Skip to main content
SpringerLink
Log in

Synthesis and Structure of Oxygen-Containing Antimony Complexes (Ar2SbO)4(O2)2

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Triarylantimony Ar3Sb (Ar = 4-FC6H4, 3-MeC6H4) is oxidized by hydrogen peroxide to form tetranuclear complexes [(4-FC6H4)2SbO]4(O2)2 and [(3-MeC6H4)2SbO]4(O2)2 (as a DMSO solvate). The structure of the resulting compounds was examined by single crystal X-ray diffraction analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hadjikakou, S.K., Ozturk, I.I., Banti, C.N., Kourkoumelis, N., and Hadjiliadis, N., J. Inorg. Biochem., 2015, vol. 153, p. 293. doi https://doi.org/10.1016/j.jinorgbio.2015.06.006

    Article  CAS  PubMed  Google Scholar 

  2. Tiekink, E.R.T., Crit. Rev. Oncol. Hematol., 2002, vol. 42, no. 3, p. 217. doi https://doi.org/10.1016/S1040-8428(01)00217-7

    Article  PubMed  Google Scholar 

  3. Ozturk, I.I., Banti, C.N., Manos, M.J., Tasiopoulos, A.J., Kourkoumelis, N., Charalabopoulos, K., and Hadjikakou, S.K., J. Inorg. Biochem., 2012, vol. 109, p. 57. doi https://doi.org/10.1016/j.jinorgbio.2012.01.014

    Article  CAS  PubMed  Google Scholar 

  4. Ali, M.I., Rauf, M.K., Badshah, A., Kumar, I., Forsyth, C.M., Junk, P.C., Kedzierski, L., and Andrews, P.C., Dalton Trans., 2013, vol. 42, no. 1, p. 16733. doi https://doi.org/10.1039/C3DT51382C

    Article  CAS  PubMed  Google Scholar 

  5. Zhang, X.Y., Cui, L.S., Zhang, X., Jin, F., and Fan, Y.-H., J. Mol. Struct., 2017, vol. 1134, p. 742. doi https://doi.org/10.1016/j.molstruc.2017.01.039

    Article  CAS  Google Scholar 

  6. Ferguson, G., Glidewell, C., Kaitner, B., Lloyd, D., and Metcalfe, S., Acta Crystallogr., Sect. C, 1987, vol. 43, no. 5, p. 824. doi https://doi.org/10.1107/S0108270187093922

    Article  Google Scholar 

  7. Matano, Y., Nomura, H., Hisanaga, T., Nakano, H., Shiro, M., and Imahori, H., Organometallics, 2004, vol. 23, no. 23, p. 5471. doi https://doi.org/10.1021/om0494115

    Article  CAS  Google Scholar 

  8. Sharutin, V.V., Molokova, O.V., Sharutina, O.K., and Smirnova, S.A., Russ. J. Inorg. Chem., 2012, vol. 57, no. 9, p. 1252. doi https://doi.org/10.1134/S0036023612090185

    Article  CAS  Google Scholar 

  9. Beckmann, J., Finke, P., Hesse, M., and Wettig, B., Angew. Chem., Int. Ed., 2008, vol. 47, no. 51, p. 9982. doi https://doi.org/10.1002/anie.200803997

    Article  CAS  Google Scholar 

  10. Bordner, J., Doak, G.O., and Everett, T.S., J. Am. Chem. Soc., 1986, vol. 10, no. 14, p. 4206. doi https://doi.org/10.1021/ja00274a059.

