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Reaction of Triarylantimony Dibromides Ar3SbBr2 with Sodium Salts (X = NO3, NCS, F)

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Abstract

Triarylantimony dibromides reacted with sodium nitrate, thiocyanate, and fluoride in aqueous acetone at room temperature to give bridged dinuclear antimony compounds [(4-MeC6H4)3SbONO2]2O, (Ph3SbNCS)2O, [(3-MeC6H4)3SbNCS]2O, and [(4-MeC6H4)3SbNCS]2O and mononuclear derivatives (2-MeC6H4)3Sb(NCS)2 and (3-FC6H4)3SbF2. The antimony atoms in these compounds have a distorted trigonal-bipyramidal configuration with electronegative atoms in the axial positions.

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Authors and Affiliations

  1. South Ural National Research University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & D. M. Sopshina

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. D. M. Sopshina
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Correspondence to V. V. Sharutin.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 9, pp. 1438–1445 https://doi.org/10.31857/S0044460X21090158.

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Sharutin, V.V., Sharutina, O.K. & Sopshina, D.M. Reaction of Triarylantimony Dibromides Ar3SbBr2 with Sodium Salts (X = NO3, NCS, F). Russ J Gen Chem 91, 1717–1723 (2021). https://doi.org/10.1134/S1070363221090152

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