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µ2-Oxo-Bis[(2,5-Dinitrophenoxo)triarylantimony]: Syntheses, Structures, and Reactions with Pentaarylantimony

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Abstract

Antimony aroxides [Ph3SbOC6H3(NO2)2-2,5]2O (I) and [(4-MeC6H4)3SbOC6H3(NO2)2-2,5]2O (II) were synthesized by the oxidation of triarylantimony with tert-butyl hydroperoxide in the presence of 2,5-dinitrophenol. The SbOSb fragments in compounds I and II are bent (the corresponding angles are 139.70(10)° and 142.32(12)°). The Sb−Оbr bonds (1.973(3), 1.980(3) Å in I; 1.975(2), 1.977(2) Å in II) are substantially shorter than Sb−Ot (2.211(3), 2.213(3) and 2.191(2), 2.191(2) Å in I and II, respectively). Aroxides Ar4SbOC6H3(NO2)2-2,5 (Ar = Ph (III) and 4-MeC6H4 (IV)) and carbonates (Ar4Sb)2CO3 (Ar = Ph (V) and 4-MeC6H4 (VI)) are formed from Ar5Sb and compounds I and II in the presence of oxygen and carbon dioxide, respectively. In the trigonal bipyramidal molecules of compounds III and IV, the СSbO axial angles are 175.80(7)° and 176.86(10)° (Sb−O 2.290(2) and 2.342(2) Å, respectively). One of the antimony atoms in compound V and in crystallographically independent molecules of two types of compound VI is pentacoordinated (the Sb−Oax bond is 2.245(6) Å in V and is 2.263(3) and 2.263(3) Å in VIа and VIb, respectively), whereas the second antimony atom is hexacoordinated (Sb−O 2.249(6) and 2.273(5) Å in V; 2.216(2), 2.251(2) Å and 2.217(2), 2.251(2) Å in VIа and VIb). The crystallographic data are deposited with the Cambridge Crystallographic Data Centre (СIF files ССDС nos. 1890704 (I), 1890706 (II), 1890713 (III), 1890714 (IV), 994519 (V), and 994177 (VI)).

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REFERENCES

  1. Hadjikakou, S.K., Ozturk, I.I., Banti, C.N., et al., J. Inorg. Biochem., 2015, vol. 153, p. 293.https://doi.org/10.1016/j.jinorgbio.2015.06.006

    Article  CAS  PubMed  Google Scholar 

  2. Ali, M.I., Rauf, M.K., Badshah, A., et al., Dalton Trans., 2013, vol. 42, p. 16733.https://doi.org/10.1039/C3DT51382C

    Article  CAS  PubMed  Google Scholar 

  3. Zhang, X.-Y., Cui, L., Zhang, X., et al., J. Mol. Struct., 2017, vol. 1134, p. 742.https://doi.org/10.1016/j.molstruc.2017.01.039

    Article  CAS  Google Scholar 

  4. Gushchin, A.V., Grunova, E.V., Moiseev, D.V., et al., Izv. Akad. Nauk, Ser. Khim., 2003, no. 6, p. 1302.

  5. Sharutin, V.V., Sharutina, O.K., Efremov, A.N., et al., Russ. J. Inorg. Chem., 2018, vol. 63, no. 2, p. 174. https://doi.org/10.1134/S0036023618020195

    Article  CAS  Google Scholar 

  6. Sharutin, V.V., Sharutina, O.K., and Efremov, A.N., Russ. J. Inorg. Chem., 2018, vol. 63, no. 3, p. 343.https://doi.org/10.1134/S0036023618030208

    Article  CAS  Google Scholar 

  7. Sharutin, V.V., Sharutina, O.K., Senchurin, V.S., et al., Vestnik YuUr.Gos. Univ. Ser. Khim., 2014, vol. 6, no. 4, p. 14.

    Google Scholar 

  8. SMART and SAINT-Plus. Version 5.0. Data Collection and Processing Software for the SMART System, Madison: Bruker AXSInc., 1998.