    Article  Google Scholar 

  11. Jami, A.K. and Baskar, V., Dalton Trans., 2012, vol. 41, p. 12524. doi https://doi.org/10.1039/c2dt30587a

    Article  CAS  PubMed  Google Scholar 

  12. Brünig, J., Hupf, E., Lork, E., Mebs, S., and Beckmann, J., Dalton Trans., 2015, vol. 44, p. 7105 doi https://doi.org/10.1039/c5dt00588d

    Article  CAS  PubMed  Google Scholar 

  13. Breunig, H.J., Krüger, T., and Lork, E., J. Organomet. Chem., 2002, vol. 648, no. 2, p. 209. doi https://doi.org/10.1016/S0022-328X(01)01466-8

    Article  CAS  Google Scholar 

  14. Breunig, H.J., Krüger, T., and Lork, E., Angew. Chem., Int. Ed., 1997, vol. 36, p. 615. doi https://doi.org/10.1002/anie.199706151

    Article  CAS  Google Scholar 

  15. Betz, R., Lindner, C., Klufers, P., and Mayer, P., Acta Crystallogr., Sect. E, 2009, vol. 65, p. m253. doi https://doi.org/10.1107/S160053680804419X

    Article  CAS  Google Scholar 

  16. Sharutin, V.V., Pakusina, A.P., Sharutina, O.K., Platonova, T.P., Smirnova, S.A., Pushilin, M.A., and Gerasimenko, A.V., Russ. J. Coord. Chem., vol. 30, no. 5, p. 336. doi https://doi.org/10.1023/B:RUCO.0000025999.14773.59

  17. Sharutin, V.V., Sharutina, O.K., Chagarova, O.V., and Molokova, O.V., Russ. J. Gen. Chem., 2011, vol. 81, no. 11, p. 2246. doi https://doi.org/10.1134/S1070363211110065

    Article  CAS  Google Scholar 

  18. Sharutin, V.V. and Senchurin, V.S., Imennye reaktsii v khimii elementoorganicheskikh soedinenii (Name Reactions in the Chemistry of Organoelement Compounds), Chelyabinsk: Yuzhno-Ural’sk. Gos. Univ., 2011, p. 148.

    Google Scholar 

  19. Sharutin, V.V., Sharutina, O.K., Senchurin, V.S., Kartseva, M.K., and Andreev, P.V., Russ. J. Inorg. Chem., 2018, vol. 63, no. 7, p. 867. doi https://doi.org/10.1134/S0036023618070185

    Article  CAS  Google Scholar 

  20. Fukin, G.K., Zakharov, L.N., Domrachev, G.A., Fedorov, A.Yu., Zaburdyaeva, S.N., and Dodonov, V.A., Russ. Chem. Bull., 1999, vol. 48, no. 9, p. 1722.

    Article  CAS  Google Scholar 

  21. Sharutin, V.V., Sharutina, O.K., and Shalabanova, N.A., Russ. J. Coord. Chem., 2018, vol. 44, no. 12, p. 765. doi https://doi.org/10.1134/S1070328418120138

    Article  CAS  Google Scholar 

  22. Gushchin, A.V., Dodonov, V.A., Usyatinskii, R.I., Koreshkova, E.R., and Tipanov, B.B., Izv. Ross. Akad. Nauk, Ser. Khim., 1994, no. 7, p. 1302.

  23. Batsanov, S.S., Zh. Neorg. Khim., 1991, vol. 36, no. 12, p. 3015.

    CAS  Google Scholar 

  24. SMART and SAINT-Plus, Versions 5.0. Data Collection and Processing Software for the SMART System, Madison, Wis.: Bruker AXS, 1998.

  25. SHELXTL/PC, Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Madison, Wis.: Bruker AXS, 1998; Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Cryst., 2009, vol. 42, p. 339. doi https://doi.org/10.1107/S0021889808042726

Download references

Author information

Authors and Affiliations

  1. South Ural State University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, A. V. Rybakova & P. V. Andreev

Authors
  1. V. V. Sharutin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. K. Sharutina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Rybakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. V. Andreev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Rybakova.

Additional information

Conflict of Interest

No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 8, pp. 1254–1259.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sharutin, V.V., Sharutina, O.K., Rybakova, A.V. et al. Synthesis and Structure of Oxygen-Containing Antimony Complexes (Ar2SbO)4(O2)2. Russ J Gen Chem 89, 1637–1641 (2019). https://doi.org/10.1134/S1070363219080140

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363219080140

Keywords

Search

Navigation