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Synthesis, structure, and ESR spectra of the new heteronuclear complex {Li4(VO)2[(OOC)2C(H)Bu]4(H2O)8}·H2O

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Abstract

The reaction of an aqueous solution of vanadyl sulfate VOSO4·3H2O, butylmalonic acid (H2Bumal = C4H10(COOH)2), and lithium carbonate at pH ∼4–5 gave crystals of the complex Li4(VO)2(Bumal)4(H2O)8]·H2O (1). The structure of complex 1 was established by X-ray diffraction analysis. The molecule of complex 1 consists of two mononuclear bischelate dianionic units {VO(Bumal)2(H2O)} linked by four lithium ions to form the hexanuclear heterometallic {V2Li4} structure. The crystals and an ethanolic solution of compound 1 were studied by ESR spectroscopy.

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References

  1. I. Sádaba, S. Lima, A. A. Valente, M. Lypez Granados, Carb. Res., 2011 346, 2785.

    Article  Google Scholar 

  2. M. Di Serio, M. Cozzolino, R. Tesser, P. Patrono, F. Pinzari, B. Bonelli, E. Santacesaria, Appl. Catal. A: Gen., 2007 320, 1.

    Article  Google Scholar 

  3. S. K. De, R. A. Gibbs, J. Mol. Cat. A: Chem., 2005 232, 123.

    Article  CAS  Google Scholar 

  4. M. S. Refat, S. A. El-Shazly, Eur. J. Med. Chem., 2010 45, 3070.

    Article  CAS  Google Scholar 

  5. A. M. Cortizo, M. Silvina Molinuevo, D. A. Barrio, L. Bruzzone, Int. J. Biochem. Cell. B., 2006 38, 1171.

    Article  CAS  Google Scholar 

  6. D. Lapenna, G. Ciofani, C. Bruno, S. D. Pierdomenico, L. Giuliani, M. A. Giamberardino, F. Cuccurullo, Biochem. Pharmacol., 2002 63, 375.

    Article  CAS  Google Scholar 

  7. C. Weeks, Y. Song, M. Suzuki, N. A. Chernova, P. Y. Zavalij, M. S. Whittingham, J. Mater. Chem., 2003 13, 1420.

    Article  CAS  Google Scholar 

  8. E. C. Sacudo, A. A. Smith, P. V. Mason, M. Helliwell, G. Aromi, R. E. P. Winpenny, Dalton Trans., 2006, 1981.

    Google Scholar 

  9. J. Salta, J. Zubieta, Inorg. Chim. Acta, 1996 252, 435.

    Article  CAS  Google Scholar 

  10. F. A. Cotton, G. E. Lewis, G. N. Mott, Inorg. Chem., 1982 21, 3127.

    Article  CAS  Google Scholar 

  11. J. Salta, Ch. J. O’Connor, S. Li, J. Zubieta, Inorg. Chim. Acta, 1996 250, 303.

    Article  CAS  Google Scholar 

  12. S. Yang, G. Li, Sh. Tian, F. Liao, J. Lin, Eur. J. Inorg. Chem., 2006, 2850.

    Google Scholar 

  13. B. Baruah, V. O. Golub, Ch. J. O’Connor, A. Chakravorty, Eur. J. Inorg. Chem., 2003, 2299.

    Google Scholar 

  14. M. Sutradhar, T. R. Barman, G. Mukherjee, M. Kar, S. S. Saha, M. G. B. Drew, S. Ghosh, Inorg. Chim. Acta, 2011 368, 13.

    Article  CAS  Google Scholar 

  15. Q. Zh. Zhang, C. Zh. Lu, W. B. Yang, Sh. M. Chen, Ya Q. Yu, J. Mol. Struct., 2004 693, 199.

    Article  CAS  Google Scholar 

  16. I. G. Filippova, G. A. Kiosse, Koord. Khim., 2000 26, 666 [Russ. J. Coord. Chem. (Engl. Transl.), 2000 26].

    Google Scholar 

  17. E. S. Bazhina, M. E. Nikiforova, G. G. Aleksandrov, V. V. Minin, N. N. Efimov, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko, Russ. Chem. Bull. (Int. Ed.), 2011 60, 798 [Izv. Akad. Nauk, Ser. Khim., 2011, 779].

