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Low-temperature synthesis, structure, sorption properties and acidity of zeolite ZSM-5

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Abstract

High structure-directing activity and specificity of templating action of tetrapropylammonium cations TPA+ as well as high concentration of framework-forming substances in the initial reaction mixtures contribute to the formation of zeolite ZSM-5 at relatively low temperature (100 °C) in the alkali-free media. Zeolite ZSM-5 obtained at 100 °C has higher micropore and mesopore volumes, specific surface area, less uniform micropore size distribution in comparison with ZSM-5 synthesized at 170 °C in an alkaline medium in the presence of hydrated Na+ cations. Samples synthesized at 100 °C possess a lower concentration of acid sites and broader distribution of them in strength, compared with ZSM-5 obtained at 170 °C in an alkaline medium. ZSM-5 obtained at 100 °C exhibits a high catalytic activity in the reaction of cracking of cumene, as well as a higher selectivity to propylene and styrene, in comparison with isostructural analogue obtained at 170 °C in an alkaline medium. It is assumed that the investigated alkali-free reaction mixtures and the corresponding sol-precursors of zeolite ZSM-5 containing the elements of secondary building units can be used for obtaining of micro-mesoporous aluminosilicates in the conditions of low-temperature synthesis (100 °C) by dual-template method—in the presence of molecular and micellar templates.

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Acknowledgments

The authors express their gratitude to Yulia Voloshyna and Maria Krylova from Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of Ukraine for the carrying out the test reaction of catalytic cracking of cumene.

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Authors and Affiliations

  1. L. V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 pr. Nauky, Kiev, 03028, Ukraine

    Roman Barakov, Nataliya Shcherban, Pavel Yaremov, Vladimir Solomakha & Vladimir Ilyin

  2. M. P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation, National Academy of Sciences of Ukraine, 34 pr. Acad. Palladina, Kiev, 03680, Ukraine

    Aleksey Vyshnevskyy

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  1. Roman Barakov
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Correspondence to Roman Barakov.

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Barakov, R., Shcherban, N., Yaremov, P. et al. Low-temperature synthesis, structure, sorption properties and acidity of zeolite ZSM-5. J Porous Mater 23, 517–528 (2016). https://doi.org/10.1007/s10934-015-0105-8

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