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Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid

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Abstract

The results on the synthesis and study of the crystal structures of compounds based on anionic fragments {VO(Cbdc)2}2– formed by oxovanadium(IV) (vanadyl, VO2+) and two chelate-bound anions of cyclobutane-1,1-dicarboxylic acid (H2Cbdc = C4H6(COOH)2) are presented. The use of ammonium cation NH4+ as a counterion in the synthesis leads to the formation of the mononuclear complex (NH4)2[VO(Сbdc)2(H2O)] · 2H2O (I). In the case of K+ cation, compound [K4(VO)2(Сbdc)4(H2O)4] n (II) with the 3D polymeric crystal structure is formed. The reaction of compound II with Mg(NO3)2 · 6H2O in an aqueous solution involves the partial substitution of K+ by Mg2+ cations to form 1D polymeric compound {[KMg0.5(VO)(Сbdc)2(H2O)6.5] · 3H2O} n (III), while a similar reaction of compound I does not afford the product of substitution of NH4+ by Mg2+ cations (CIF files CCDC 1551021–1551023 for compounds I–III, respectively).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. S. Bazhina, G. G. Aleksandrov, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

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  1. E. S. Bazhina
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  2. G. G. Aleksandrov
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  3. M. A. Kiskin
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  4. A. A. Sidorov
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  5. I. L. Eremenko
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Correspondence to E. S. Bazhina.

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† Deceased.

Original Russian Text © E.S. Bazhina, G.G. Aleksandrov, M.A. Kiskin, A.A. Sidorov, I.L. Eremenko, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 11, pp. 641–649.

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Bazhina, E.S., Aleksandrov, G.G., Kiskin, M.A. et al. Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid. Russ J Coord Chem 43, 709–717 (2017). https://doi.org/10.1134/S107032841711001X

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  • DOI: https://doi.org/10.1134/S107032841711001X

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