    Article  Google Scholar 

  18. E. S. Bazhina, M. E. Nikiforova, G. G. Aleksandrov, N. N. Efimov, M. A. Kiskin, E. A. Ugolkova, V. V. Minin, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko, Russ. Chem. Bull. (Int. Ed.), 2012 61, 1426 [Izv. Akad. Nauk, Ser. Khim., 2011, 1411].

    Article  CAS  Google Scholar 

  19. N. V. Zauzolkova, Ph. D. (Chem.) Thesis, Moscow, 2010, 165 pp. (in Russian).

  20. A. A. Sidorov, M. E. Nikiforova, N. V. Zauzolkova, E. N. Zorina, M. A. Kiskin, V. V. Zyuzin, E. F. Zharikova, S. V. Savilov, Zh. V. Dobrokhotova, V. M. Novotortsev, I. L. Eremenko, Izv. Vuzov, Ser. Khim. i Khimich. Tekh. [Proceedings of Educational Institutes: Chemistry and Chemical Technology], 2010 53, 69 (in Russian).

    CAS  Google Scholar 

  21. A. E. Gol’dberg, Ph. D. (Chem.) Thesis, Moscow, 2011, 143 pp. (in Russian).

  22. H. Necefoglu, W. Clegg, A. J. Scott, Acta Crystallogr., Sect. E: Struct. Rep. Online, 2002 58, m123.

    Article  CAS  Google Scholar 

  23. W. Clegg, P. A. Hunt, B. P. Straughan, M. A. Mendiola, J. Chem. Soc., Dalton Trans., 1989, 1127.

    Google Scholar 

  24. C. Cadiou, R. A. Coxall, A. Graham, A. Harrison, M. Helliwell, S. Parsons, R. E. P. Winpenny, Chem. Commun., 2002, 1106.

    Google Scholar 

  25. E. K. Brechin, A. Graham, S. G. Harris, S. Parsons, R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1997, 3405.

    Google Scholar 

  26. Yu. V. Rakitin, G. M. Larin, V. V. Minin, Interpretatsiya spektrov EPR koordinatsionnykh soedinenii [Interpretation of ESR Spectra of Coordination Compounds], Nauka, Moscow, 1993, 399 pp. (in Russian).

    Google Scholar 

  27. Ya. S. Lebedev, V. I. Muromtsev, EPR i relaksatsiya ctabilizirovannykh radikalov [ESR and Relaxation of Stabilized Radicals], Khimiya, Moscow, 1972, p. 25 (in Russian).

    Google Scholar 

  28. R. Wilson, D. Kivelson, J. Chem. Phys., 1966 44, 154.

    Article  CAS  Google Scholar 

  29. SMART (Control) and SAINT (Integration) Software, Version 5.0, Bruker AXS, Inc., Madison (WI), 1997.

  30. G. M. Sheldrik, SADABS, Program for Scanning and Correction of Area Detector Data, Göttingen University, Göttingen, Germany, 2004

    Google Scholar 

  31. G. M. Sheldrick, Acta Crystallogr., Sect. A: Found. Crystallogr., 2008 64, 112.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. S. Bazhina, G. G. Aleksandrov, N. N. Efimov, E. A. Ugolkova, V. V. Minin, A. A. Sidorov, V. M. Novotortsev & I. L. Eremenko

Authors
  1. E. S. Bazhina
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  2. G. G. Aleksandrov
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  3. N. N. Efimov
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  4. E. A. Ugolkova
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  5. V. V. Minin
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  6. A. A. Sidorov
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  7. V. M. Novotortsev
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  8. I. L. Eremenko
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Correspondence to E. S. Bazhina.

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Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0962–0965, April, 2013.

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Bazhina, E.S., Aleksandrov, G.G., Efimov, N.N. et al. Synthesis, structure, and ESR spectra of the new heteronuclear complex {Li4(VO)2[(OOC)2C(H)Bu]4(H2O)8}·H2O. Russ Chem Bull 62, 962–965 (2013). https://doi.org/10.1007/s11172-013-0125-y

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  • DOI: https://doi.org/10.1007/s11172-013-0125-y

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