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A study of the interaction between polyvinylpyrrolidone and gemini surfactant G12-3-12 by NMR

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Abstract

The interaction between a water-soluble polymer polyvinylpyrrolidone (PVP) and a gemini surfactant N,N'-didodecyl-N,N,N',N'-tetramethyl-N,N'-propanediyl-diammonium dibromide (G12-3-12) was investigated by means of NMR in a D2O solution at 298 K. The critical micelle concentration (СMC), critical aggregation concentration (СAC) and adsorption reached the saturated concentration (C2) were confirmed by chemical shift and self-diffusion coefficients, respectively. The results of the relaxation time ratio (T R = T 2/T 1) of G12-3-12 show that the motion of the ionic head N+–CH *3 proton (G6) is seriously restricted, and thus, it can be proved that the cationic head groups are situated in the hydrophilic layer of the micelle. The size of the mixed-aggregates in the G12-3-12/PVP solution is larger than pure G12-3-12 micelles according to self-diffusion coefficients, indicating that the G12-3-12 and PVP has formed mixed micelles, and ionic heads N+–CH *3 become more tightly packed in the hydrophilic layer of the micelle shell. On the other hand, strong cross peaks, such as G1-P2, G1-P3, and G2-P3, appear in the 2D nuclear Overhauser enhancement spectroscopy (2D NOESY) spectra of the G12-3-12/PVP system, further indicating that the interaction sites are located between the hydrophobic tail of G12-3-12 and PVP ring.

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Authors and Affiliations

  1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, College of Chemistry and Chemical Engineering, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan, 430062, China

    S. G. Chai, H. Zhang, L. Xie, Q. C. Zou & J. Z. Zhang

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  1. S. G. Chai
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  2. H. Zhang
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  3. L. Xie
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  4. Q. C. Zou
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  5. J. Z. Zhang
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Correspondence to J. Z. Zhang.

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Chai, S.G., Zhang, H., Xie, L. et al. A study of the interaction between polyvinylpyrrolidone and gemini surfactant G12-3-12 by NMR. Polym. Sci. Ser. A 58, 315–323 (2016). https://doi.org/10.1134/S0965545X16030032

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  • DOI: https://doi.org/10.1134/S0965545X16030032

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