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Physical and Chemical Properties of the Surface of Aluminosilicate Halloysite Nanotubes Modified by Magnetite Nanoparticles

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Abstract

Halloysite is modified with magnetite nanoparticles by the chemical coprecipitation of iron salts. To characterize the surface and study the physical-chemical properties of the resulting composite and its components (halloysite and magnetite), we use dynamic light scattering, electron microscopy, the low-temperature adsorption–desorption of nitrogen, X-ray diffraction analysis, Mössbauer and IR (infrared) spectroscopy, and magnetic measurements. Energy-dispersive analysis data and X-ray diffraction patterns confirm the modification of halloysite by magnetite nanoparticles, changing the zeta potential and the adsorption capacity of the surface. IR spectral analysis of the studied composites reveal shifts in the characteristic bands of halloysite and magnetite during their formation. The halloysite/magnetite composite samples have a higher field strength of effective anisotropy and coercive force compared to magnetite.

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REFERENCES

  1. Y. Lvov, A. Aerov, and R. Fakhrullin, Adv. Colloid Interface Sci. 207, 189 (2014). https://doi.org/10.1016/j.cis.2013.10.006

    Article  CAS  Google Scholar 

  2. K. Tazaki, Clays Clay Miner. 53, 224 (2005). https://doi.org/10.1346/CCMN.2005.0530303

    Article  CAS  Google Scholar 

  3. K. A. Gonchar, A. V. Kondakova, Subhra Jana, and V. Yu. Timoshenkova, Phys. Solid State 58, 601 (2016).

    Article  CAS  Google Scholar 

  4. A. N. Vasiliev, L. V. Shvanskaya, O. S. Volkova, and A. V. Koshelev, Mater. Charact. 129, 179 (2017). https://doi.org/10.1016/j.matchar.2017.04.028

    Article  CAS  Google Scholar 

  5. L. Dong, M. Li, S. Zhang, X. Si, Y. Bai, and C. Zhang, Desalination 476, 114227 (2020). https://doi.org/10.1016/j.desal.2019.114227

    Article  CAS  Google Scholar 

  6. L. Lia, F. Wanga, Y. Lva, J. Liua, D. Zhanga, and Z. Shao, Appl. Clay Sci. 161, 225 (2018). https://doi.org/10.1016/j.clay.2018.04.002

    Article  CAS  Google Scholar 

  7. N. H. Abdullah, K. Shameli, E. C. Abdullah, and L. C. Abdullah, Composites, Part B 162, 538 (2019). https://doi.org/10.1016/j.compositesb.2018.12.075

    Article  CAS  Google Scholar 

  8. A.-H. Lu, E. L. Salabas, and F. Schuth, Angew. Chem., Int. Ed. 46, 1222 (2007). https://doi.org/10.1002/anie.200602866

    Article  CAS  Google Scholar 

  9. O. V. Alekseeva, A. N. Rodionova, A. V. Noskov, and A. V. Agafonov, Clays Clay Miner. 67, 471 (2019). https://doi.org/10.1007/s42860-019-00037-w

    Article  CAS  Google Scholar 

  10. A. Guinier, X-Ray Diffraction: In Crystals, Imperfect Crystals, and Amorphous Bodies (Dover, New York, 1994).

  11. Y. Lvov and E. Abdullayev, Prog. Polym. Sci. 38, 1690 (2013). https://doi.org/10.1016/j.progpolymsci.2013.05.009

    Article  CAS  Google Scholar 

  12. Y. Zhang, Y. Li, Y. Zhang, D. Ding, L. Wang, M. Liu, and F. Zhang, J. Therm. Anal. Calorim. 135, 2429 (2019). https://doi.org/10.1007/s10973-018-7354-0

    Article  CAS  Google Scholar 

  13. Y. Zhang, L. Bai, C. Cheng, Q. Zhou, Z. Zhang, Y. Wu, and H. Zhang, Appl. Clay Sci. 182, 105259 (2019). https://doi.org/10.1016/j.clay.2019.105259

    Article  CAS  Google Scholar 

  14. X. Tian, W. Wang, N. Tian, C. Zhou, C. Yang, and S. Komarneni, J. Hazard. Mater. 309, 151 (2016). https://doi.org/10.1016/j.jhazmat.2016.01.081

    Article  CAS  Google Scholar 

  15. S. Zhong, C. Zhou, X. Zhang, H. Zhoub, H. Li, X. Zhua, and Y. Wang, J. Hazard. Mater. 276, 58 (2014). https://doi.org/10.1016/j.jhazmat.2014.05.013

    Article  CAS  Google Scholar 

  16. J. Lopez, L. F. Gonzalez, F. A. Bonilla, G. Zambrano, M. E. Gomez, Rev. Latinoam. Metal. Mater. 30, 60 (2010).

    Google Scholar 

  17. M. A. Stepovich, M. N. Shipko, V. G. Kostishin, and V. V. Korovushkin, J. Surf. Invest.: X-ray, Synchrotron Neutron Tech. 11, 194 (2017). https://doi.org/10.1134/S1027451017010190

    Article  CAS  Google Scholar 

  18. J. Lu, Z. Yuan, X. Guo, Z. Tong, and L. Li, Int. J. Miner. Metall. Mater. 26, 1 (2019). https://doi.org/10.1007/s12613-019-1704-1

    Article  CAS  Google Scholar 

  19. M. A. Stepovich, M. N. Shipko, V. V. Korovushkin, and V. G. Kostishin, Bull. Russ. Acad. Sci.: Phys. 81, 1037 (2017). https://doi.org/10.3103/S1062873817080299

    Article  CAS  Google Scholar 

  20. A. V. Koshelev, E. A. Zvereva, D. A. Chareev, O. S. Volkova, A. Vymazalova, F. Laufek, E. V. Kovalchuk, B. Rahaman, T. Saha-Dasgupta, and A. N. Vasiliev, Phys. Chem. Miner. 43, 44 (2015). https://doi.org/10.1007/s00269-015-0772-7

    Article  CAS  Google Scholar 

  21. O. V. Alekseeva, A. N. Rodionova, N. A. Bagrovskaya, and A. V. Agafonov, Prot. Met. Phys. Chem. Surf. 52, 819 (2016). https://doi.org/10.1134/S2070205116050038

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The studies were carried out using equipment of the Collective Use Center “Verkhne-Volzhsky Regional Center for Physical and Chemical Research.”

Funding

The work was partially supported by the Russian Foundation for Basic Research (project no. 19-03-00271).

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Authors and Affiliations

  1. G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045, Ivanovo, Russia

    O. V. Alekseeva, D. N. Smirnova, A. V. Noskov & A. V. Agafonov

  2. Ivanovo State University of Power Engineering, 153000, Ivanovo, Russia

    M. N. Shipko

  3. Kaluga State University, 248023, Kaluga, Russia

    M. A. Stepovich

Authors
  1. O. V. Alekseeva
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  2. M. N. Shipko
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  3. D. N. Smirnova
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  4. A. V. Noskov
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  5. A. V. Agafonov
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  6. M. A. Stepovich
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Corresponding author

Correspondence to M. N. Shipko.

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We declare that we have no conflicts of interest.

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Translated by O. Zhukova

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Alekseeva, O.V., Shipko, M.N., Smirnova, D.N. et al. Physical and Chemical Properties of the Surface of Aluminosilicate Halloysite Nanotubes Modified by Magnetite Nanoparticles. J. Surf. Investig. 15 (Suppl 1), S18–S24 (2021). https://doi.org/10.1134/S1027451022020021

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  • DOI: https://doi.org/10.1134/S1027451022020021

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