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Influence of Type of Organic Template on the Properties of Zeolites ZSM-23

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The influence of the type of organic template from the series: pyrrolidine, dimethylformamide, N-methylpyrrolidone on the physicochemical properties of zeolite of MTT structure (ZSM-23) was studied. The optimal composition of the reaction mixture and the synthesis conditions of ZSM-23 were determined for each template. The use of relatively inexpensive organic templates, dimethylformamide and N-methylpyrrolidone, makes it possible to obtain phase-pure zeolite of MTT topology with SiO2/Al2O3 ratio from 60 to 100, the acid characteristics of which are similar to zeolites obtained with pyrrolidine expensive and not produced in Russia. The synthesis with use of dimethylformamide allows obtaining zeolite ZSM-23 with a yield of more than 95% calculated in term of silica spent and improved texture characteristics: the micropore volume 0.08–0.09 cm3 g−1, the total pore volume 0.3–0.35 cm3 g−1. An analysis of the features of the syntheses with different templates exhibited that dimethylformamide can be considered as the most suitable for use in producing MTT zeolite (ZSM-23).

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Funding

This work was financially supported by the Ministry of Education and Science of the Russian Federation in the framework of the federal target program “Research and Development in Priority Directions for the Development of the Russian Science and Technology Complex for 2014–2020” under the Agreement on the provision of subsidy no. 14.610.21.0009 dated 03.10.2017 (unique project identifier RFMEFI61017X0009).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    L. V. Piryutko, M. V. Parfenov, A. I. Lysikov & E. Yu. Gerasimov

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  1. L. V. Piryutko
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  2. M. V. Parfenov
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  3. A. I. Lysikov
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  4. E. Yu. Gerasimov
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Correspondence to L. V. Piryutko.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 12, pp. 1550–1560.

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Piryutko, L.V., Parfenov, M.V., Lysikov, A.I. et al. Influence of Type of Organic Template on the Properties of Zeolites ZSM-23. Russ J Appl Chem 92, 1664–1673 (2019). https://doi.org/10.1134/S1070427219120061

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