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The effect of the substituents in the malonate anion and the solvent molecules on the structures of novel coordination polymers [Li2VO(R2mal)2] n

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Abstract

Reactions of vanadyl sulfate (VOSO4∙3H2O) with dimethylmalonic (H2Me2mal = = C3H6(CO2H)2), cyclobutane-1,1-dicarboxylic (H2cbdc = C4H6(CO2H)2), or butylmalonic acid (H2Bumal = C4H10(CO2H)2) and Li2CO3 in a ratio of 1: 2: 2 afforded novel coordination polymers of similar compositions ([Li2(VO)(Me2mal)2] n (1), [Li2(VO)(Me2mal)2(EtOH)-(H2O)] n (2), [Li4(VO)2(cbdc)4(H2O)7] n (3), and [Li2(VO)(Bumal)2(H2O)5.5] n (4)) but different structures. The crystal structures of the compounds containing the Me2mal2– and Bumal2– anions depend on the solvent nature.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. S. Bazhina, G. G. Aleksandrov, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

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  1. E. S. Bazhina
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  2. G. G. Aleksandrov
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  3. M. A. Kiskin
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  4. A. A. Sidorov
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  5. I. L. Eremenko
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Corresponding author

Correspondence to E. S. Bazhina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0249—0258, January, 2016.

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Bazhina, E.S., Aleksandrov, G.G., Kiskin, M.A. et al. The effect of the substituents in the malonate anion and the solvent molecules on the structures of novel coordination polymers [Li2VO(R2mal)2] n . Russ Chem Bull 65, 249–258 (2016). https://doi.org/10.1007/s11172-016-1293-3

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  • DOI: https://doi.org/10.1007/s11172-016-1293-3

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