (2017).
W. Yao, Y. Li, and X. Huang, Polymer 55, 6197 (2014).
V. Roche, F. Vacandio, D. Bertin, and Y. Massiani, J. Electroceram. 16, 41 (2006).
A. Farahi, F. Bentiss, C. Jama, M. El Mhammedi, and M. Bakasse, J. Alloys Compd. 723, 1032 (2017).
B.Simionescu, M. Aflori, and M. Olaru, Constr. Build. Mater. 23, 3426 (2009).
L. de Ferri, P. P. Lottici, A. Lorenzi, A. Montenero, and E. Salvioli-Mariani, J. Cult. Heritage 12, 356 (2011).
C. Ma, L. Cao, X. Wang, L. Zhang, M. Shi, and J. Wang, J. Supercrit. Fluids 62, 232 (2012).
L. Cao, C. Ma, J. Wang, and P. Chen, J. Supercrit. Fluids 75, 152 (2013).
Y. Sun and W. Liu, J. Polym. Res. 19, 1 (2012).
C. Tang, W. Liu, S. Ma, Z. Wang, and C. Hu, Prog. Org. Coat. 69, 359 (2010).
S. Ozbay and H. Y. Erbil, Colloids Surf., A 452, 9 (2014).
P. Chen, R. Wu, J. Wang, Y. Liu, C. Ding, and S. Xu, J. Polym. Res. 19, 9825 (2012).
K. Matsubara, M. Danno, M. Inoue, H. Nishizawa, Y. Honda, and T. Abe, Surf. Coat. Technol. 236, 269 (2013).
T. Nishino, M. Meguro, K. Nakamae, M. Matsushita, and Y. Ueda, Langmuir 15, 4321 (1999).
T. L. Zheng, X. Wang, Y. B. Li, and B. Q. Chen, Mater. Sci. Forum 546–549, 2237 (2007).
ACKNOWLEDGMENTS
The authors gratefully acknowledge the financial supports from Foundation of Hebei Province and Chengde (nos. QN2016331, CZ2014005, 201601A094).
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Chuang Ma, Wang, H., Zhang, H. et al. Preparation and Properties of Fluorinated Poly(ethyl methacrylate-co-butyl acrylate). Polym. Sci. Ser. B 61, 163–169 (2019). https://doi.org/10.1134/S1560090419020076
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DOI: https://doi.org/10.1134/S1560090419020076