  9. SHELXTL/PC. Version 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Bruker AXS Inc., Madison, 1998.

  10. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, p. 339.https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  11. Li, N., Qiu, R., Zhang, X., et al., Tetrahedron, 2015, vol. 71, p. 4275.https://doi.org/10.1016/j.tet.2015.05.013

    Article  CAS  Google Scholar 

  12. Gibbons, M.N. and Sowerby, D.B., J. Organomet. Chem., 1998, vol. 555, p. 271.https://doi.org/10.1016/S0022-328X(97)00759-6

    Article  CAS  Google Scholar 

  13. Ruther, R., Huber, F., and Preut, H., Angew. Chem., Int. Ed. Engl., 1987, vol. 26, p. 906.https://doi.org/10.1002/anie.198709061

    Article  Google Scholar 

  14. Preut, H., Ruther, R. and Huber, F., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1986, vol. 42, p. 1154.https://doi.org/10.1107/S010827018609306X

    Article  Google Scholar 

  15. Gibbons, M.N. and Sowerby, D.B., J. Chem. Soc., Dalton Trans. (1972–1999), 1997, p. 2785.

  16. Effendy Grigsby, W.J., Hart, R.D., et al., Aust. J. Chem., 1997, vol. 50, p. 675.https://doi.org/10.1071/C96042

    Article  Google Scholar 

  17. Quan, L., Yin, H., and Wang, D., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2009, vol. 65.https://doi.org/10.1107/S1600536808042335

    Article  Google Scholar 

  18. Quan, L., Yin, H., and Wang, D., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2008, vol. 64.https://doi.org/10.1107/S1600536808000676

    Article  CAS  Google Scholar 

  19. Ebina, F., Ouchi, A., Yoshino, Y., et al., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1978, vol. 34, p. 2134.https://doi.org/10.1107/S0567740878007578

    Article  Google Scholar 

  20. Mahon, M.F., Molloy, K.C., Omotowa, B.A., et al., J. Organomet.Chem., 1998, vol. 560, p. 95.https://doi.org/10.1016/S0022-328X(98)00488-4

    Article  CAS  Google Scholar 

  21. Abakumov, G.A., Vavilina, N.N., Kursky, Yu.A., et al., Russ. Chem. Bull., 2007, vol. 9, p. 1813.

    Article  Google Scholar 

  22. Perpetuo, G.J. and Janczak, J., Acta Crystallogr., Sect. C: Crystal Struct. Commun., 2005, vol. 61, p. o165.https://doi.org/10.1107/S0108270105001253

    Article  CAS  Google Scholar 

  23. Sharutin, V.V., Sharutina, O.K., Senchurin, V.S., et al., Russ. J. Coord. Chem., 2001, vol. 27, no. 9, p. 669.https://doi.org/10.1023/A:1017909824029

    Article  CAS  Google Scholar 

  24. Batsanov, S.S., Russ. J. Inorg. Chem., 1991, vol. 36, no. 12, p. 3015.

    CAS  Google Scholar 

  25. Ferguson, G. and Hawley, D.M., Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1974, vol. 30, no. 1, p. 103.https://doi.org/10.1107/S0567740874002299

    Article  Google Scholar 

  26. Sharutin, V.V., Sharutina, O.K., Platonova, T.P., et al., Russ. J. Gen. Chem., 2001, vol. 71, no. 10, p. 1550.https://doi.org/10.1023/A:1013938600798

    Article  CAS  Google Scholar 

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Funding

South Ural State University thanks the Ministry of Science and Higher Education of the Russian Federation for financial support, project no. 4.6151.2017/8.9.

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  1. South Ural State University, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & A. N. Efremov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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Correspondence to V. V. Sharutin.

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Translated by E. Yablonskaya

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Sharutin, V.V., Sharutina, O.K. & Efremov, A.N. µ2-Oxo-Bis[(2,5-Dinitrophenoxo)triarylantimony]: Syntheses, Structures, and Reactions with Pentaarylantimony. Russ J Coord Chem 46, 42–52 (2020). https://doi.org/10.1134/S1070328419120066

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